Colored resin composition for color filter, color filter, and display device
A resin composition, color filter technology, applied in the direction of filter, optomechanical equipment, photosensitive materials for optomechanical equipment, etc., can solve the problem that color filter is difficult to achieve high brightness requirements, etc., Achieve the effects of superior stability over time, superior solvent resistance, and superior sensitivity
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[0447] Hereinafter, the present invention will be specifically described with reference to examples. However, the present invention is not limited to these descriptions.
Synthetic example 1
[0448] (Synthesis Example 1: Synthesis of Intermediate 1)
[0449] 15.2 g (60 mmol) of 1-iodonaphthalene produced by Wako Pure Chemical Industries, Ltd., 4.63 g (30 mmol) of norbornanediamine (NBDA) (CAS No.56602-77-8) produced by Mitsui Chemicals Co., Ltd., tert-butyl 8.07 g (84 mmol) of sodium oxide, 0.09 g (0.2 mmol) of 2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl manufactured by Aldrich, 0.021 g (0.1 mmol) of palladium acetate manufactured by Wako Pure Chemical Industries, Ltd. mmol) was dispersed in 30 mL of xylene, and reacted at 130-135°C for 48 hours. After the reaction, cool to room temperature and add water for extraction. Then, it was dried over magnesium sulfate and concentrated to obtain 18.5 g of an intermediate represented by the following chemical formula (1) (yield: 70%).
[0450] The obtained compound was confirmed to be the target compound by the analysis results described below.
[0451] MS (ESI) (m / z): 407 (M+H)
[0452] Elemental analysis value: CH...
Synthetic example 2
[0456] (Synthesis Example 2: Synthesis of Intermediate 2)
[0457] Put 8.46 g (20.8 mmol) of intermediate 1, 13.5 g (41.6 mmol) of 4,4′-bis(dimethylamino)benzophenone manufactured by Tokyo Chemical Industry Co., Ltd., and 60 mL of toluene, and stir at 45-50°C . 6.38 g (51.5 mmol) of phosphorus oxychloride manufactured by Wako Pure Chemical Industries, Ltd. was added dropwise, refluxed for 2 hours and cooled. After the reaction was over, toluene was decanted. Add 40 mL of chloroform, 40 mL of water, and concentrated hydrochloric acid to dissolve the resinous precipitate, and separate the chloroform layer. The chloroform layer was washed with water, dried over magnesium sulfate, and concentrated. 65 mL of ethyl acetate was added to the concentrate and refluxed. After cooling, the precipitate was filtered to obtain 15.9 g (70% yield) of an intermediate (BB7-Nb-dimer) represented by the following chemical formula (2).
[0458] The obtained compound was confirmed to be the tar...
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