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Anti-aging and high flame retardant ABS composite material and preparation method thereof

A composite material and high flame-retardant technology, which is applied in the field of anti-aging high flame-retardant ABS composite materials, can solve the problems of poor flame-retardant performance and anti-aging performance, and achieve good smoke absorption and good flame-retardant performance , cost reduction effect

Inactive Publication Date: 2017-05-03
WENZHOU CHUYING TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

ABS resin can be used in the interior and exterior of the car, small parts such as steering wheel, oil guide pipe, handle and button, etc. The exterior of the car includes front radiator grille and lampshade, etc. The current ABS resin has poor flame retardancy and anti-aging performance. The present invention aims to solve this technical problem

Method used

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  • Anti-aging and high flame retardant ABS composite material and preparation method thereof
  • Anti-aging and high flame retardant ABS composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0033] Anti-aging high flame-retardant ABS composite material, the anti-aging high flame-retardant ABS composite material is processed from the following raw materials in parts by weight: 80 parts of ABS resin, 40 parts of PC resin, 5 parts of EPDM resin, 6 parts of antioxidant, compound 8 parts of flame retardant, said composite flame retardant is ammonium polyphosphate-diatomite / magnetically ordered mesoporous nickel ferrite composite flame retardant prepared by in-situ polymerization, and the preparation method of composite flame retardant is as follows: Pour 85% concentrated phosphoric acid into the reactor, heat and stir, add appropriate amount of urea when the temperature rises to 60°C, add appropriate amount of diatomite and magnetically ordered mesoporous nickel ferrite powder when the temperature rises to 125°C, and stir for 10 minutes , and then the product was solidified at 280°C for 2 hours, and a composite flame retardant was obtained after being pulverized by a na...

Embodiment 2

[0036] Anti-aging high flame-retardant ABS composite material, the anti-aging high flame-retardant ABS composite material is processed from the following raw materials in parts by weight: 100 parts of ABS resin, 60 parts of PC resin, 15 parts of EPDM resin, 10 parts of antioxidant, compound 12 parts of flame retardant, the composite flame retardant is the ammonium polyphosphate-diatomite / magnetically ordered mesoporous nickel ferrite composite flame retardant prepared by in-situ polymerization, and the preparation method of the composite flame retardant is as follows: Pour 85% concentrated phosphoric acid into the reactor, heat and stir, add appropriate amount of urea when the temperature rises to 80°C, add appropriate amount of diatomite and magnetically ordered mesoporous nickel ferrite powder when the temperature rises to 120°C, and stir for 20 minutes , and then solidify the product at 320°C for 1 hour, and obtain a composite flame retardant after being pulverized by a nano...

Embodiment 3

[0039]Anti-aging high flame-retardant ABS composite material, the anti-aging high flame-retardant ABS composite material is processed from the following raw materials in parts by weight: 90 parts of ABS resin, 50 parts of PC resin, 8 parts of EPDM resin, 8 parts of antioxidant, compound 8 parts of flame retardant, said composite flame retardant is ammonium polyphosphate-diatomite / magnetically ordered mesoporous nickel ferrite composite flame retardant prepared by in-situ polymerization, and the preparation method of composite flame retardant is as follows: Pour 85% concentrated phosphoric acid into the reactor, heat and stir, add appropriate amount of urea when the temperature rises to 70°C, add appropriate amount of diatomite and magnetically ordered mesoporous nickel ferrite powder when the temperature rises to 122°C, and stir for 15 minutes , and then solidify the product at 300°C for 1.5h, and pulverize it with a nano pulverizer to obtain a composite flame retardant. The ma...

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PUM

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Abstract

The invention relates to an anti-aging and high flame retardant ABS composite material and a preparation method thereof. The anti-aging and high flame retardant ABS composite material is prepared from 80 to 100 parts by weight of ABS resin, 40 to 60 parts by weight of PC resin, 5 to 15 parts by weight of EPDM resin, 6 to 10 parts by weight of an antioxidant and 8 to 12 parts by weight of a compound flame retardant. The preparation method comprises pouring concentrated phosphoric acid having a concentration of 85% into a reactor, carrying out heating stirring, adding an appropriate amount of urea into the mixture when the temperature rises to 60 to 80 DEG C, adding an appropriate amount of diatomite and magnetic ordered mesoporous nickel ferrite powder when the temperature rises to 120 to 125 DEG C, carrying out a stirring reaction process for 10 to 20min, curing the product at a temperature of 280 to 320 DEG C for 1 to 2h, and crushing the product through a nano-crusher to obtain the anti-aging and high flame retardant ABS composite material. The preparation method utilizes phosphoric acid and urea as main raw materials, diatomite and magnetic ordered mesoporous nickel ferrite as carriers and an in-situ polymerization method to prepare the ammonium polyphosphate-diatomite / magnetic ordered mesoporous nickel ferrite composite flame retardant and can give full play to synergistic flame retardant effects of ammonium polyphosphate and silicon, iron and nickel so that the ABS composite material has good flame retardant properties.

Description

technical field [0001] The invention relates to an anti-aging high flame-retardant ABS composite material and a preparation method thereof. Background technique [0002] ABS resin (acrylonitrile-styrene-butadiene copolymer) is a thermoplastic polymer material structure with high strength, good toughness and easy processing. [0003] ABS is a general-purpose thermoplastic engineering plastic developed in the 1940s. It is a plastic variety with excellent comprehensive mechanical properties. It not only has good rigidity, hardness and processing fluidity, but also has high toughness. It can be injected, extruded or heated. forming. [0004] Most of the auto parts are processed by injection molding method, the advantages of ABS resin are impact resistance, sound insulation, scratch resistance, better heat resistance, more beautiful than PP, especially suitable for transverse impact resistance and use Temperature-critical parts. ABS resin is the third largest resin used in aut...

Claims

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Application Information

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IPC IPC(8): C08L55/02C08L69/00C08L23/16C08K13/04C08K7/24C08K3/24C08K3/34C08K3/32C08K5/21C08K5/134
CPCC08L55/02C08K2201/01C08L2201/02C08L2205/03C08L69/00C08L23/16C08K13/04C08K7/24C08K3/24C08K3/346C08K2003/323C08K5/21C08K5/1345
Inventor 蒲昀博
Owner WENZHOU CHUYING TECH CO LTD
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