The invention relates to the field of coatings, and specifically relates to an anti-pollution flashover coating for an electrical device and a preparation method thereof. The coating is hydrophobic, insulated and self-cleaning coating developed based on pollution flashover occurring principle and is applicable to the surface treatment of an outdoor electrical device, in particular an insulator. The anti-pollution flashover coating comprises 5-20 parts of organic silicon resin, 2-12 parts of fluoridized titanium dioxide powder, 1-10 parts of fumed silica powder, 0.1-0.5 part of silane couplingagent, 0.2-3 parts of auxiliary, 0.3-2 parts of carbon black, 50-80 parts of mixed solvent, and 8-15 parts of a curing agent. The anti-pollution flashover coating has the beneficial effects of being hydrophobic, anti-pollution, self-cleaning, and insulated, and is applicable to an outer coating layer of the outdoor electrical device; nano silica and the silane coupling agent are compounded, so that the superficiality of the coating layer is greatly reduced, and the hydrophobic and oleophobic performances of the coating layer are improved; nano fluoridized titanium dioxide is added, so that thecoating is capable of self-cleaning; the coating has a good adhering performance relative to a base material, and is high in weather resistance, resistant to high- and low-temperature, resistance toillumination, and resistance to radiativity.