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Preparation method of aging-enhanced copper-chromium alloy

An enhanced and alloyed technology, which is applied in the field of preparation of aging-enhanced CuCr alloys, can solve the problems of Cr agglomeration, large precipitated phase size, and low content, and achieve the effects of good alloy composition uniformity, simple operation, and high density

Inactive Publication Date: 2018-01-19
XIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to provide a method for preparing an aging-enhanced CuCr alloy, which solves the problems of low content of Cr in the copper matrix, agglomeration of Cr in the copper matrix and large size of precipitated phases, ensures uniform composition of the alloy, and has high electrical conductivity. sex and intensity

Method used

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  • Preparation method of aging-enhanced copper-chromium alloy
  • Preparation method of aging-enhanced copper-chromium alloy
  • Preparation method of aging-enhanced copper-chromium alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Use a balance to weigh a certain proportion of copper and chromium, the mass ratio of chromium is 4%, remove the oil and impurities on the surface of the material, and melt in a vacuum induction melting furnace with a vacuum degree of 8×10 -3 Pa, nitrogen protection atmosphere + 0.05MPa, heating rate of 2°C / s, superheat of 200°C, heat preservation for 5min, and then use restricted nozzle atomization, atomization pressure 5MPa, nozzle diameter 4mm, atomization process is about 9s, for The prepared alloy powder is sieved with different particle sizes, and the alloy powder with a certain particle size is cold-pressed, and then the cold-pressed sample is placed in a Φ21 graphite mold for atmosphere-protected hot-press sintering, and the sintering temperature is 1030°C , the pressure is 30MPa, and the holding time is 1h. After the surface treatment of the hot-pressed sample, the sample is subjected to aging treatment at 450°C. The aging time is 2h. The obtained alloy sample h...

Embodiment 2

[0032] Use a balance to weigh a certain mass fraction of copper block and chromium pellets, the mass ratio of chromium is 3.5%, remove the oil and impurities on the surface of the material, and melt in a vacuum induction melting furnace with a vacuum degree of 9×10 -3 Pa, nitrogen protective atmosphere + 0.04MPa, heating rate of 2°C / s, superheat of 200°C, heat preservation for 6min, and then use restricted nozzle atomization, atomization pressure 6MPa, nozzle diameter 4mm, atomization process is about 8s, for The prepared alloy powder was sieved with different particle sizes, and 29g of alloy powder was weighed for cold-press molding, and then the cold-pressed sample was placed in a Φ21 graphite mold for atmosphere-protected hot-press sintering, and the sintering temperature was 1030°C. The pressure is 30MPa, and the holding time is 1h. After the surface treatment of the hot-pressed sample, the sample is subjected to aging treatment at 440°C. The aging time is 2h. The obtained ...

Embodiment 3

[0034] Use a balance to weigh a certain mass fraction of copper block and chromium pellets, the mass ratio of chromium is 3.5%, remove the oil and impurities on the surface of the material, and melt in a vacuum induction melting furnace with a vacuum degree of 7×10 -3 Pa, nitrogen protection atmosphere + 0.04MPa, heating rate of 2°C / s, superheat of 200°C, heat preservation for 6min, and then use restricted nozzle atomization, atomization pressure 5MPa, nozzle diameter 5mm, atomization process is about 7s, for The prepared alloy powders were sieved with different particle sizes, and 29g of alloy powders were weighed for cold-press molding, and then the cold-pressed samples were placed in a Φ21 graphite mold for atmosphere-protected hot-press sintering, and the sintering temperature was 1020°C. The pressure is 29MPa, and the holding time is 1h. After the surface treatment of the hot-pressed sample, the sample is subjected to aging treatment at 460°C. The aging time is 2h. The obt...

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Abstract

The invention discloses a preparation method of an aging-enhanced copper-chromium alloy. The preparation method comprises the following steps that 1, vacuum induction melting is carried out by adopting nitrogen as a protective gas; 2, powder is prepared through atomization by using a ring hole limiting type atomizer; 3, screening is carried out on the atomized alloy powder according to different particle sizes; and 4, hot pressed sintering and aging treatment are carried out in the alloy powder with a certain particle size to obtain the copper-chromium alloy. According to the preparation method of the copper-chromium alloy, the solid solubility of chromium in copper is improved; compared with an alloy prepared through a mechanical ball milling method, the alloy is better in component uniformity; the copper-chromium alloy prepared through gas atomization has fine grain structures and relatively high degree of supersaturation of chromium, and the obtained alloy sample has high conductivity and strength; and phases precipitated from the alloy powder obtained after sintering are small in size and large in number, and the alloy powder can be used for materials of high-energy electric conduction elastic devices and electrical contacts in the aerospace field.

Description

technical field [0001] The invention belongs to the technical field of dispersion-strengthened copper alloys, and in particular relates to a method for preparing an aging-enhanced CuCr alloy. Background technique [0002] With the rapid development of electronics, electric power, transportation and aerospace industries, higher requirements are placed on the conductivity, wear resistance and service life of materials. Copper-chromium alloys have higher strength and thermal conductivity than other alloy materials. and better conductivity. According to the solid solubility curve, it can be seen that the solid solubility of chromium in copper is only about 0.7%. Improving the solid solubility of chromium in the copper matrix is ​​the main method to improve the comprehensive performance of copper-chromium alloys. At present, the methods for preparing copper-chromium alloys mainly include Powder mixing method, infiltration method, pouring method, powder mixing and infiltration me...

Claims

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Application Information

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IPC IPC(8): C22C9/00C22C1/04C22F1/08C22F1/02B22F9/08B22F3/14B22F3/24
Inventor 肖鹏刘笛姜伊辉邹俊涛梁淑华
Owner XIAN UNIV OF TECH
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