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Titanium-aluminum-based alloy surface protective coating and preparation method thereof

A protective coating and alloy coating technology, which is applied in metal material coating technology, coating, ion implantation plating, etc., can solve the problems of poor bonding strength between the modified layer and the substrate, loss of protective effect, easy peeling, etc. Achieve the effects of improving corrosion resistance, prolonging service life, and saving energy resources

Inactive Publication Date: 2017-12-01
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the bonding strength between the modified layer and the substrate formed by the above-mentioned technical means is poor, it is easy to peel off and lose the protective effect, and many technical means are costly, requiring certain restrictions on the size and shape of the workpiece to be processed. Therefore, the above-mentioned technical means There are great limitations

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  • Titanium-aluminum-based alloy surface protective coating and preparation method thereof
  • Titanium-aluminum-based alloy surface protective coating and preparation method thereof
  • Titanium-aluminum-based alloy surface protective coating and preparation method thereof

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Embodiment 1

[0021] Firstly, the surface of the titanium-aluminum-based alloy is ground and polished to 1000#, then ultrasonically cleaned with a cleaning agent prepared from ethanol and acetone with a volume ratio of 3:1, and then dried; the processed titanium-aluminum-based alloy and Ta-W alloy The target material is put into the Shuanghui plasma surface metallurgical infiltration furnace. The Ta-W alloy target material contains 78% Ta and 22% W according to mass percentage. The titanium-aluminum-based alloy is used as the workpiece electrode and Ta-W The alloy target is the source, and the distance between the two electrodes is adjusted to 15mm; the double-glow plasma surface metallurgical infiltration furnace is evacuated to a pressure of 0.2Pa, argon gas is introduced to start the glow, and the source voltage is controlled to 800V. Workpiece voltage is 450V, working pressure is 30Pa, working time is 2h; stop glow, cut off power, complete Ta-W co-infiltration on the surface of titanium-a...

Embodiment 2

[0023] Firstly, the surface of the titanium-aluminum-based alloy is ground and polished to 1000#, then ultrasonically cleaned with a cleaning agent prepared from ethanol and acetone with a volume ratio of 3.5:1, and then dried; the processed titanium-aluminum-based alloy and Ta-W alloy The target material is put into the Shuanghui plasma surface metallurgical infiltration furnace. The Ta-W alloy target material has a Ta content of 79% and a W content of 21% by mass percentage. The titanium-aluminum-based alloy is used as the workpiece electrode, and Ta-W The alloy target is the source, and the distance between the two electrodes is adjusted to 15mm; the double-glow plasma surface metallurgical infiltration furnace is evacuated to a pressure of 0.2Pa, argon gas is introduced to start the glow, and the source voltage is controlled to 800V. Workpiece voltage is 450V, working pressure is 30Pa, working time is 2h; stop glow, cut off power, complete Ta-W co-infiltration on the surface...

Embodiment 3

[0025] First, the surface of the titanium-aluminum-based alloy is ground and polished to 1200#, then ultrasonically cleaned with a cleaning agent prepared from ethanol and acetone with a volume ratio of 4:1, and then dried; the processed titanium-aluminum-based alloy and Ta-W alloy The target material is put into the Shuanghui plasma surface metallurgical infiltration furnace. The Ta-W alloy target material is calculated by mass percentage of Ta content of 80%, W content of 20%, titanium-aluminum-based alloy as the workpiece electrode, and Ta-W The alloy target is the source electrode, and the distance between the two electrodes is adjusted to 25mm; the double-glow plasma surface metallurgical infiltration furnace is evacuated to a pressure of 0.2Pa, and argon gas is introduced to start the glow, and the source voltage is controlled to 950V. The workpiece voltage is 550V, the working pressure is 30Pa, and the working time is 2h; stop the glow and cut off the power to complete th...

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Abstract

The invention provides a titanium-aluminum-based alloy surface protective coating and a preparation method thereof. The comprehensive performance of titanium-aluminum-based alloy can be improved, the application range of the titanium-aluminum-based alloy is expanded, the service life is prolonged, and the purposes of saving energy resources and reducing the cost are achieved. The coating comprises, by mass, 75-95% of Ta and 5-25% of W. The coating is prepared by achieving Ta-W co-permeation on the surface of the titanium-aluminum-based alloy through the double-layer glow plasma surface metallurgy technology, and the prepared alloy coating is combined with base body metallurgy and comprises a diffusion layer and a deposition layer.

Description

Technical field [0001] The invention belongs to the technical field of metal material surface engineering, and in particular relates to a titanium-aluminum-based alloy surface protective coating and a preparation method thereof. Background technique [0002] Titanium-aluminum-based alloy is a new type of lightweight high-temperature structural material with the advantages of low density, high specific strength, and excellent high-temperature creep performance. Its application in the aviation field is of great significance for reducing aircraft weight and improving aircraft performance. But when the service temperature of titanium-aluminum-based alloy exceeds 650°C, TiO 2 With Al 2 O 3 The free energy of formation is close, and selective oxidation occurs during the oxidation process, while TiO 2 The formation rate of is greater than Al 2 O 3 Formation rate, so TiO is formed in the titanium aluminum alloy 2 With Al 2 O 3 Mixed oxide film, a lot of TiO 2 Doping will cause the surface...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/48C23C14/16C23C14/58
CPCC23C14/48C23C14/16C23C14/5806
Inventor 刘颖超张平则魏东博陈小虎丁丰
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS