Production technology of metallized film

A metallized film and production process technology, applied in the field of capacitors, can solve problems such as intractability, capacitor capacity decline, breakdown, etc., to avoid breakdown accidents, improve service life, and reduce the rate of erosion.

Active Publication Date: 2017-01-04
TONGLING CHAOYUE ELECTRON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The commonly used metallized film is to vapor-deposit a layer of aluminum coating on the insulating base film. The aluminum-coated metallized film has good adhesion performance, and the production process is easy to handle, but the aluminum-coated metallized film is easily oxidized in the air. And form a dense oxide layer with aluminum oxide as the main component. Although this oxide layer can prevent the metallized film from being oxidized further, when working under AC high voltage and high current, this oxide layer will lead to a rapid decline in the capacity of the capacitor.
After the galvanized metallized film is oxidized in the air, although the adaptability to AC high-voltage and large current will not drop sharply, the adhesion between the galvanized layer and the insulating base film is lower than that between the aluminum-plated layer and the insulating base film. The adhesion between the films, and the oxidation speed of the galvanized layer is fast, the zinc oxide formed by oxidation has a fluffy structure, it is difficult to prevent further oxidation, and it is easy to form insulation defects on the insulating base film, so the metallized film galvanized layer is not only It is difficult to handle during processing, and it is easy to cause accidents of heating or even breakdown of capacitors

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Send the insulating base film into the reduction tank, and continuously pass the hydrogen sulfuric acid solution with a mass fraction of 35% into the reduction tank. The temperature of the hydrogen sulfuric acid solution is 95°C. into deionized water, and then dry the insulating base film at a temperature of 85°C. Then the insulating base film is sent into the first vacuum coating machine, and in the first vacuum coating machine, a 0.1 μm galvanized layer is formed on the working surface of the insulating base film by vacuum evaporation; wherein, in the first vacuum coating machine Middle: The working temperature of the first cooling spindle is 0°C, and the heating temperature of the zinc crucible is 780°C. Then the insulating base film is sent into a constant temperature oven to treat the galvanized layer on the surface of the insulating base film. During the surface treatment process of the galvanized layer, the oxidizing gas is continuously fed into the constant temp...

Embodiment 2

[0024] Send the insulating base film into the reduction tank, and continuously pass the hydrogen sulfuric acid solution with a mass fraction of 36% into the reduction tank. The temperature of the hydrogen sulfuric acid solution is 99 ° C. into deionized water, and then dry the insulating base film at a temperature of 88°C. Then the insulating base film is sent into the first vacuum coating machine, and in the first vacuum coating machine, a 0.1 μm galvanized layer is formed on the working surface of the insulating base film by vacuum evaporation; wherein, in the first vacuum coating machine Middle: The working temperature of the first cooling spindle is 1°C, and the heating temperature of the zinc crucible is 785°C. Then the insulating base film is sent into a constant temperature oven to treat the galvanized layer on the surface of the insulating base film. During the surface treatment process of the galvanized layer, the oxidizing gas is continuously fed into the constant te...

Embodiment 3

[0026] Send the insulating base film into the reduction tank, and continuously pass the hydrogen sulfuric acid solution with a mass fraction of 38% into the reduction tank. The temperature of the hydrogen sulfuric acid solution is 100°C. into deionized water, and then dry the insulating base film at a temperature of 90°C. Then the insulating base film is sent into the first vacuum coating machine, and in the first vacuum coating machine, a 0.1 μm galvanized layer is formed on the working surface of the insulating base film by vacuum evaporation; wherein, in the first vacuum coating machine Middle: The working temperature of the first cooling spindle is 2°C, and the heating temperature of the zinc crucible is 790°C. Then the insulating base film is sent into a constant temperature oven to treat the galvanized layer on the surface of the insulating base film. During the surface treatment process of the galvanized layer, the oxidizing gas is continuously fed into the constant tem...

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PUM

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Abstract

The invention relates to a production technology of a metallized film. The production technology is characterized in that an insulation base film is performed with an insulation base film pretreatment technology, a primary evaporation technology, a galvanized layer surface treatment technology, a secondary evaporation technology and a silver plating layer surface treatment technology, so as to form the metallized film. The production technology has the advantages that the surface of the insulation base film is treated by hydrosulphuric acid solution, so that the large-scale oxidizing of metal zinc on the surface of the insulation base film is avoided, the bonding force between a zinc plating layer and the insulation base film is guaranteed, and the self-healing capability of the metallized film is improved; a metal layer on the surface of the insulation base film is of a zinc plating layer, zinc oxide layer, silver plating layer and silver oxide oxide film four-layer structure, so that the erosion rate of the metal layer is effectively reduced, the capacity of a capacitor is not decreased, and the breakthrough accident is avoided; the service life of the metal layer is obviously prolonged.

Description

technical field [0001] The invention relates to a metallized film production process, which belongs to the technical field of capacitors. Background technique [0002] The commonly used metallized film is to vapor-deposit a layer of aluminum coating on the insulating base film. The aluminum-coated metallized film has good adhesion performance, and the production process is easy to handle, but the aluminum-coated metallized film is easily oxidized in the air. And form a dense oxide layer with aluminum oxide as the main component. Although the oxide layer can prevent the metallized film from being oxidized further, when working under high-voltage and high-current AC, the oxide layer will cause the capacity of the capacitor to drop rapidly. After the galvanized metallized film is oxidized in the air, although the adaptability to AC high-voltage and large current will not drop sharply, the adhesion between the galvanized layer and the insulating base film is lower than that betw...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G4/33H01G4/015C23C14/02C23C14/20C23C14/24C23C14/58
CPCC23C14/021C23C14/20C23C14/24C23C14/5853H01G4/015H01G4/33
Inventor 陈五一
Owner TONGLING CHAOYUE ELECTRON CO LTD
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