Eureka AIR delivers breakthrough ideas for toughest innovation challenges, trusted by R&D personnel around the world.

A kind of polyaryletherketone cable material resin and its synthesis method

A cable material resin, polyaryl ether ketone technology, applied in the field of polyaryl ether ketone cable material resin and its synthesis, can solve the problems of complex preparation process requirements, reduce cable reliability, increase product cost, etc., and achieve multiple cross-linking points. , The effect of improving thermal stability and physical and mechanical properties

Active Publication Date: 2019-06-07
福建超阳电线电缆有限公司
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is difficult to form a uniform blend between traditional polyaryletherketone polymers, and the requirements for the preparation process are relatively complicated, and more additives are added, which undoubtedly increases the product cost and reduces the reliability of the cable.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of polyaryletherketone cable material resin and its synthesis method
  • A kind of polyaryletherketone cable material resin and its synthesis method
  • A kind of polyaryletherketone cable material resin and its synthesis method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Synthesis of polyaryl ether ketone cable material resin Synthesis: Add 12.25g (5mmol) perfluorocyclobutyl aryl ether phenol polymer, 5.04g (15mmol) hexafluorobisphenol A, 1.39g (10mmol) 2 , 5-difluorobenzonitrile, 2.18g (10mmol) 4,4'-difluorobenzophenone, toluene 100mL, DMAc120mL, 5.53g (40mmol) potassium carbonate, in 1mL / s N 2 Flow down at 140°C for 3 hours, then raise the temperature to 170°C for 20 hours, immediately pour the reaction solution into deionized water for precipitation under stirring, and filter. Soak the filtered precipitate with deionized water, change the water every 3 hours, repeat 7 times, filter, and then filter, place the precipitate in a freeze drying oven for 10 hours to obtain a polyaryletherketone cable material resin sample Analysis by GPC: Mn=46200, PDI=2.34, yield 96%. Its synthetic route:

[0027]

Embodiment 2

[0029] Synthesis of polyaryletherketone cable material resin: 24.50g (10mmol) perfluorocyclobutyl aryl ether phenol polymer, 3.36g (10mmol) hexafluorobisphenol A, 1.39g (10mmol) 2,5 -Difluorobenzonitrile, 2.18g (10mmol) 4,4'-difluorobenzophenone, toluene 100mL, DMAc120mL, 5.53g (40mmol) potassium carbonate, in 1mL / s N 2 Flow down at 140°C for 3 hours, then raise the temperature to 170°C for 20 hours, immediately pour the reaction solution into deionized water for precipitation under stirring, and filter. Soak the filtered precipitate with deionized water, change the water every 3 hours, repeat 7 times and then filter, place the precipitate in a freeze drying oven for 10 hours to obtain a polyaryletherketone cable material resin sample and analyze it by GPC : Mn=47200, PDI=2.64, the yield is 98%, and the result of DSC research shows that the glass transition temperature of the polyaryletherketone sample prepared in this embodiment is 185°C, and the result of thermogravimetric a...

Embodiment 3

[0031] Synthesis of polyaryletherketone cable material resin: 24.50g (10mmol) perfluorocyclobutyl aryl ether phenol polymer, 3.36g (10mmol) hexafluorobisphenol A, 0.82g (5mmol) 2,5 -Difluoroterephthalonitrile, 3.27g (15mmol) 4,4'-difluorobenzophenone, toluene 100mL, DMAc120mL, 5.53g (40mmol) potassium carbonate, in 1mL / s of N 2 Flow down at 140°C for 3 hours, then raise the temperature to 170°C for 20 hours, immediately pour the reaction solution into deionized water for precipitation under stirring, and filter. Soak the filtered precipitate with deionized water, change the water every 3 hours, repeat 7 times and then filter, place the precipitate in a freeze drying oven for 10 hours to obtain a polyaryletherketone cable material resin sample and analyze it by GPC : Mn=56580, PDI=2.75, yield 94.2%. Its synthetic route:

[0032]

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
glass transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention discloses a poly(aryl ether ketone) cable material resin and a synthesis method thereof. According to the synthesis method, perfluorocyclobutylaryl ether-phenol polymer, hexafluorobisphenol A, dihalobenzonitrile / dihalo-para-phthalonitrile, and 4,4'-difluorobenzophenone are taken as the raw materials; and after two temperature controlled reactions in a nitrogen atmosphere in the presence of a catalyst, the reaction product is subjected to precipitation, filtration, washing, and centrifugal drying to obtain the poly(aryl ether ketone) cable material resin. The thermal stability, crystallinity, and dissolvability of the polymer are effectively improved; the polymer dielectric constant, polymer dielectric loss factor, and signal attenuation ratio of high speed transmission frequency band are reduced; at the same time, the excellent properties of poly(aryl ether ketone) material are preserved; and the poly(aryl ether ketone) material has the advantages of poly(arylene ether nitrile), polyether ether ketone, and a material having a fluorine containing structure.

Description

technical field [0001] The invention relates to a polyaryl ether ketone cable material resin and a synthesis method thereof, belonging to the field of polymer materials. Background technique [0002] Polyaryletherketone is an aromatic thermoplastic special engineering plastic with good physical and chemical properties, so it is often used as a cable material. However, it is difficult to form a uniform blend between traditional polyaryletherketone polymers, and the requirements for the preparation process are relatively complicated, and more additives are added, which undoubtedly increases the product cost and reduces the reliability of the cable. In recent years, focusing on improving the processing performance and improving the heat resistance level, such new materials with excellent performance have been continuously developed to meet different use requirements. For example, different functional groups are introduced into the polymer main chain, such as naphthalene rings,...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08G65/40
CPCC08G65/4031C08G2650/48C08G2650/50
Inventor 黄雪红郑飞江生光
Owner 福建超阳电线电缆有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com