A kind of anti-reflection coating liquid and preparation method thereof
A coating solution and anti-reflection technology, applied in the direction of coating, etc., can solve the problems of high refractive index of the film layer, poor anti-reflection effect, non-wear resistance, etc., achieve good film uniformity, increase light transmittance, and reduce costs low effect
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Embodiment 1
[0029] A kind of anti-reflection coating liquid, its preparation method comprises the following steps:
[0030] (1) Slowly add 6% vinylsilane modified silicone resin dropwise to 10% nano-silica and 15% hollow silica to carry out surface modification treatment;
[0031] Among them, the average particle diameter of nano-silica is 15nm, and the average particle diameter of hollow silica is 25nm;
[0032] After surface modification treatment, the organosilicon modifier is attached to the surface of nano-silica and hollow silica particles, making the combination between the particles stronger.
[0033] (2) 10% nano silicon dioxide and 15% hollow silicon dioxide, 5% oxide, 35% deionized water and 1% hydrochloric acid after the above-mentioned surface modification treatment are added in 28% solvent, at 30 ℃ condition Under reaction 15h;
[0034] The solvent is a mixture of ethanol, isopropanol and ethylene glycol in a volume ratio of 1:2:1;
[0035] The oxide is a mixture of alumi...
Embodiment 2
[0038] A kind of anti-reflection coating liquid, its preparation method comprises the following steps:
[0039] (1) Slowly add 8% epoxy silane modified silicone resin dropwise to 15% nano-silica and 20% hollow silica for surface modification;
[0040] Among them, the average particle diameter of nano-silica is 30nm, and the average particle diameter of hollow silica is 50nm;
[0041] After surface modification treatment, the organosilicon modifier is attached to the surface of nano-silica and hollow silica particles, making the combination between the particles stronger.
[0042] (2) 15% nano silicon dioxide and 20% hollow silicon dioxide, 2% oxide, 30% deionized water and 2% catalyst after the above-mentioned surface modification treatment are added in 23% ethylene glycol diethyl ether, React at 60°C for 10 hours;
[0043] The catalyst is an acid solution in which sulfuric acid and nitric acid are configured at a volume ratio of 1:1;
[0044] The oxide is a mixture of zirc...
Embodiment 3
[0047] A kind of anti-reflection coating liquid, its preparation method comprises the following steps:
[0048] (1) Slowly add 10% silicone oil-modified silicone resin dropwise to 5% nano-silica and 10% hollow silica for surface modification;
[0049] Among them, the average particle diameter of nano-silica is 80nm, and the average particle diameter of hollow silica is 110nm;
[0050] After surface modification treatment, the organosilicon modifier is attached to the surface of nano-silica and hollow silica particles, making the combination between the particles stronger.
[0051] (2) 5% nano silicon dioxide and 10% hollow silicon dioxide, 3% oxide, 40% deionized water and 2% acetic acid after the above-mentioned surface modification treatment are added in 30% butanediol monoethyl ether, React at 80°C for 5h;
[0052] The oxide is a mixture of titanium dioxide and zirconium dioxide at a mass ratio of 1:1.
[0053] (3) After cooling while stirring, the anti-reflection coatin...
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Abstract
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