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Lithium titanate battery electrolyte and lithium titanate battery

A lithium titanate battery and electrolyte technology, applied in battery electrodes, lithium batteries, electrolytes, etc., can solve the problems of reducing the theoretical cycle life of lithium titanate batteries, restricting the large-scale application of lithium titanate batteries, and failing to use them normally. Achieve the effect of reducing flatulence, improving storage and cycling performance, and enhancing stability

Active Publication Date: 2016-11-23
湖南航盛新能源材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the prior art, the lithium titanate material is used as the negative electrode material in the battery. Due to its own characteristics, the interaction between the material and the electrolyte is easy to occur and gas is precipitated during the charge-discharge cycle reaction process. Therefore, ordinary titanium Lithium-acid batteries are prone to flatulence, resulting in bulging of the battery cells, and a significant drop in electrical performance, which greatly reduces the theoretical cycle life of lithium titanate batteries
The test data shows that ordinary lithium titanate batteries will be flattened during the cycle, resulting in failure to use normally, which is also an important reason restricting the large-scale application of lithium titanate batteries

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Preparation of lithium titanate battery electrolyte: the lithium carbonate battery electrolyte is made of lithium salt LiPF 6 And organic solvent composition, described organic solvent is made up of 99.9wt% nitrile solvent acetonitrile and 0.1wt% additive LiDFOB.

[0021] Preparation of positive pole pieces for lithium titanate batteries: Mix different positive active materials with polyvinylidene fluoride (PVDF), conductive carbon black (SP) and N-methylpyrrolidone (NMP) at a mass ratio of 93:2:5, and pass Stir to obtain the slurry, apply it on the aluminum foil of the current collector on the coating machine, dry it, and obtain the positive pole piece after cold pressing and slitting;

[0022] Preparation of lithium titanate battery negative electrode sheet: Lithium titanate is used as the negative electrode active material, and polyvinylidene fluoride (PVDF), conductive carbon black (SP) is mixed with N-methylpyrrolidone (NMP) according to the mass ratio of 93:2:5 M...

Embodiment 2

[0025] The difference between this embodiment and embodiment 1 is:

[0026] The organic solvent consists of 80 wt% acetonitrile, 19.5 wt% propionitrile and 0.5 wt% LiDFOB.

Embodiment 3

[0028] The difference between this embodiment and embodiment 1 is:

[0029] The lithium salt is LiBF 4 , the organic solvent is composed of 80wt% propionitrile, 19.5wt% DMC and 0.5wt% LiDFOB.

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PUM

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Abstract

The invention relates to the technical field of batteries and particularly relates to lithium titanate battery electrolyte and a lithium titanate battery. The lithium titanate battery electrolyte is composed of a lithium salt and an organic solvent; the organic solvent is prepared from the following raw materials: 10wt%-99.9wt% of a nitrile solvent, 0wt%-89wt% of an auxiliary solvent and 0.1wt%-5wt% of an additive. The nitrile solvent does not have a side reaction with a rock-salt-phase Li7Ti5O12 material at a charging state, and certain catalysis reactions which occur in the presence of carbonyl or hydroxyl can be effectively avoided; the decomposition of the electrolyte is reduced and the probability of producing gas by lithium titanate is reduced; a gas swelling phenomenon in the lithium titanate battery is reduced, so that the storage and circulating properties of the lithium titanate battery are improved. The lithium titanate battery provided by the invention takes the lithium titanate with relatively high electric potential as an electric potential negative electrode and the side reactions of the electrolyte and the electrode can be avoided, so that the stability of the lithium titanate battery electrolyte is enhanced.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a lithium titanate battery electrolyte and a lithium titanate battery. Background technique [0002] In the prior art, the lithium titanate material is used as the negative electrode material in the battery. Due to its own characteristics, the interaction between the material and the electrolyte is easy to occur and gas is precipitated during the charge-discharge cycle reaction process. Therefore, ordinary titanium Lithium-acid batteries are prone to flatulence, resulting in bulging of the battery cells, and a significant drop in electrical performance, which greatly reduces the theoretical cycle life of lithium titanate batteries. The test data shows that ordinary lithium titanate batteries will be flattened during the cycle, resulting in failure to use normally, which is also an important reason restricting the large-scale application of lithium titanate batteries. Contents...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0569H01M4/131H01M10/052
CPCH01M4/131H01M10/052H01M10/0569H01M2300/0037Y02E60/10
Inventor 田秀丽黄继宏蒋传政
Owner 湖南航盛新能源材料有限公司
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