Antibacterial stain-resistant wood-plastic packaging material and preparation method thereof
A packaging material and wood-plastic technology, applied in the field of antibacterial and antifouling wood-plastic packaging materials and their preparation, can solve the problems of the beautiful appearance of the wood-plastic packaging material, the unreported antibacterial and antifouling ability, the poor antibacterial and antifouling ability, and the impact on product quality and performance, etc. problems, to achieve the effect of improving antibacterial and antifouling properties, improving mechanical properties, and closely fitting and falling off.
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Embodiment 1
[0021] (1) Mix 50 parts of wood fiber, 35 parts of polypropylene PP, 5 parts of titanate coupling agent and 10 parts of ethyl acrylate, grind to 50 μm, then preheat to 110 ° C, and stir for 15 minutes;
[0022] (2) Then add 4 parts of attapulgite and 8 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 8 parts of octamethylcyclotetrasiloxane, preheat at 200°C, and press mold at 0.8MPa;
[0023] (3) In step (2), soak the surface of the molding material into 10% methanol solution of ethylene glycol dimethacrylate for 10 minutes; take it out and irradiate it under a UV lamp for 3 minutes; after the irradiation is completed, rinse it with methanol solution for 5 times to form material surface;
[0024] (4) Add the molding material obtained in step (3) into the solution with PH=3.2, add 5 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;
[0025] (5) Crush the drie...
Embodiment 2
[0027] (1) Mix 60 parts of wood fiber, 40 parts of polypropylene PP, 10 parts of titanate coupling agent and 15 parts of ethyl acrylate, grind to 30 μm, then preheat to 130 ° C, and stir for 10 minutes;
[0028] (2) Then add 6 parts of attapulgite and 5 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 10 parts of octamethylcyclotetrasiloxane, preheat at 150°C, and press mold at 0.5MPa;
[0029] (3) In step (2), soak the surface of the molding material into 20% methanol solution of ethylene glycol dimethacrylate for 5 minutes; take it out and irradiate it under a UV lamp for 6 minutes; rinse it with methanol solution for 5 times to form material surface;
[0030] (4) Add the molding material obtained in step (3) into the solution of PH=4.5, add 10 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;
[0031] (5) Crush the dried material into 150 mesh particles, ...
Embodiment 3
[0033] (1) Mix 55 parts of wood fiber, 38 parts of polypropylene PP, 10 parts of titanate coupling agent and 12 parts of ethyl acrylate, grind to 35 μm, then preheat to 115 ° C, and stir for 12 minutes;
[0034] (2) Then add 5 parts of attapulgite and 6 parts of nano-zirconia, and disperse ultrasonically for 20 minutes at a power of 3000W; then add 9 parts of octamethylcyclotetrasiloxane, preheat at 170°C, and press mold at 0.58MPa;
[0035] (3) In step (2), soak the surface of the molding material into a 13% methanol solution of ethylene glycol dimethacrylate for 6 minutes; take it out and irradiate it under a UV lamp for 4 minutes; rinse it with methanol solution for 5 times to form material surface;
[0036] (4) Add the molding material obtained in step (3) into the solution of PH=3.5, add 7 parts of methyl methanesulfonate for reaction, and then wash it repeatedly with deionized water and methanol for 8 times;
[0037] (5) Crush the dried material into 120 mesh particles,...
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