A kind of method for preparing furfural by hemicellulose two-step method in continuous flow microchannel reactor
A technology of microchannel reactor and channel reactor, which is applied in chemical instruments and methods, chemical/physical/physical chemical reactors, organic chemistry, etc., can solve the problems of low utilization rate of raw materials, pollution, low yield of furfural, etc. To achieve the effect of improving selectivity or safety, reducing cost, and reducing the amount of reaction materials
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Embodiment 1
[0060] The continuous flow microchannel reactor used is the enhanced mass transfer microchannel reactor of Corning Corporation of the United States, (the mode of the reactor is a "heart-shaped" structural function module) and the hydraulic diameter is 8mm. figure 1 1. Determine the connection mode of the microchannel reactor, the number of mixed reaction modules is determined according to the flow rate and reaction residence time, and the heating medium is heat transfer oil.
[0061] The hemicellulose raw material comes from the turbid liquid with a hemicellulose content of 20% recovered from chemical fiber waste liquid. The equipment is divided into two reaction areas
[0062] First reaction zone:
[0063] (1) In order to make the reaction reach the best yield, the raw material of hemicellulose is configured as an aqueous solution with a hemicellulose content of 20wt%, and the catalyst sulfuric acid is made into a 40wt% aqueous solution. Beyond this range, solids will be prec...
Embodiment 2
[0077] The microchannel reactor that the present invention adopts is the enhanced mass transfer type microchannel reactor of American Corning Company, and this reaction system is assembled by a plurality of modules; The material of this module is silicon carbide and special glass etc.; The microchannel structure in the module There are two types of direct-flow channel structure and enhanced mixed-type channel structure. The direct-flow channel is a tubular structure, and the enhanced-mixed channel structure is a heart-shaped structure. The hydraulic diameter of the channel is 8mm; the continuous flow microchannel reactor used (straight channel functional module + "Heart-shaped" structural function module) process, refer to figure 1 1. Determine the connection mode of the microchannel reactor, the number of mixed reaction modules is determined according to the flow rate and reaction residence time, and the heating medium is heat transfer oil.
[0078] The hemicellulose raw mate...
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