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Preparation method of integral type SCR (Selective Catalytic Reduction) catalytic reactor compounded by inorganic oxide

A technology of inorganic oxides and catalytic reactors, which is applied in the preparation of integral SCR catalytic reactors and the field of nitrogen oxide reduction, which can solve the problems of rising overall cost of honeycomb catalysts, unusable active components, and coating binding strength Limited and other problems, to save the coating process, improve the durability, and the effect of cheap raw materials

Inactive Publication Date: 2017-11-07
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] However, in the honeycomb catalysts involved in the above two disclosed inventions, the catalytically active components are evenly distributed in each part of the honeycomb catalyst. In actual use, the active components inside the honeycomb catalyst cannot be utilized, which will inevitably lead to Increase in overall catalyst cost and waste of catalytically active components
[0006] At present, the existing technology is to coat the catalyst on the ceramic honeycomb carrier by coating process, and then perform low-temperature drying and high-temperature roasting to obtain a catalytic reactor. However, the bonding strength of the coating is limited. As the user uses it, the vehicle Bumping and vibration will cause the catalyst to fall off and reduce the catalytic efficiency. At the same time, the coating process has certain requirements for equipment and cost

Method used

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  • Preparation method of integral type SCR (Selective Catalytic Reduction) catalytic reactor compounded by inorganic oxide

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Experimental program
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Embodiment 1

[0016] The honeycomb ceramic catalyst was prepared by using kaolin, inorganic oxide, mullite fiber and aluminum dihydrogen phosphate as raw materials.

[0017] The first step: preparation of honeycomb ceramic mud

[0018] 6.0kg kaolin, inorganic oxide, 0.5kg mullite fiber, 1.5kg aluminum dihydrogen phosphate, 0.3kg methyl cellulose (binder), 0.3kg tung oil (lubricant), 0.3kg glycerin (plasticizer) ) and 2kg of water were put into a mud kneader and mixed for 5 hours to make mud; then the mud was put into a vacuum mud mixer for mud refining, and the mixing time was 2 hours; after that, the mud made of vacuum mud was used for fresh-keeping Wrap it with a film, put it into a cool and humid air and stale for 20 hours to make a mud base with good plasticity; put the aged mud base into an extruder for extrusion molding, and the extrusion pressure is 23Mpa to make the mud base pass through Bottom diameter is 18cm, 200-mesh stainless steel mould, and then cut into the required length ...

Embodiment 2

[0023] The honeycomb ceramic catalyst was prepared by using bentonite, inorganic oxide and mullite fiber as raw materials.

[0024] The first step: preparation of honeycomb ceramic mud

[0025] 5.5kg kaolin, inorganic oxides, 0.3kg mullite fiber, 2.5kg aluminum dihydrogen phosphate, 0.4kg hydroxypropyl methylcellulose (binder), 0.3kg tung oil (lubricant), 0.3kg glycerin ( Plasticizer) and 2.5kg of water were put into a mud kneader and mixed for 5 hours to form mud; then the mud was put into a vacuum mud mill for mud refining, and the mixing time was 2 hours; The mud base is wrapped with a plastic wrap, put into a cool and humid air and stale for 20 hours to obtain a good plasticity mud base; the aged mud base is put into an extruder for extrusion molding, and the extrusion pressure is 23Mpa. Make the mud body pass through a stainless steel mold with a bottom diameter of 18cm and 200 meshes, and then cut it into a honeycomb ceramic wet body of the required length with a molybd...

Embodiment 3

[0030] Attapulgite, inorganic oxides, and mullite fibers were used as raw materials to prepare honeycomb ceramic catalysts.

[0031] The first step: preparation of honeycomb ceramic mud

[0032] 6kg attapulgite, inorganic oxide, 0.2kg mullite fiber, 3.0kg aluminum dihydrogen phosphate, 0.3kg hydroxyethyl cellulose (binder), 0.3kg tung oil (lubricant), 0.3kg glycerin ( Plasticizer) and 2.0kg of water were put into a mud kneader and mixed for 5 hours to form mud; then the mud was put into a vacuum mud mill for mud refining, and the mixing time was 2 hours; after that, the mud made of vacuum mud The billet is wrapped with a plastic wrap, put into a cool and humid air and stale for 20 hours to obtain a mud billet with good plasticity; the stale mud billet is put into an extruder for extrusion molding, and the extrusion pressure is 23Mpa, so that The mud body passes through a 200-mesh stainless steel mold with a diameter of 18cm on the bottom surface, and then cuts it into a honey...

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Abstract

The invention discloses a preparation method of an integral type SCR (Selective Catalytic Reduction) catalytic reactor compounded by inorganic oxide. The preparation method comprises the steps of adding inorganic oxide powder into a manufacturing raw material of a ceramic honeycomb carrier, and manufacturing to obtain a ceramic honeycomb catalyst carrier with the outer surface being compounded by the inorganic oxide. The inorganic oxide in the carrier is utilized as an SCR reaction catalyst, so that the defect that a coating type honeycomb catalyst coating falls off can be overcome, the waste of active components in the honeycomb catalyst is avoided, and the production cost is reduced. Meanwhile, metal oxide in pores of the honeycomb catalyst can be used as a sulfur poisoning active center, so that the durability of the honeycomb catalyst is improved.

Description

technical field [0001] The invention relates to a preparation method of an inorganic oxide composite monolithic SCR catalytic reactor, which is especially used in the field of diesel vehicle exhaust gas purification, and is especially used for the reduction of nitrogen oxides according to the selective catalytic reduction method, that is, using nitrogen-containing reduction agent for nitrogen oxide reduction. Background technique [0002] Nitrogen oxides (NOx) are one of the main pollutants in the atmosphere, among which NO and NO2 account for the largest proportion. With the rapid development of my country's economy, the demand for energy is increasing day by day, and the emission of NOx is also increasing sharply. Diesel vehicles are one of the main emission sources of NOx, and the control of NOx emission has become a very concerned topic in environmental protection. For diesel vehicle NOx emissions, the emission regulations of countries around the world are becoming inc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/86B01D53/56B01J23/889B01J35/04B01J32/00
CPCB01D53/8628B01D53/8631B01J23/002B01J23/8892B01J2523/00B01J35/56B01J2523/17B01J2523/47B01J2523/69B01J2523/72B01J2523/842B01J2523/847
Inventor 崔龙韩建张斌于力娜张克金
Owner CHINA FIRST AUTOMOBILE