The invention belongs to the technical field of
lithium battery electrolytes, and discloses a
microemulsion gel
electrolyte, a preparation method thereof and a
solid-state
lithium battery, the
microemulsion gel
electrolyte is composed of a continuous phase (a
solvent, a double
lithium salt solute, a
monomer and an initiator), an insoluble phase (a
perfluorinated compound) and an amphiphilic phase (a
fluorine-containing
ether compound), the three phases form the
microemulsion gel
electrolyte with a three-dimensional
network structure through microemulsion and thermal
polymerization, the process is simple, and large-scale production is easy to realize. According to the electrolyte,
fluorine-containing micelles are driven by liquid-liquid interfacial tension to spontaneously migrate to an
electrode interface to form a LiF-rich protective layer, and meanwhile, monomers are initiated to directionally polymerize to construct a three-dimensional
network structure. Through the synergistic effect, a stable interface under the ultralow electrolyte dosage (0.9 g / Ah) is achieved, the lithium-rich
manganese-based positive
electrode is matched to assemble a lithium-free negative
electrode battery, the
energy density reaches up to 698.20 Wh / kg, meanwhile, excellent safety performance is shown, and fire and
smoke do not occur in an
acupuncture test.