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Viscosity reduction type polycarboxylate superplasticizer used for high-strength concrete

A technology of viscous polycarboxylic acid and high-strength concrete, which is applied in the field of building admixtures, and can solve the problems that do not involve viscosity-reducing polycarboxylate water-reducing agent and the like

Active Publication Date: 2017-02-22
KZJ NEW MATERIALS GROUP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In practical engineering applications, synthesis and compounding are generally required, but none of the above technical solutions involves a viscosity-reducing polycarboxylate superplasticizer for high-strength concrete

Method used

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  • Viscosity reduction type polycarboxylate superplasticizer used for high-strength concrete

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preparation example Construction

[0028] Concrete preparation method comprises as follows:

[0029] (1) Weigh each raw material component in proportion.

[0030](2) Dissolving the first unsaturated monomer in deionized water to form solution A, and dissolving ascorbic acid in deionized water to form solution B.

[0031] (3) Dissolve 2-methallyl polyoxyethylene ether and hydrogen peroxide in deionized water, adjust the reaction temperature, add solution A and solution B dropwise according to a certain rate of addition, and add sodium hydroxide after the reaction Adjust the pH value to neutral to obtain the water-reducing PCE mother liquor.

[0032] The mass concentration of the viscosity-reducing PCE mother liquor is 45-55%. It is obtained by free radical solution polymerization from allyl polyoxyethylene ether and the second unsaturated monomer using a redox initiation system; the number-average molecular weight of its active ingredients 10000~20000, the structural formula is where R 4 -H or -CH 3 , M is...

Embodiment 1

[0043] First add 798.38kg of water into the 1000L reactor, and then add EVONIK SitrenAirVoid 6010.25kg, TAKEMOTO Chupol AFK-2 0.15kg, aminotrimethylene phosphonic acid 3.94kg, benzotriazole 0.05kg and Cathone 0.10kg, and stir for 30 minutes , then add water-reducing PCE mother liquor PCE-1 98.57kg, viscosity-reducing PCE mother liquor PCE-524.64kg and slump-preserving PCE mother liquor PCE-9 73.92kg, and continue stirring until it dissolves into a uniform solution with a mass concentration of 10 %, that is, the viscosity-reducing polycarboxylate water-reducer for high-strength concrete.

Embodiment 2

[0045] Add 798.86kg of water to the 1000L reactor first, then add 0.10kg of BASF MasterAir 303A, 0.2kg of TAKEMOTO ChupolAFK-2, 3.45kg of monoethanol diisopropanolamine, 0.10kg of carboxybenzotriazole, and 0.05kg of paraben kg, after stirring for 30min, add water-reducing PCE mother liquor PCE-2 123.28kg, viscosity-reducing PCE mother liquor PCE-624.66kg and slump-preserving PCE mother liquor PCE-10 49.31, and continue stirring until it dissolves into a uniform solution. The mass concentration is 10%, that is, the viscosity-reducing polycarboxylate water reducer for high-strength concrete.

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Abstract

The invention discloses a viscosity reduction type polycarboxylate superplasticizer used for high -strength concrete. The polycarboxylate superplasticizer is prepared from, by weight, 20.0-40.0 parts of water reduction type PCE mother liquor, 2.5-5.0 parts of viscosity reduction type PCE mother liquor, 2.5-15.0 parts of slump retaining type PCE mother liquor, 0.02-0.05 part of air entraining agent, 0.02-0.05 part of antifoaming agent, 0.5-0.8 part of thickening time control agent, 0.01-0.02 part of corrosion inhibitor, 0.01-0.02 part of antiseptic and proper amount of water. According to the viscosity reduction type polycarboxylate superplasticizer, three kinds of mother liquor of the water reduction type PCE, the viscosity reduction type PCE and the slump retaining type PCE are adopted, proper evacuation time required by the high-strength concrete can be obtained by adjusting the ratio of the three kinds of mother liquor according to practical conditions of raw materials such as binding material and aggregate, and viscosity of the high-strength concrete is controlled.

Description

technical field [0001] The invention belongs to the technical field of building admixtures, in particular to a viscosity-reducing polycarboxylate water reducer for high-strength concrete. Background technique [0002] With the development needs of modern buildings with large spans, high loads, super high-rises, and complex structures, high-strength concrete, as a new building material, has the advantages of high compressive strength, strong deformation resistance, high density, and low porosity. properties, are increasingly used. The compressive strength of high-strength concrete is high, which is 4 to 6 times that of ordinary concrete, so the section of the component can be reduced, the size of the column section can be reduced, the self-weight of the building can be reduced, and the economic benefit can be improved; high-strength steel and The stress is artificially controlled to improve the flexural rigidity and crack resistance of flexural members, so more and more high...

Claims

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Application Information

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IPC IPC(8): C04B24/26C08F283/06C08F220/06C08F220/14C08F220/18C08F222/06C08F220/58C08F220/28C04B103/30
CPCC04B40/0039C08F283/065C04B2103/302C04B24/003C04B24/16C04B24/165C04B24/2694C04B2103/304C04B2103/50C04B24/122C04B24/129C04B24/045C08F220/585C08F220/1802C08F220/281C08F220/58
Inventor 方云辉柯余良张小芳李格丽林倩林祥毅林添兴
Owner KZJ NEW MATERIALS GROUP CO LTD
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