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High-efficiency flue gas desulfurization and denitrification catalyst and preparation method thereof

A technology of desulfurization and denitrification and catalyst, which is applied in the field of desulfurization and denitrification, and can solve the problems of high desulfurization and denitrification rate and high operating cost

Active Publication Date: 2017-12-29
NANJING WEIHENG EXPERIMENTAL EQUIP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although electron beam hair has been industrialized, due to its high operating costs, it is difficult to promote it on a large scale in China, and it is difficult for existing catalysts to have high desulfurization and denitrification rates at the same time

Method used

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Examples

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Comparison scheme
Effect test

preparation example Construction

[0027] Wherein, the preparation method of graphitized activated carbon comprises the following steps:

[0028] Add iron nitrate and sodium carbonate to activated carbon, heat treatment at 500-1000°C for 5-8 hours in a nitrogen atmosphere, and then wash and dry with 0.4-0.6mol / L dilute nitric acid and distilled water in turn to obtain graphitized activated carbon; activated carbon, nitric acid The mass ratio of iron to sodium carbonate is 1:(0.1-0.2):(0.2-0.3).

[0029] The preparation method of alcohol aminated activated carbon comprises the following steps:

[0030] Add triethanolamine and sodium hydroxide to activated carbon, heat-treat at 500-1000°C for 5-8 hours in a nitrogen atmosphere, and then wash and dry with 0.4-0.6mol / L dilute nitric acid and distilled water in sequence to obtain graphitized activated carbon; activated carbon, The mass ratio of triethanolamine and sodium hydroxide is 1:(0.16-0.22):(0.3-0.4).

[0031] In the embodiment of the present invention, the...

Embodiment 1

[0038] The preparation method of graphitized activated carbon comprises the following steps:

[0039] Add ferric nitrate and sodium carbonate to activated carbon, heat-treat at 750°C for 6.5 hours in a nitrogen atmosphere, and then wash and dry with 0.5mol / L dilute nitric acid and distilled water in turn to obtain graphitized activated carbon; the mixture of activated carbon, ferric nitrate and sodium carbonate The mass ratio is 1:0.15:0.25.

Embodiment 2

[0041] The preparation method of graphitized activated carbon comprises the following steps:

[0042] Add ferric nitrate and sodium carbonate to activated carbon, heat treatment at 1000°C for 8 hours in a nitrogen atmosphere, and then wash and dry with 0.6mol / L dilute nitric acid and distilled water in turn to obtain graphitized activated carbon; the mass of activated carbon, ferric nitrate and sodium carbonate The ratio is 1:0.2:0.3.

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Abstract

The invention discloses a high-efficiency flue gas desulfurization and denitrification catalyst and a preparation method thereof. The high-efficiency flue gas desulfurization and denitrification catalyst is prepared from 8-12 wt% of active components, 5-8 wt% of cocatalyst and 80-87 wt% of carrier; the active components comprise yttrium oxide, tricobalt tetroxide, manganese dioxide and aluminum chloride; the cocatalyst is ferric oxide or nickel oxide; the carrier is modified activated carbon; the specific surface area of a molecular sieve is 350-500m<2> / g, and the pore diameter is 0.8 to 1.2 mL / g. The catalyst disclosed by the invention takes the yttrium oxide, the tricobalt tetroxide, the manganese dioxide and the aluminum chloride as the active components, the ferric oxide or the nickel oxide as the cocatalyst and the modified activated carbon as the carrier, and has a good effect on desulfurization and denitrification, can remove sulfur and nitrate in flue gas, and can be widely used for desulfurization and denitrification of large-scale flue gas emission enterprises such as iron and steel enterprises, bituminous coal power plants, bituminous coal furnaces and metallurgical industry.

Description

technical field [0001] The invention relates to the field of desulfurization and denitrification, in particular to a high-efficiency flue gas desulfurization and denitrification catalyst and a preparation method thereof. Background technique [0002] Sulfur dioxide and nitrogen oxides are one of the main air pollutants. They are the culprits of acid rain and acid fog. They interact with hydrocarbons to form photochemical smog, which poses a serious threat to human biological health. The removal of sulfur dioxide and nitrogen oxides from coal-burning flue gas and motor vehicles is the main task of air pollution control in my country at present. [0003] At present, the common flue gas desulfurization and denitrification technologies mainly include electron beam method, activated carbon method and aluminum-based copper method. Although electron beam hair has been industrialized, due to its high operating costs, it is difficult to promote it on a large scale in China, and it i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/889B01J37/08B01D53/86B01D53/60
CPCB01D53/8637B01D2258/0283B01J23/002B01J23/8892B01J37/088B01J2523/00B01J2523/31B01J2523/36B01J2523/72B01J2523/842B01J2523/845B01J2523/847
Inventor 汪泽维黄浩郭伟
Owner NANJING WEIHENG EXPERIMENTAL EQUIP CO LTD
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