Preparation method for modified biological carbon which efficiently adsorbs soil inorganic phosphorus and dissolves organic phosphorus at same time and application

A technology of biochar and inorganic phosphorus, applied in agricultural machinery and tools, carbon preparation/purification, chemical instruments and methods, etc., can solve the problems of polluted groundwater, low effective utilization rate, etc., and achieve low price, wide range of sources, and preparation The process is simple and feasible

Inactive Publication Date: 2017-12-12
INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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  • Application Information

AI Technical Summary

Problems solved by technology

As a large agricultural country, my country's agricultural waste is mainly straw and animal manure, with a huge annual output, but the effective utilization rate is low, and the long-term open-air accumulation of manure will pollute groundwater with runoff.

Method used

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  • Preparation method for modified biological carbon which efficiently adsorbs soil inorganic phosphorus and dissolves organic phosphorus at same time and application
  • Preparation method for modified biological carbon which efficiently adsorbs soil inorganic phosphorus and dissolves organic phosphorus at same time and application
  • Preparation method for modified biological carbon which efficiently adsorbs soil inorganic phosphorus and dissolves organic phosphorus at same time and application

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Experimental program
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Embodiment 1

[0025] 1. Preparation of modified biochar:

[0026] (1) Collect air-dried yak dung and pass it through a 0.5cm diameter hole sieve after crushing;

[0027] (2) Dissolve magnesium chloride hexahydrate in ultrapure water to prepare a modified impregnation solution with a magnesium ion content of 2.0mol / L;

[0028] (3) Mix the yak dung and the modified impregnating solution evenly at a solid-to-liquid ratio of 1:5 (yak dung, g / modified impregnating solution, mL);

[0029] (4) Place the mixture of yak manure and modified impregnation solution in a shaking table and shake at a rate of 200rpm for 2h;

[0030] (5) Filter the impregnated yak dung and dry it in an oven at 100°C to constant weight;

[0031] (6) Pyrolyze the dried yak dung in a muffle furnace for 3 hours under the protection of nitrogen, the pyrolysis heating rate is 5°C / min, and the final pyrolysis temperature is 600°C;

[0032] 2. Modified biochar adsorbs inorganic phosphorus and dissolved organic phosphorus in soil...

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Abstract

The invention provides modified biological carbon which efficiently adsorbs soil inorganic phosphorus and dissolves organic phosphorus at the same time. The modified biological carbon is prepared according to the following steps: (1) collecting air-dried yak excrement, smashing the collected yak excrement, and sieving the smashed yak excrement; (2) preparing an impregnating liquid containing magnesium ions with a certain concentration by using magnesium chloride hexahydrate; (3) mixing the sieved yak excrement with the modification impregnating liquid uniformly according to a proportion; (4) placing the mixture of the treated yak excrement and the impregnating liquid in a shaking bed, and performing impregnation fully; (5) filtering impregnated yak excrement out, placing filtered yak excrement in a drying oven, and performing drying; and (6) performing slow-speed pyrolysis on dried yak excrement in a muffle furnace under nitrogen protection to obtain the modified biological carbon. According to the invention, the dried yak excrement is fired into the modified biological carbon, thus high-efficiency recycling of biological matter is realized, the modified biological carbon can efficiently adsorb the soil inorganic phosphorus and dissolve the organic phosphorus at the same time, and agricultural non-point source pollution is effectively controlled.

Description

technical field [0001] The invention relates to the preparation of a modified biochar that efficiently and simultaneously adsorbs soil inorganic phosphorus and dissolved organic phosphorus, and is applied to the control of farmland phosphorus non-point source pollution, belonging to the field of water pollution control. Background technique [0002] In recent years, with the rapid development of sewage treatment technology, point source pollution has gradually been effectively controlled, but agricultural non-point source pollution is still a thorny problem, and it has become the main pollution source of water eutrophication in my country. At present, the control of the source of pollutants, the interception of pollutant loss paths, and the restoration of polluted land are the three major measures to control agricultural non-point source pollution. Among them, the control of the source of pollutants is the most effective prevention and control measure, which can not only ach...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/05B01J20/20B01J20/32C09K17/04C09K101/00
CPCB01J20/20B01J20/3204B01J20/3225C01P2002/85C01P2004/03C09K17/04C09K2101/00
Inventor 罗专溪侯杰发汪艳如颜昌宙
Owner INST OF URBAN ENVIRONMENT CHINESE ACAD OF SCI
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