Preparation method of MgO-doped ZnO sputtering target material

A sputtering target and target technology, applied in sputtering coating, metal material coating process, ion implantation coating and other directions, can solve the problems of high requirements, complicated preparation process and difficult to control, expensive equipment, etc. Good dispersion, excellent luminous properties, uniform particle effect

Inactive Publication Date: 2017-02-08
GEMCH MATERIAL TECH SUZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation process of these methods is complicated and difficult to control, the conditions are relatively high, and the required equipment is expensive.
[0005] At present, the preparation of Zn for Mg-doped ZnO 1-x Mg x There are many studies on O thin films, but there are few reports on the preparation of Mg-doped ZnO powders by solid state reaction.

Method used

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preparation example Construction

[0020] In the present invention, the preparation method steps include:

[0021] (1) Weigh ZnO and MgO powders in proportion, the powder purity is greater than 99.99%, and put the two powders into a nylon ball mill jar.

[0022] (2) Add absolute ethanol and agate balls of different diameters into the ball mill jar, the weight ratio of ZnO and MgO powder, agate balls and absolute ethanol is 10:16:20.

[0023] (3) Put ZnO powder, MgO powder, absolute ethanol and agate balls into a nylon tank and place them on a star ball mill to fix them.

[0024] (4) After quick ball milling for 2 hours, take out the mixed powder in the nylon tank, and separate the agate balls through a 40-mesh sieve.

[0025] (5) Put the uniformly mixed ZnO powder and MgO powder into a low-temperature oven and dry with absolute ethanol.

[0026] (6) The dried ZnO powder and MgO powder are filled into a high temperature resistant and pressure resistant mold.

[0027] (7) Put the mold in a heated and pressuriz...

Embodiment 1

[0032] Weigh 500 g of ZnO powder with a purity of 99.99% and 20 g of MgO powder with a purity of 99.99%, put it into a nylon ball mill jar with a volume of 5 L, and then put into 800 g of agate balls and 1 kg of absolute ethanol. The nylon ball mill jar was fixed on a high-speed ball mill and ball milled for 3 hours. Use a 40-mesh sieve to separate the agate balls. The powder solution separated with a sieve is placed in a baking tray, and the baking tray is put into an oven and baked for 4 hours at a temperature of 60°C. The dried powder is packed in a 1800°C-resistant mold with a size of 200mm×200mm×500mm. The mold is placed in a heating and pressurizing furnace filled with an oxidizing atmosphere. The heating rate of the furnace is 15°C / min, and the maximum temperature is 1200°C for 3 hours. . Pressurize at a speed of 0.2MPa, to a maximum pressure of 15MPa, and keep pressurized for 5 hours; cool down in the furnace, and after the heat preservation and pressure holding are ...

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Abstract

A preparation method of a MgO-doped ZnO sputtering target material comprises the following steps: weighing ZnO powder and MgO powder in proportion and putting the powders into a nylon ball-milling tank, adding anhydrous ethanol and agate ball, rapidly ball-milling by a planetary ball mill and obtaining mixed powder, and screening agate ball; drying anhydrous ethanol; filling a mould and heating and pressing in a high temperature furnace; and discharging and processing and slicing a target billet to obtain the target material. According to the invention, high-purity ZnO powder and MgO powder are mixed and hot-pressed to prepare the target material. The technology is simple, and cost is reduced. A luminescent material prepared by the use of the target material has uniform particles, good dispersity and excellent luminescent properties. In addition, concentration of Mg-doped ZnO is adjustable, so as to change bandwidth and wave length of green ray. The target material can be used in fields of light emitting diodes and lasers, etc. Practicality is greatly enhanced.

Description

technical field [0001] The invention relates to the general coating technology of IPC classification C23C vacuum evaporation method, sputtering method, ion implantation method or chemical vapor deposition method, belongs to the field of new materials, especially the preparation method of MgO-doped ZnO sputtering target material. Background technique [0002] ZnO is a widely studied direct bandgap semiconductor with a bandgap width of 3.37eV at room temperature. The growth of GaN requires high temperature conditions, difficult film growth, high cost and lack of matching substrate crystallization quality, which is difficult to improve ZnO compared with GaN. Wide selection range of substrate materials Low growth temperature and rich sources of ZnO Low price, non-toxic to the environment, good radiation resistance, excellent photoelectric properties, excellent materials for preparing optoelectronic devices, and widely used in the fields of transparent conduction and thin film tra...

Claims

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Application Information

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IPC IPC(8): C04B35/453C04B35/622C23C14/34
CPCC04B35/453C04B35/622C04B2235/3206C04B2235/656C04B2235/6583C04B2235/77C23C14/3414
Inventor 贾泽夏庄志杰诸斌顾宗慧
Owner GEMCH MATERIAL TECH SUZHOU
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