Catalyst for treating chemical industry organic wastewater

An organic waste water and catalyst technology, applied in physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, oxidized water/sewage treatment, etc. Dissolution and other problems, to achieve the effect of excellent performance and simple preparation process

Inactive Publication Date: 2017-02-15
JIANGSU JIHUA CHEMICAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the perspective of engineering application practice, the efficiency of this type of catalyst to catalyze the oxidant is not high, which leads to an increase in the amount of oxidant, which leads to an increase in cost; secondly, because the activated carbon catalyst itself contains calcium and magnesium ions, it will be in the process. Dissolution will produce precipitation in the subsequent alkaline operating environment, which will affect the effect of wastewater treatment; moreover, due to the production process of activated carbon catalysts, the active metal oxides loaded on it are easy to dissolve, affecting its service life, and the catalyst’s The strength is not ideal, and the wear is serious during the aeration process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Embodiment 1, a kind of catalyst for treating chemical industry organic wastewater, comprises the following substances in parts by mass: Al 2 o 3 is 45 parts, nickel oxide is 25 parts, manganese oxide is 8 parts, and lanthanum oxide is 2 parts; wherein, the Al 2 o 3 As a carrier, the nickel oxide, manganese oxide, and lanthanum oxide are supported.

[0016] The preparation method of the above-mentioned catalyst for treating chemical organic wastewater comprises the following steps:

[0017] 1) dissolving lanthanum nitrate crystals in distilled water to prepare a solution with a concentration of 1.2mol / L;

[0018] 2) After the lanthanum nitrate crystal is dissolved, add spherical Al 2 o 3 , left to stand for 12 hours to dry after stirring, and then roasted at 400 ° C for 5 hours to obtain the precursor of the catalyst;

[0019] 3) prepare the nickel nitrate solution of 4mol / L, then add manganese nitrate, make the concentration of manganese nitrate be 1.2mol / L;

[...

Embodiment 2

[0021] Embodiment 2, a catalyst for treating chemical industry organic wastewater, in parts by mass, includes the following substances: Al 2 o 3 is 70 parts, nickel oxide is 45 parts, manganese oxide is 18 parts, and lanthanum oxide is 10 parts; wherein, the Al 2 o 3 As a carrier, the nickel oxide, manganese oxide, and lanthanum oxide are supported.

[0022] The preparation method of the above-mentioned catalyst for treating chemical industry organic wastewater is the same as in Example 1.

Embodiment 3

[0023] Embodiment 3, a catalyst for treating chemical organic wastewater, in parts by mass, includes the following substances: Al 2 o 3 is 60 parts, nickel oxide is 35 parts, manganese oxide is 14 parts, and lanthanum oxide is 6 parts; wherein, the Al 2 o 3 As a carrier, the nickel oxide, manganese oxide, and lanthanum oxide are supported.

[0024] The preparation method of the above-mentioned catalyst for treating chemical industry organic wastewater is the same as in Example 1.

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Abstract

The present invention provides a catalyst for treating chemical industry organic wastewater. The catalyst comprises, by mass, 45-70 parts of Al2O3, 25-45 parts of nickel oxide, 8-18 parts of manganese oxide, and 2-10 parts of lanthanum oxide, wherein the Al2O3 is a carrier and supports the nickel oxide, the manganese oxide, and the lanthanum oxide. According to the present invention, the catalyst has excellent performances in the field of hardness, active component stability, service life and catalytic oxidation efficiency, the preparation process is simple, and the industrial production can be achieved; and the catalyst can be used in the fixed bed and the fluidized bed in the engineering, and provides good competitive strength in the treatment effect and the engineering application prospects compared to the traditional active carbon.

Description

technical field [0001] The invention relates to the field of chemical wastewater treatment, in particular to a catalyst for treating chemical organic wastewater. Background technique [0002] With the development of industrialization in our country, water resources are becoming more and more scarce, and more and more attention has been paid to the treatment and recycling of wastewater. The total amount of these wastewaters is huge and tends to increase year by year. If they are not treated before discharge, the high concentration of soluble inorganic salts and refractory toxic organic substances in the wastewater will cause serious damage to the natural ecological environment, such as soil, surface water, and groundwater. Cause destructive pollution, and ultimately affect the living and production water that is closely related to people. Usually, these high-concentration industrial wastewater that is difficult to degrade biochemically can hardly be treated with conventional...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/889C02F1/72
Inventor 屠国锋
Owner JIANGSU JIHUA CHEMICAL CO LTD
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