Lithium battery electrolyte and preparing method thereof
An electrolyte and lithium battery technology, applied in the field of fine chemicals, to achieve the effects of high electrical conductivity, high electrochemical stability and wide electrochemical window
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Embodiment 1
[0012] Pass the propylene carbonate through a molecular sieve dehydration device to remove the moisture contained in the propylene carbonate, and then add lithium hexafluorophosphate and N,N-dimethyl-N-ethyl-N-2-methoxyethylammonium bis(trifluoro Methylamide) imide salt is dissolved in propylene carbonate to obtain lithium hexafluorophosphate content is 1mol / L, DEMETf 2 An electrolyte with a N content of 0.1mol / L. After testing, at 25°C, 1mol / L lithium hexafluorophosphate and 0.1mol / L DEMETf 2 The conductivity of N in propylene carbonate is 12.70mS·cm -1 , composed of lithium hexafluorophosphate and DEMETf 2 The electrolyte composed of N in propylene carbonate solution can ensure the stable cycle of the capacitor under the voltage of 3.5V.
Embodiment 2
[0014] Pass the mixed solvent composed of propylene carbonate, ethylene carbonate and γ-butyl lactone in a volume ratio of 2:1:1 through a molecular sieve dehydration device to remove the water contained in the mixed solvent, and then lithium hexafluorophosphate and N, N-di Methyl-N-ethyl-N-2-methoxyethylammonium bis(trifluoromethylamide) imide salt is dissolved in mixed solvent to obtain lithium hexafluorophosphate content is 1mol / L, DEMETf 2 An electrolyte with a N content of 0.5mol / L. After testing, at 25°C, 1mol / L lithium hexafluorophosphate and 0.5mol / L DEMETf 2 The conductivity of N in the mixed solvent is 12.90mS·cm -1 , the above-mentioned electrolyte can guarantee the stable circulation of the capacitor under the voltage of 3.5V.
Embodiment 3
[0016] A mixed solvent composed of ethylene carbonate, sulfolane, 3-methylsulfolane and acetonitrile in a volume ratio of 3:2:1:1 is passed through a molecular sieve dehydration device to remove the moisture contained in the mixed solvent, and then lithium hexafluorophosphate and N,N- Dimethyl-N-ethyl-N-2-methoxyethylammonium bis(trifluoromethylamide) imide salt is dissolved in mixed solvent to obtain lithium hexafluorophosphate content is 1mol / L, DEMETf 2 An electrolyte with a N content of 1mol / L. After testing, it can be obtained that at 25°C, 1mol / L lithium hexafluorophosphate and 1mol / L DEMETf 2 The conductivity of N in the mixed solvent is 13.00mS·cm -1 , the above-mentioned electrolyte can guarantee the stable circulation of the capacitor under the voltage of 3.5V.
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