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High strength epoxy resin cis-polybutadiene composite material for hydraulic hammer high pressure oil pipes and preparation method thereof

A hydraulic breaker and epoxy resin technology, which is applied in the field of rubber materials, can solve the problems of the large difference in solubility parameters between epoxy resin and cis-butadiene rubber, phase separation phenomenon, and roughness inequality, so as to improve flexibility and improve aging resistance. , the effect of improving light resistance

Inactive Publication Date: 2017-03-22
MAANSHAN JIECHUANG PLASTIC TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Due to the large difference in solubility parameters between epoxy resin and butadiene rubber, the compatibility is poor, and the phase separation phenomenon is obvious, the addition of epoxy resin makes the fracture interface of the sample rough and uneven, and more holes are produced on the surface of the sample.

Method used

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Examples

Experimental program
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Embodiment Construction

[0014] An epoxy resin butadiene rubber composite material for high-strength hydraulic breaker high-pressure oil pipes, made of the following raw materials in parts by weight (kg): butadiene rubber 100, 4,4'-diaminodiphenylmethane 11, N- Cyclohexyl-2-benzothiazole sulfenamide 1.5, sulfur 2.5, stearic acid 2, zinc oxide 5, E-44 epoxy resin 40, butadiene 15, hydrogenated gasoline amount, nickel naphthenate 0.02, three Isobutyl aluminum 0.1, high aromatic oil 7, nano antimony tin oxide 2, methyl methacrylate 2, nano boron fiber 2.3, silane coupling agent kh-550 0.7, tetrapod zinc oxide whisker 0.8.

[0015] The preparation method of the epoxy resin butadiene rubber composite material for the high-strength hydraulic breaker high-pressure oil pipe comprises the following steps:

[0016] (1) Mix nano-antimony tin oxide and methyl methacrylate evenly, heat to 65°C, then mix evenly with E-44 epoxy resin, and oxidize nano-boron fibers, silane coupling agent kh-550, and tetrapods The zi...

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Abstract

The invention discloses a high strength epoxy resin cis-polybutadiene composite material for hydraulic hammer high pressure oil pipes. The composite material is prepared from the following raw materials by weight: 100-110 parts of cis-polybutadiene, 11-12 parts of 4, 4'-diaminodiphenylmethane, 1.5-1.7 parts of N-cyclohexyl-2-benzothiazole sulfonamide, 2.5-2.8 parts of sulfur, 2-2.3 parts of stearic acid, 5-5.3 parts of zinc oxide, 40-42 parts of E-44 epoxy resin, 2-2.3 parts of nano tin antimony oxide, 2-2.5 parts of methyl methacrylate, 2.3-2.5 parts of nano boron fiber, 0.7-0.9 part of a silane coupling agent kh-550, and 0.8-1.2 parts of tetrapod-like zinc oxide whisker. Through use of nano boron fiber, the silane coupling agent kh-550 and tetrapod-like zinc oxide whisker, the tensile strength, tear strength, abrasion resistance and heat resistance of the rubber are improved.

Description

technical field [0001] The invention relates to the technical field of rubber materials, in particular to an epoxy resin butadiene rubber composite material for high-strength hydraulic breaker high-pressure oil pipes and a preparation method thereof. Background technique [0002] With the development of modern science and technology, people's requirements for the performance of polymer materials are becoming more and more diverse. It is often difficult for a single homopolymer and copolymer to meet various requirements. People begin to focus on using existing polymer materials to prepare them by blending methods. Multiphase composite materials with new functions can meet the new requirements of polymer materials in various industrial applications. In recent years, it has become a new field in polymer science to blend different types of polymers by physical or chemical methods to improve the properties of the original polymers or to form polymer blending systems with new prop...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/00C08L51/08C08K13/06C08K9/06C08K7/06C08K7/08C08K3/22
CPCC08L9/00C08K2201/011C08L2201/08C08L2203/18
Inventor 吴传兴
Owner MAANSHAN JIECHUANG PLASTIC TECH CO LTD