Method for preparing electrode material by using twin polymerization
A technology for preparing electrodes and polymerization methods, which is applied in the fields of hybrid capacitor electrodes, carbon preparation/purification, and hybrid/electric double layer capacitor manufacturing, etc. It can solve the problems of poor rate cycle performance, poor conductivity, and high cost, and achieve good rate performance , good cycle performance and large specific capacity
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0028] Preparation of sulfur-doped porous carbon materials by twin polymerization, according to the following steps;
[0029] ① Measure 8.55 g of highly purified liquid tetrathienyloxysilane and perform ultrasonic treatment for 15 minutes in an ultrasonic instrument with a power of 80-160 W, then put it into a 50 mL round bottom flask, and stir at room temperature.
[0030] ②Measure 442μL ([M] / [I]=5) of trifluoroacetic acid and dissolve it in 19mL of dichloromethane, stir well to make it evenly mixed, and slowly add the solution dropwise to the solution containing tetrathienyl In the round-bottomed flask of oxysilane, add it dropwise in about half an hour.
[0031] ③Set up the condensation reflux device, heat and stir the twin monomers added with the catalyst at 80°C for 3 hours to obtain the product A mixture, then take out the product A, let it stand at room temperature, and add a large amount of dichloromethane to extract after cooling , take the lower layer of the cloudy ...
Embodiment 2
[0036] Preparation of porous carbon material by twin polymerization, according to the following steps;
[0037]① Measure 2.5g of highly purified liquid tetrafurfuryloxysilane and perform ultrasonic treatment for 15 minutes in an ultrasonic instrument with a power of 80-160W, then put it into a 50mL round bottom flask, and stir at room temperature.
[0038] ② Measure 100μL ([M] / [I]=10) of trifluoroacetic acid and dissolve it in 4.43mL of dichloromethane, stir well to make it evenly mixed, and slowly add the solution dropwise to the solution containing tetrathiophene In the round-bottomed flask of oxysilane, add it dropwise in about half an hour.
[0039] ③Set up the condensation reflux device, and heat and stir the twin monomers added with the catalyst at 90°C for 2.5 hours to obtain the product A mixture, then take out the product A, let it stand at room temperature, and add a large amount of dichloromethane after cooling After extraction, the lower layer of the cloudy liquid...
Embodiment 3
[0045] Preparation of a composite material of titanium dioxide and sulfur-doped carbon by twinning polymerization is carried out as follows;
[0046] ① Measure 4.5 g of highly purified 1,2,3,4-tetrathienyloxycyclotetratitanium and perform ultrasonic treatment for 15 minutes in an ultrasonic instrument with a power of 80-160W, then put it into a 50mL round bottom flask, and Stir at room temperature.
[0047] ②Using 1,2,3,4-tetrathienyloxycyclotetratitanium as a monomer and trifluoromethanesulfonic anhydride as an initiator, take 510 μL of trifluoromethanesulfonic anhydride ([M] / [I]=5) to dissolve and Disperse evenly in 10mL of toluene, then slowly add the solution dropwise into the round bottom flask filled with 1,2,3,4-tetrathienyloxycyclotetratitanium, and the dropwise addition is completed in about half an hour.
[0048] ③Stir the twin monomer with the catalyst added at room temperature for 16 hours to obtain a product A mixture, then take out the product A, add a large amo...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More