Catalyst for directly dehydrogenating propane to prepare propylene as well as preparation and application of catalyst
A catalyst and dehydrogenation technology, applied in molecular sieve catalysts, physical/chemical process catalysts, hydrocarbons, etc., can solve the problem of easy coking of catalysts, and achieve carbon deposition inhibition, good propylene activity and propylene selectivity, and less coking. Effect
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[0039] Example 1
[0040] Preparation of molecular sieves with nano-flake MFI structure: NaOH, aluminum sulfate, water glass, template C 22-6-6 Br 2 , H 2 SO 4 And distilled water to 30Na 2 O:1Al 2 O 3 :100SiO 2 :8C 22-6-6 Br 2 :18H 2 SO 4 :4000H 2 The molar ratio of O (where "Na 2 The amount of O" refers to NaOH and Na 2 O) Stir and mix to prepare molecular sieve gel. The gel was placed in an autoclave equipped with a polytetrafluoroethylene inner layer and crystallized at 140-160°C for 120 hours. After the crystallization reaction is completed, the product is washed with distilled water, dried at 120°C, and then calcined at 550°C for 6 hours to obtain a nano-flaky MFI molecular sieve.
[0041] Catalyst preparation: Dissolve 0.082g chloroplatinic acid, 0.1753g magnesium nitrate and 0.2730g zinc nitrate in 50mL water to prepare a mixed solution, put 6g of the above-mentioned nanoflake MFI molecular sieve into it and soak in it for 12h, dry at 120℃, and then at 500℃ It is calcined ...
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[0044] Example 2
[0045] Preparation of molecular sieve with nano-flakes MFI structure: NaOH, aluminum sulfate, white carbon black, template C 18-6-6 Br 2 , H 2 SO 4 And distilled water to 28Na 2 O:1Al 2 O 3 :300SiO 2 :8C 18-6-6 Br 2 :18H 2 SO 4 :4000H 2 The molar ratio of O is stirred and mixed to prepare a molecular sieve gel. The gel was placed in an autoclave equipped with a polytetrafluoroethylene inner layer and crystallized at 140-160°C for 120 hours. After the crystallization reaction is completed, the product is washed with distilled water, dried at 120°C, and then calcined at 550°C for 12 hours to obtain a nano-flaky MFI molecular sieve.
[0046] Catalyst preparation: Dissolve 0.080g chloroplatinic acid, 0.1351g calcium nitrate and 0.2730g zinc nitrate in 50mL water to prepare a mixed solution, put 6g of the above-mentioned nanoflake MFI molecular sieve into it and soak it for 12h, dry at 120℃, and then at 500℃ After calcination for 12 hours, a molecular sieve of Pt-Zn-...
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[0049] Example 3
[0050] Preparation of molecular sieves with nano-flake MFI structure: NaOH, aluminum sulfate, silica sol, template C 16-6-3 Br 2 , H 2 SO 4 And distilled water to 26Na 2 O:1Al 2 O 3 :500SiO 2 :8C 16-6-3 Br 2 :18H 2 SO 4 :4000H 2 The molar ratio of O is stirred and mixed to prepare a molecular sieve gel. The gel was placed in an autoclave equipped with a polytetrafluoroethylene inner layer and crystallized at 140-160°C for 120 hours. After the crystallization reaction is completed, the product is washed with distilled water, dried at 120°C, and then calcined at 550°C for 6 hours to obtain a nano-flaky MFI molecular sieve.
[0051] Catalyst preparation: Dissolve 0.080g chloroplatinic acid, 0.0812g strontium nitrate and 0.1251g zinc chloride in 50mL water to prepare a mixed solution, put 6g of the above-mentioned nanoflake MFI molecular sieve into it, soak for 12h, dry at 120℃, and then It is calcined at 550°C for 10 hours to obtain a molecular sieve with a Pt-Zn-S...
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