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52results about How to "With photocatalytic function" patented technology

Micro-droplet self-transported wedged non-uniform wetting surface and preparation method thereof

The invention relates to a micro-droplet self-transported wedged non-uniform ultra-wetting surface and a preparation method thereof. A super-hydrophobic surface containing titanium dioxide or zinc oxide nano-materials is constructed on the surface of a substrate by using a coating spraying or hydrothermal oxidation method, and a template method is used, ultraviolet light catalysis or oxygen plasma region selective modification is carried out to obtain a wedged super-hydrophilic region, the template method also can be used to obtain a wedged covering region, and then the coating spraying or hydrothermal oxidation method can be used again, and region selection is carried out to construct the super-hydrophobic surface, so as to obtain the wedged non-uniform ultra-wetting surface, finally, the wedged region is further modified by using polyvinyl alcohol again to obtain a bulge of the smooth super-hydrophilic wedged region, so that micro-droplets can be transported spontaneously in the wedged region without external force driving. By selecting the region of a template, the wedged super-hydrophilic region arranged in an array can be obtained on the super-hydrophobic surface, and multiple micro-droplets are in self-propelled movement by one time, so that the micro-droplet self-transported wedged non-uniform ultra-wetting surface has broad application prospects in fields of condensation heat transfer enhancement or evaporation heat transfer, fog catchment, microfluid and the like.
Owner:SOUTHEAST UNIV

Preparation method of PAN-based oil-water separation microporous membrane with photocatalysis function

The invention discloses a preparation method of a PAN-based oil-water separation microporous membrane with a photocatalysis function. The preparation method comprises the following steps: firstly, introducing shell-layer SiO2 nanoparticles onto the outer surface of TiO2 by adopting a sol-gel method to realize coating of nanometer TiO2 with a photocatalysis function so as to obtain a SiO2@TiO2 additive, thereby isolating direct contact between a base membrane and photocatalysis particles and laying a foundation for migration of the photocatalysis particles to the surface of the membrane in thenext step; then blending SiO2@TiO2 and P(AN-MA) to prepare a membrane casting solution; curing the membrane casting solution containing the SiO2@TiO2 additive by using a TIPS method so as to form a membrane; then, subjecting the cured membrane to a hydrolysis reaction so as to convert cyano groups on the surface of the membrane into hydrophilic carboxyl groups; and dissolving the additive shell-layer SiO2, and allowing TiO2 in the additive to break away from constraint and migrate to the surface of the membrane so as to achieve the purpose of efficiently utilizing the photocatalysis particleswithout damaging the original performance of the base membrane, thereby obtaining the PAN-based microporous membrane with an oil-water separation function and photocatalytic degradation performance. The method has the advantages of simple process, high efficiency, no pollution and no influence on the permeability of the base membrane.
Owner:TIANJIN POLYTECHNIC UNIV

Preparation method of yttrium zirconate ceramic glaze material having photocatalytic function

The invention relates to a preparation method of a yttrium zirconate ceramic glaze material having a photocatalytic function. The preparation method comprises the following steps: preparing quartz, potash feldspar, albite, borax, Y2O3, Suzhou clay and lithium carbonate, keeping the temperature at 1270-1290 DEG C for 20-40 minutes, taking out, pouring into water, quenching to prepare a fusion cake, and grinding the fusion cake to obtain a material A; preparing the material A, Y2O3, ZrO2 and Suzhou clay, and grinding to obtain a material B; adding the material B and dispersing agent into water, and uniformly stirring and mixing to prepare a glaze slip; and applying the glaze slip to the surface of ceramics in a glaze spray manner, and firing to obtain the yttrium zirconate ceramic glaze material having a photocatalytic function. According to the invention, the ceramic glaze is prepared through a firing process and does not need coating, so that the prepared functional ceramic glaze material can be tightly combined with a ceramic matrix; and the photocatalyst yttrium zirconate generated in the sintering process of Y2O3 and ZrO2 is uniformly distributed in the glaze material, thereby avoiding influencing the aesthetic property of the glaze material due to a rainbow effect.
Owner:广西艾陶新型材料科技有限公司

Photocatalytic negative ion ceramic tile containing modified porous material and preparation process of ceramic tile

PendingCN112321270AEfficient harmful gas purification efficiencyWith photocatalytic functionCeramic materials productionClaywaresNano zinc oxidePhoto catalysis
The invention relates to the technical field of ceramics and functional decorative materials, in particular to a photocatalytic negative ion ceramic tile containing a modified porous material and a preparation process of the ceramic tile. The ceramic tile comprises a ceramic tile blank and cover glaze, raw materials of the cover glaze comprise a composite porous photocatalytic suspension and a base material, wherein the composite porous photocatalytic suspension accounts for 40-50 wt% of the weight of the base material, the composite porous photocatalytic suspension is prepared from the following raw materials: a porous material, elbaite, nano magnesium oxide, bismuth vanadate, nano zinc oxide and calcium oxide, the porous material is prepared from zeolite and diatomite, and the particle sizes of the elbaite, the nano magnesium oxide, the bismuth vanadate, the nano zinc oxide and the calcium oxide are all smaller than the pore diameters of micropores of the porous material. The prepared photocatalytic negative ion ceramic tile cover glaze contains a porous material, micropores of the porous material can absorb harmful gas in air, and harmful gas is purified through negative ions, photocatalysis, far infrared rays and other materials.
Owner:FOSHAN DONGPENG CERAMIC +2

Preparation method of orange-yellow photonic crystal structure color thin film with photo-catalytic effect

The invention discloses a preparation method of an orange-yellow photonic crystal structure color thin film with a photo-catalytic effect. The method comprises the following steps: firstly mixing SiO2 microsphere powder with particle diameter of 252+/-5 nm and polyvinylpyrrolidone and then adding water to prepare PVP (Polyvinyl Pyrrolidone)-modified SiO2 microspheres; then adding into absolute ethyl alcohol to perform ultrasonic treatment to obtain emulsion containing SiO2 microspheres; then preparing mixed solution of lithium hydroxide-ethanol and zinc acetate-ethanol; dropwise adding the emulsion containing SiO2 microspheres into the mixed solution, reacting and then filtering, washing, centrifuging, drying and thermally treating precipitate to prepare the SiO2@ZnO core-shell structure microspheres with the photo-catalytic effect; next adding ethanol into the SiO2@ZnO core-shell structure microspheres to perform ultrasonic dispersion to prepare emulsion; finally vertically inserting a glass substrate into the emulsion by using a vertical deposition method to generate the orange-yellow photonic crystal structure color thin film with the photo-catalytic effect. The method is simple and easy, causes no pollution to environment, can realize large-scale industrial production and has broad application prospect.
Owner:SHAANXI UNIV OF SCI & TECH

Oil-based rock debris cement paste and preparation method thereof

The invention discloses oil-based rock debris cement paste which comprises the following raw materials in parts by weight: 90-100 parts of cement, 10-15 parts of oil-based rock debris, 30-40 parts of metal powder, 1-3 parts of an anti-freezing agent, 1-3 parts of an antibacterial agent, 1-3 parts of a defoaming agent, 15-35 parts of gypsum powder and 30-35 parts of water. The preparation method of the oil-based rock debris cement slurry comprises the following steps: weighing the raw materials, crushing and sieving the raw materials, uniformly mixing the raw materials, calcining and cooling the raw materials, and stirring the raw materials to prepare slurry. The main component of the oil-based rock debris subjected to thermal desorption treatment is a siliceous material, so that the cement component is reduced, the cost is reduced, and the waste utilization rate is high; wherein the metal powder are slags, so that the compression resistance of the cement is enhanced; due to the anti-freezing agent, the cement paste is good in use state under the low-temperature condition; moreover, the antibacterial agent endows the cement with a good antibacterial effect, wherein the nano titanium dioxide has a photocatalytic function, can generate hydroxyl radicals with high oxidability in water after absorbing light, and plays a role in sterilization.
Owner:SICHUAN XINGCHUANCHENG CEMENT CO LTD

Preparation method of ianthinus photonic crystal structure colored film with photocatalysis effects

The invention discloses a preparation method of an ianthinus photonic crystal structure colored film with photocatalysis effects. The preparation method comprises 1, blending SiO2 microsphere powder with particle sizes of 180+ / -5nm and polyvinylpyrrolidone, adding water into the mixture and preparing PVP-modified SiO2 microspheres, 2, adding the PVP-modified SiO2 microspheres into anhydrous ethanol and carrying out ultrasonic treatment to obtain a SiO2 microsphere-containing emulsion, 3, preparing lithium hydroxide-ethanol and zinc acetate-ethanol mixed solutions, dropwisely adding the SiO2 microsphere-containing emulsion into the mixed solution, carrying out a reaction process, filtering the reaction product, carrying out washing, centrifugation and drying on the precipitates, and carrying out heat treatment to obtain SiO2@ZnO core-shell structure microspheres with photocatalysis functions, 4, adding ethanol into the SiO2@ZnO core-shell structure microspheres, and carrying out ultrasonic dispersion to obtain an emulsion, and 5, vertically inserting a glass substrate into the emulsion by a vertical sedimentation method so that the ianthinus photonic crystal structure colored film with photocatalysis effects is produced. The preparation method has the advantages of simple and easy processes, no pollution on the environment, large scale industrial production and wide application prospect.
Owner:SHAANXI UNIV OF SCI & TECH

Usemethod of nanometer titanium dioxide on ceramics, leather, cloth and furniture

The invention discloses a use method of nanometer titanium dioxide on ceramics, leather, cloth and furniture, and relates to the technical field of materials. The use method comprises: S1, adding a Ti<4+> salt solution into hydrogen peroxide, and carrying out a flocculation reaction on the Ti <4+> salt solution and the hydrogen peroxide to prepare a titanium peroxide complex; S2, adding a crystalform control agent into the titanium peroxide complex, carrying out a reaction on the crystal form control agent and the titanium peroxide complex, heating to 300-500 DEG C, and keeping for 5-10 hto obtain a titanium oxide blocky gel; and S6, adding a silane coupling agent into the nanometer titanium dioxide sol, and adding the mixed solution into a water-based glass baking varnish resin accordingto the adding amount of 0.5-1.5% of the nanometer titanium dioxide. According to the invention, the resin coating material is mixed and processed into glass, furniture and ceramic finished products,so that the glass, furniture and ceramic finished products have photocatalysis function, can catalyze and photolyze various organic matters such as formaldehyde and the like and part of inorganic matters attached to the surface of objects, have a self-cleaning function, improve automatic cleaning effect and are convenient to clean.
Owner:广东绿驰科技有限公司
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