Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A heterojunction interface doped composite photocatalyst and its preparation method

A composite light and heterojunction technology, applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve problems such as unfavorable utilization of visible light, many by-products of carbon dioxide reduction, and difficulties in industrial production. Achieve the effect of good prospects for industrial application, enhanced recycling capacity, and large scale

Inactive Publication Date: 2020-04-10
HUAIBEI NORMAL UNIVERSITY
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are many by-products of carbon dioxide reduction in this technology, and zinc oxide is a wide-bandgap semiconductor that is not conducive to the utilization of visible light, so it has caused difficulties for actual industrial production.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A heterojunction interface doped composite photocatalyst and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] First, 10 g of melamine was heated to 700 °C at room temperature at 5 °C / min, and then cooled to room temperature at 20 °C / min for 5 h to prepare porous g-C. 3 N 4 Nanosheets. Then add g-C to the glycerol solution of bismuth chloride 3 N 4 The nanosheets were stirred and dispersed evenly, and then 10 mol / l sodium hydroxide was added dropwise to adjust the pH of the solution to 9. The precipitate was washed with water, centrifuged and dried. Heterojunction interfacially doped Bi 12 o 17 Cl 2 / g -C 3 N 4 composite photocatalyst.

[0030] The methane conversion rate reaches 323μmol / g / h.

Embodiment 2

[0032] First, 5 g urea and 10 g thiourea were heated to 800 °C at room temperature at 8 °C / min, and then cooled to room temperature at 30 °C / min for 6 h to prepare porous g-C. 3 N 4 Nanosheets. Then add g-C to the ethylene glycol solution of bismuth nitrate 3 N 4 The nanosheets were stirred and dispersed evenly, and then 3 mol / l ammonia water was added dropwise to adjust the pH of the solution to 10. The precipitate was washed with water, centrifuged and dried. Heterojunction interfacially doped Bi 12 o 17 Cl 2 / g -C 3 N 4 composite photocatalyst.

[0033] The methane conversion rate reaches 516μmol / g / h.

Embodiment 3

[0035] First, 150 g melamine and 50 g urea were heated to 600 °C at room temperature at 8 °C / min, and then cooled to room temperature at 5 °C / min for 3 h to prepare porous g-C. 3 N 4 Nanosheets. Then add g-C to the glycerol solution of bismuth carbonate 3 N 4 The nanosheets were stirred and dispersed evenly, and then 10 mol / l potassium hydroxide was added dropwise to adjust the pH of the solution to 12. The precipitate was washed with water, centrifuged and dried. Heterojunction interface-doped Bi 12 o 17 Cl 2 / g -C 3 N 4 composite photocatalyst.

[0036] The methane conversion rate reaches 364μmol / g / h.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a heterojunction interface doped composite photocatalyst and a preparation method. The prepared heterojunction interface is doped with Bi 12 O 17 Cl 2 / g‑C 3 N 4 Composite photocatalyst has a strong ability to convert carbon dioxide into methane under visible light. The present invention adopts g-C 3 N 4 and Bi 12 O 17 Cl 2 The composite of nanosheets makes it easier to form a large-area heterojunction, thus promoting the separation of carriers; through thermal diffusion, the Bi 12 O 17 Cl 2 The bismuth atoms on the g-C were successfully doped into 3 N 4 The lattice induces a super strong electric field at the heterojunction interface, achieving super visible light reduction performance of carbon dioxide; porous g‑C 3 N 4 The extremely high specific surface area and countless micropores facilitate interface doping; the matching band gap structure and interface doping successfully control the flow direction of carriers, achieve selective reduction of carbon dioxide into methane, and enhance the recycling of photocatalysts. Capability; material synthesis is simple, green, large-scale, and has good prospects for industrial application.

Description

technical field [0001] The invention relates to a heterojunction interface doped composite photocatalyst and a preparation method thereof, belonging to the technical fields of energy environment and nanometer materials. Background technique [0002] Energy and environmental issues are related to sustainable economic and social development and human survival. Although fossil fuels can temporarily meet the needs of human development, fossil fuels are non-renewable energy sources. The long-term use of fossil fuels will not only reduce the reserves of fossil fuels, but also the emission of carbon dioxide, a large amount of combustion products, will lead to the greenhouse effect. Photocatalysts use solar energy to convert carbon dioxide into organic fuels such as methane, methanol, formaldehyde, and carbon monoxide, providing an ideal way to solve energy and environmental problems. The whole process of utilizing solar energy to reduce carbon dioxide into organic fuel is green a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/24B01J37/08C07C1/12C07C9/04
CPCC07C1/12B01J27/24B01J37/08B01J35/39C07C9/04
Inventor 代凯王中辽吕佳丽李真霍瑶胡太平
Owner HUAIBEI NORMAL UNIVERSITY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com