Synergistically modified cobalt lithium fluorophosphate cathode material and preparation method thereof
A lithium cobalt fluorophosphate, cathode material technology, applied in nanotechnology for materials and surface science, battery electrodes, electrical components, etc., can solve problems such as low conductivity and poor cycle performance, achieve high energy density, improve Electronic conductivity, effect of protecting structural stability
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[0033] Example 1
[0034] (1) Put LiOH . H 2 O, Co(CH 3 COO) 2 . 4H 2 O, Ni(CH 3 COO) 2 . 4H 2 O, LiF according to the ratio of the amount of Li: Co: Ni: F substance is 2.02: 0.93: 0.07:1 in deionized water, stir evenly, add H 3 PO 4 , LiF press PO 4 3- : The ratio of the amount of F substance is 1:1 H 3 PO 4 Drop into the above solution, continue to stir for 8 min, transfer it to the autoclave, hydrothermally heat at 200°C for 11 h, cool to room temperature naturally, take it out, and dry to obtain the precursor;
[0035] (2) After mixing the above-mentioned nickel-doped precursor and carbon in Ketjen Black / ascorbic acid at a mass ratio of 95:5, dry milling, tableting, pre-burning at 350°C for 6h in an argon atmosphere, followed by furnace Cool down, take out, grind, press tablets, calcine at 650℃ for 5 h, get Li 2 Co 0.93 Ni 0.07 PO 4 F / C material;
[0036] (3) Weigh 0.5 g of silica powder into a beaker, add ionized water, ultrasonicate for 30 minutes, and then add 1.0 g of the abo...
Example Embodiment
[0037] Example 2
[0038] (1) Put LiOH . H 2 O, Co(NO 3 ) 2 . 6H 2 O, Ni(NO 3 ) 2 . 6H 2 O, LiF according to the ratio of the amount of Li: Co: Ni: F substance is 2.02:0.93:0.07:1 in deionized water, stir evenly, add NH 4 H 2 PO 4 , LiF press PO 4 3- : The ratio of the amount of F substance is 1:1 NH 4 H 2 PO 4 Add to the above solution, continue to stir for 15 min, transfer it to the autoclave, hydrothermally at 180°C for 15 h, cool to room temperature naturally, take it out, and dry to obtain the precursor;
[0039] (2) After mixing the above-mentioned nickel-doped precursor and the carbon in glucose / sucrose at a mass ratio of 90:10, add an appropriate amount of ethanol, wet mill, dry at 60°C, grind, and press, under argon atmosphere, Pre-fired at 400°C for 4 hours, put the sample into water for quenching, grinding, tableting, and calcining at 700°C for 4 hours to obtain Li 2 Co 0.93 Ni 0.07 PO 4 F / C material;
[0040] (3) Weigh 1.0 g of pH=8.5 nano-silica dispersion (30.2%) into a...
Example Embodiment
[0041] Example 3
[0042] (1) Put LiCH 3 COO . 2H 2 O, CoSO 4 . 7H 2 O, NiSO 4 . 6H 2 O, HF according to the ratio of the amount of Li: Co: Ni: F substance is 2.02: 0.93: 0.07:1 in deionized water, stir evenly, add NH 4 H 2 PO 4 , LiF press PO 4 3- : The ratio of the amount of F substance is 1:1 NH 4 H 2 PO 4 Add to the above solution, continue to stir for 20 min, transfer it to the autoclave, hydrothermally at 120°C for 20 h, cool to room temperature naturally, take it out, and dry to obtain the precursor;
[0043] (2) After mixing the above-mentioned nickel-doped precursor and the carbon in carbon nanofibers / pyrrole at a mass ratio of 85:15, dry grinding, tableting, pre-sintering at 300°C for 7 h in an argon atmosphere, continuous Calcined at 600℃ for 5 h to obtain Li 2 Co 0.93 Ni 0.07 PO 4 F / C material;
[0044] (3) Weigh 1.0 g of silica particles in a beaker, add ionized water, ultrasound for 90 min, and then add 1.0 g of the above Li 2 Co 0.93 Ni 0.07 PO 4 F / C material, magnetic...
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