Preparation method of bismuth zirconate microcrystal ceramic glaze with photocatalytic function

A technology of microcrystalline ceramics and bismuth zirconate, applied in the field of ceramic glaze, can solve the problems of poor bonding between photocatalytic film and substrate, uneven distribution of photocatalyst glaze, affecting the aesthetics of ceramics, etc. Good surface decoration effect, good opacity effect

Active Publication Date: 2017-05-10
SHAANXI UNIV OF SCI & TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among the above methods, the former has the disadvantages of poor bonding between the photocatalytic film and the substrate, and easy shedding and loss.
The latter has the shortcomings of uneven distribution in the photocatalyst glaze and the "rainbow effect", which directly affects the aesthetics of ceramics

Method used

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  • Preparation method of bismuth zirconate microcrystal ceramic glaze with photocatalytic function
  • Preparation method of bismuth zirconate microcrystal ceramic glaze with photocatalytic function
  • Preparation method of bismuth zirconate microcrystal ceramic glaze with photocatalytic function

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, and lithium carbonate are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=57:4:22:4:7:4:3.

[0033] 2) Dry mix and grind the above-mentioned powders, pass through a 60-mesh sieve to obtain the mixture, put it into a crucible, put it into an electric furnace and keep it at 1270°C for 20 minutes, take it out and pour it into water to quench to make a frit. Take out the frit from the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 3 hours, and dry for later use. This powder is denoted as A material.

[0034] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And Suzhou soil is A material according to the mass ratio: Bi 2 o 3 : Suzhou soil = 82:7:7 ratio for batching,...

Embodiment 2

[0041] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, and lithium carbonate are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=58:5:23:3:6:3:2.

[0042] 2) Dry mix and grind the above-mentioned powders, pass through a 60-mesh sieve to obtain the mixture, put it into a crucible, put it into an electric furnace and keep it warm at 1280°C for 30 minutes, take it out and pour it into water to quench to make a frit. Take the frit out of the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 4 hours, and dry for later use. This powder is denoted as A material.

[0043] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And Suzhou soil is A material according to the mass ratio: Bi 2 o 3 : Suzhou soil = 84:6.5:6 ratio for batc...

Embodiment 3

[0047] 1) First, quartz, potassium feldspar, albite, borax, Bi 2 o 3 , Suzhou soil, and lithium carbonate are prepared according to the following mass chemical composition ratios. SiO 2 :Al 2 o 3 :B 2 o 3 : Bi 2 o 3 : Li 2 O: Na 2 O:K 2 O=59:6:24:2:5:2:1.

[0048] 2) Dry mix and grind the above-mentioned powders, pass through a 40-mesh sieve to obtain the mixture, put it into a crucible, put it in an electric furnace at 1290° C. for 40 minutes, take it out and pour it into water to quench to obtain a frit. Take out the frit from the water, put it into a ball mill after drying, and grind it finely. The mass ratio of control material (frit): ball: water is 1:1:0.8, pass through a 250-mesh sieve after grinding for 3 hours, and dry for later use. This powder is denoted as A material.

[0049] 3) Combine the above material A and Bi 2 o 3 , ZrO 2 And Suzhou soil is A material according to the mass ratio: Bi 2 o 3 : Suzhou soil = 86:6:5 ratio for batching, and Bi 2...

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Abstract

The invention relates to a preparation method of bismuth zirconate microcrystal ceramic glaze with a photocatalytic function. The preparation method includes: blending quartz, potassium feldspar, albite, borax, Bi2O3, Suzhou kaolin and lithium carbonate according to the mass ratio, performing heat preservation at 1270-1290 DEG C for 20-40 minutes, taking out, pouring into water for quenching, and grinding to obtain a material A; blending the material A, the Bi2O3, ZrO2 and the Suzhou kaolin according to the mass ratio to obtain a material B; adding the material B and a dispersing agent into water, and evenly stirring to prepare glaze slip; glazing the surface of ceramic with the glaze slip, and sintering to obtain the bismuth zirconate microcrystal ceramic glaze with the photocatalytic function. The preparation method has the advantages that the ceramic glaze is prepared by the sintering process, coating is not needed, the prepared functional glaze can be tightly combined with a ceramic matrix, the photocatalyst generated during the sintering of the Bi2O3 and the ZrO2 is evenly distributed in the glaze, and the 'rainbow effect' which affects glaze attractiveness is not generated.

Description

technical field [0001] The invention belongs to the technical field of ceramic glazes, in particular to a method for preparing bismuth zirconate microcrystalline ceramic glazes with photocatalytic function, which can be applied to the surface of building ceramics or daily-use ceramics. Background technique [0002] Building sanitary ceramics and daily-use ceramics are materials that are widely used in people's daily life and can be seen everywhere. It is understood that the output of my country's architectural ceramics and daily-use ceramics has ranked first in the world for more than ten consecutive years. However, in recent years, with the improvement of people's living standards, the health requirements and environmental protection requirements for ceramic products have also gradually increased. Ordinary ceramics can no longer meet people's needs, and new ceramics with specific functions have gradually entered people's field of vision. The difference between this type o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/00C04B41/86B01J23/18
CPCB01J23/18B01J35/004C03C8/00C04B41/5022C04B41/86
Inventor 曹丽云罗艺佳黄剑锋李嘉胤孔新刚刘一军
Owner SHAANXI UNIV OF SCI & TECH
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