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High-hardness and anti-impact PMMA/ABS (Polymethyl Methacrylate/Acrylonitrile Butadiene Styrene) composite sheet material

A composite sheet and impact-resistant technology, which is applied in the field of high-hardness and impact-resistant PMMA/ABS composite sheets, can solve the problems of low notched impact strength, no UV resistance, and increased product cost, so as to improve surface properties, reduce production costs, The effect of improving productivity

Inactive Publication Date: 2016-10-12
GETTEL GRP TONGCHENG PLASTIC IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] PMMA resin has good transparency, strength, and chemical resistance. It is widely used in home appliances and food fields, but its notched impact strength is low and toughness is poor.
Compared with some plastic products, ordinary ABS products have a lower surface hardness, which limits their application in some fields. Although there are other types of resins on the market with ideal surface hardness, these resins have improved surface hardness and mechanical strength at the same time. Decreased performance, on the other hand, the price is expensive, resulting in an increase in product cost
And it does not have the ability to resist ultraviolet rays and is easy to age

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A kind of high-hardness impact-resistant PMMA / ABS composite plate of the present invention, its component (according to parts by weight) comprises:

[0019] PMMA resin 20, ABS resin 70, MBS resin 5, polyester graft modified silicone additive 0.5, compatibilizer 0.3, dispersant 0.1, antioxidant 0.1, ultraviolet absorber UV-5310.1.

[0020] The invention discloses a high-hardness and impact-resistant PMMA / ABS composite plate, which is prepared by a one-step method of melt blending and extrusion, and the preparation method is the same as that of the prior art.

[0021] The compatibilizer is a compatibilizer grafted from maleic anhydride to polystyrene.

[0022] The dispersant is oxidized polyethylene wax, and the long-chain molecules of oxidized polyethylene wax have a certain amount of ester groups or soap groups, so the internal and external lubricating effects are relatively balanced, the effect is good, and its transparency is also good.

[0023] The antioxidant is 2,...

Embodiment 2

[0026] A kind of high-hardness impact-resistant PMMA / ABS composite plate of the present invention, its component (according to parts by weight) comprises:

[0027] PMMA resin 30, ABS resin 55, MBS resin 15, polyester graft modified silicone additive 0.7, compatibilizer 0.45, dispersant 0.3, antioxidant 0.45, ultraviolet absorber UV-5310.2, 4,4-sulfur Substituting bis(6-tert-butyl-p-cresol) 0.02 parts.

[0028] The antioxidant is bis(3,5-tertiary butyl-4-hydroxyphenyl) sulfide.

[0029] The invention discloses a high-hardness and impact-resistant PMMA / ABS composite plate, which is prepared by a one-step method of melt blending and extrusion, and the preparation method is the same as that of the prior art.

[0030] The compatibilizer is a compatibilizer grafted from maleic anhydride to polystyrene.

[0031] The dispersant is oxidized polyethylene wax, and the long-chain molecules of oxidized polyethylene wax have a certain amount of ester groups or soap groups, so the internal...

Embodiment 3

[0034] A kind of high-hardness impact-resistant PMMA / ABS composite plate of the present invention, its component (according to parts by weight) comprises:

[0035] PMMA resin 20-40, ABS resin 30-70, MBS resin 5-15, polyester graft modified silicone additive 0.5-1, compatibilizer 0.3-0.6, dispersant 0.1-0.5, antioxidant 0.1- 0.8, ultraviolet absorber UV-5310.1-0.3, 4,4-thiobis(6-tert-butyl-p-cresol) 0-0.05 parts.

[0036] The antioxidant is tetrakis[β-(3,5-tertiary butyl-4-hydroxyphenyl) propionate] pentaerythritol ester.

[0037] The invention discloses a high-hardness and impact-resistant PMMA / ABS composite plate, which is prepared by a one-step method of melt blending and extrusion, and the preparation method is the same as that of the prior art.

[0038] The compatibilizer is a compatibilizer grafted from maleic anhydride to polystyrene.

[0039] The dispersant is oxidized polyethylene wax, and the long-chain molecules of oxidized polyethylene wax have a certain amount of...

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PUM

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Abstract

The invention discloses a high-hardness and anti-impact PMMA / ABS (Polymethyl Methacrylate / Acrylonitrile Butadiene Styrene) composite sheet material. The high-hardness and anti-impact PMMA / ABS composite sheet material is prepared from the following components in parts by weight: 10 to 50 parts of PMMA resin, 20 to 70 parts of ABS resin, 1 to 15 parts of MBS (Methacrylate-Butadiene-Styrene) resin, 0.5 to 3 parts of polyester grafted modified silicone auxiliary agent, 0.2 to 0.8 part of compatilizer, 0 to 0.5 part of dispersant, 0 to 1 part of antioxidant and 0 to 0.3 part of ultraviolet absorbent UV-531. The high-hardness and anti-impact PMMA / ABS composite sheet material disclosed by the invention combines advantages of two types of plastic and makes up the respective disadvantages; the PMMA and the ABS are commixed and other additives are added; compared with common PMMA resin, the surface hardness of the obtained PMMA / ABS material is improved by 20 percent to 30 percent; meanwhile, the PMMA has a more excellent anti-impact performance; the polyester grafted modified silicone auxiliary agent is added into to the PMMA raw material so that the surface scraping resistance, abrasion resistance, smoothness and hydrophobic property of the PMMA are improved and surface friction coefficients are reduced; an anti-scratching protection layer does not need to be arranged on the surface of a PMMA plate, so that the process can be effectively simplified, the production efficiency is improved and the production cost of enterprises is reduced; meanwhile, the high-hardness and anti-impact PMMA / ABS composite sheet material has a good ultraviolet-proof performance and the service life of the sheet material is prolonged.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a high-hardness and impact-resistant PMMA / ABS composite plate. Background technique [0002] PMMA resin has good transparency, strength, and chemical resistance. It is widely used in home appliances and food fields, but its notched impact strength is low and its toughness is poor. Compared with some plastic products, ordinary ABS products have a lower surface hardness, which limits their application in some fields. Although there are other types of resins on the market with ideal surface hardness, these resins have improved surface hardness and mechanical strength at the same time. The performance declines, and on the other hand, the price is expensive, which leads to an increase in product cost. Moreover, it does not have the ability to resist ultraviolet rays and is easy to age. Contents of the invention [0003] The object of the present invention is to provide a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L33/12C08L51/04C08L87/00C08L51/00C08L23/30C08K5/132
CPCC08L55/02C08L2201/08C08L2205/035C08L2205/08C08L33/12C08L51/04C08L87/005C08L51/003C08L23/30C08K5/132
Inventor 王兆中都昌满吴姗姗熊亚南郑旭曹茂华
Owner GETTEL GRP TONGCHENG PLASTIC IND
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