Multi-zone reactor for continuous polymerization of alpha-olefin monomers

An olefin monomer and reactor technology, applied in the field of multi-section reactors, can solve the problems of not allowing a large amount of liquid to recycle fluid, heat removal limitation, fluidized bed instability, etc., to improve operability and/or or continuity, eliminating the presence of stagnant sections, reducing the amount of fines

Active Publication Date: 2019-02-22
SAUDI BASIC IND CORP SA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0009] However, the heat removal achievable in such a condensing mode is still limited because current reactors, systems and methods for producing polyolefins using a fluidized bed and condensing mode do not allow large amounts of liquid in the recycle stream, because this causes destabilization of the fluidized bed

Method used

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  • Multi-zone reactor for continuous polymerization of alpha-olefin monomers
  • Multi-zone reactor for continuous polymerization of alpha-olefin monomers
  • Multi-zone reactor for continuous polymerization of alpha-olefin monomers

Examples

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Embodiment

[0173] A computer-based mathematical model capable of generating mass and heat balance along the fluidized bed reactor was used to run the simulations operating in dry and condensing modes. First, the model was validated by running it with actual data from commercial polyethylene production. The results are shown in Table 1.

[0174]

[0175] As can be seen from Table 1, the actual data are very comparable to the data from the model.

[0176] Subsequently, the polymerization process in a multi-zone reactor was used to carry out the polymerization of ethylene and 1-butene in condensation mode. The model was first run in condensation mode using actual data from commercial polyethylene production to produce a 1-butene / ethylene copolymer with a density of 918 kg / m 3 and a melt flow index of 1.0 (according to Example 6.2 of Turkistani US Patent 6,759,489 B1). Subsequently, the model was re-run according to the invention (scenario 1, 2 and 3).

[0177] The results are shown i...

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Abstract

The present invention relates to a multi-zone reactor suitable for the continuous fluidized bed polymerization of one or more alpha-olefin monomers, at least one of which is ethylene or propylene, which multi-zone reactor can be used in Operating in condensation mode, the multi-section reactor includes a first section, a second section, a third section, a fourth section and a distribution plate, wherein the first section and the second section separated by the distribution plate, wherein the multi-zone reactor extends vertically, wherein the second zone of the multi-zone reactor is located above the first zone, and wherein the said third section of said multi-zone reactor is located above said second section, and wherein said fourth section of said multi-zone reactor is located above said third section, wherein The second section comprises an inner wall, wherein at least a portion of the inner wall of the second section is in the form of a progressively increasing inner diameter or a continuously open cone, wherein the diameter or the opening is directed towards the A vertically increasing top of a multi-zone reactor, wherein the third zone comprises an inner wall, wherein at least a portion of the inner wall of the third zone is in the form of a progressively increasing inner diameter or a continuous open cone body, wherein said diameter or said opening increases vertically towards the top of said multi-zone reactor, wherein said inner wall of said third zone has a maximum diameter greater than that of said second zone The maximum diameter of the inner wall.

Description

technical field [0001] The present invention relates to a multi-zone reactor suitable for the continuous polymerization of alpha-olefin monomers, a method of using the reactor, a system comprising the reactor, a method of using the reactor, a method of using the system , a polyolefin obtainable by said process, and uses relating to said multi-zone reactor and uses relating to said system. Background technique [0002] There are many different methods for polymerizing alpha-olefin monomers, including gas phase fluidized bed methods, slurry, loop or stirred tank reactors, suspension and solution methods. [0003] The discovery of a process for the production of polyolefins in a fluidized bed has provided means for the production of a different series of polyolefins such as polyethylene, polypropylene and polyolefin copolymers. The use of fluidized bed polymerization processes substantially reduces energy requirements and most importantly the capital investment required to run...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F10/00C08F2/01C08F2/34
CPCC08F2/34C08F10/02B01J8/1818B01J8/1827B01J8/1863B01J2219/1943B01J2219/1946C08F10/06B01J2219/185C08F10/00C08F2/01C08F2/00B01J19/006B01J19/24B01J19/2455B01J19/248C08F2/002B01J8/085B01J19/2465B01J2208/00938B01J2219/00033
Inventor Y·巴纳特J·F·瑟瓦罗斯-坎道
Owner SAUDI BASIC IND CORP SA
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