A nanoparticle composite antibacterial and mildew-proof diatom mud
An antibacterial, antifungal, and nanoparticle technology, applied in the field of coatings, can solve the problems of easy aging, mildew, and shedding, and achieve the effects of improving crosslinking density and weather resistance, improving antibacterial performance, and enhancing force
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Embodiment 1
[0046] 100 grams of diatomite, 30 grams of kaolin, 5 grams of quartz sand, 20 grams of polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica, 1 gram of methyl hydroxyethyl cellulose, 0.2 grams of quicklime, 10 grams of heavy calcium carbonate and 5 grams of sepiolite powder are added into the mixer and fully mixed for 100 minutes, then the material is discharged, and the stirring rate is 2000 rpm;
[0047] The preparation method of the polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica is:
[0048] (1) In a dry 1000 ml three-neck flask, add 0.1 mol of p-1,12-dibromododecane, 0.02 mol of 1,4-dimethylpiperazine, 0.072 mol of ampromazine and dimethyl sulfoxide 50ml, after reacting at 50°C for 5h, dimethyl sulfoxide was removed by distillation under reduced pressure to obtain polyquaternium salt;
[0049] (2) In a dry 1000 ml three-neck flask connected with a stirrer, first add 200 grams of polyphosphoric acid, pass through n...
Embodiment 2
[0052]100 grams of diatomite, 50 grams of kaolin, 10 grams of quartz sand, 50 grams of polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica, 10 grams of methyl hydroxyethyl cellulose, 10 grams of quicklime, 20 grams of heavy calcium carbonate and 10 grams of sepiolite powder are added into the mixer and mixed thoroughly for 100 minutes, then the material is discharged, and the stirring speed is 2000 rpm;
[0053] The preparation method of the polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica is:
[0054] (1) In a dry 1000 ml three-neck flask, add 0.1 mol of p-1,12-dibromododecane, 0.02 mol of 1,4-dimethylpiperazine, 0.072 mol of ampromazine and dimethyl sulfoxide 50ml, after reacting at 50°C for 5h, dimethyl sulfoxide was removed by distillation under reduced pressure to obtain polyquaternium salt;
[0055] (2) In a dry 1000 ml three-neck flask connected with a stirrer, first add 200 grams of polyphosphoric acid, pass t...
Embodiment 3
[0058] 100 grams of diatomite, 44 grams of kaolin, 8 grams of quartz sand, 46 grams of polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica, 7 grams of methyl hydroxyethyl cellulose, 6 grams of quicklime, 13 grams of heavy calcium carbonate and 7 grams of sepiolite powder are added to the mixer and mixed fully for 100 minutes, then the material is discharged, and the stirring rate is 2000 rpm;
[0059] The preparation method of the polyquaternium-polyvinyl alcohol-polybenzimidazole composite coated nano-silica is:
[0060] (1) In a dry 1000 ml three-neck flask, add 0.1 mol of p-1,12-dibromododecane, 0.02 mol of 1,4-dimethylpiperazine, 0.072 mol of ampromazine and dimethyl sulfoxide 50ml, after reacting at 50°C for 5h, dimethyl sulfoxide was removed by distillation under reduced pressure to obtain polyquaternium salt;
[0061] (2) In a dry 1000 ml three-neck flask connected with a stirrer, first add 200 grams of polyphosphoric acid, pass through nitr...
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