Sticky diaphragm for power battery and its preparation method
A power battery, viscous technology, applied in the direction of secondary batteries, battery pack parts, separators/films/diaphragms/spacers, etc. , poor safety and other problems, to achieve the effect of improving wettability and liquid absorption, improving heat shrinkage, and reducing heat shrinkage performance
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Embodiment 1
[0037] A method for preparing a water-based adhesive diaphragm for a power battery, comprising the following steps:
[0038] S1, 100g Al 2 o 3 Mix powder, 0.6g dispersant, 1g defoamer and appropriate amount of water, stir for 2 hours at a speed of 1500r / min, then add 8g of binder, stir evenly at a speed of 600r / min, and obtain an inorganic solid with a mass fraction of 40% oxide predispersion;
[0039] S2. Coating the inorganic solid oxide predispersion on a polyethylene film with a thickness of 12 μm, and drying to obtain a first separator with a coating thickness of 4 μm;
[0040] S3. Add an appropriate amount of wetting agent and 5 g of adhesion promoter to 100 g of aqueous polyvinylidene fluoride solution, and stir evenly at a speed of 500 r / min to obtain a viscous slurry with a mass fraction of 20%, and the weight of the viscous slurry and wetting agent The ratio is 100:0.4;
[0041] S4. Apply the viscous slurry to the surface of the first separator by gravure coating...
Embodiment 2
[0044] A method for preparing a water-based adhesive diaphragm for a power battery, comprising the following steps:
[0045] S1, 100g Al 2 o 3 Powder, 0.5g dispersant, 0.8g defoamer and appropriate amount of water were stirred at a speed of 1500r / min for 2 hours, then 6g of binder was added, and stirred evenly at a speed of 600r / min to obtain an inorganic solid oxide with a mass fraction of 35%. substance pre-dispersion;
[0046] S2. Coating the inorganic solid oxide predispersion on a polyethylene film with a thickness of 12 μm, and drying to obtain a first separator with a coating thickness of 3 μm;
[0047] S3. Add an appropriate amount of wetting agent and 3 g of adhesion promoter to 100 g of aqueous polyvinylidene fluoride solution, and stir evenly at 500 r / min to obtain a viscous slurry with a mass fraction of 15%, and the weight ratio of the viscous slurry to the wetting agent for 100:0.4;
[0048] S4. Apply the viscous slurry to the surface of the first separator b...
Embodiment 3
[0050] A method for preparing a water-based adhesive diaphragm for a power battery, comprising the following steps:
[0051] S1. Stir 100g boehmite powder, 0.5g dispersant, 0.8g defoamer and appropriate amount of water at a speed of 1500r / min for 2h, then add 6g of binder, stir evenly at a speed of 500r / min to obtain the mass fraction 30% inorganic solid oxide pre-dispersion;
[0052] S2. Coating the inorganic solid oxide predispersion on a polyethylene film with a thickness of 12 μm, and drying to obtain a first separator with a coating thickness of 2 μm;
[0053] S3. Add an appropriate amount of wetting agent and 3 g of adhesion promoter to 100 g of aqueous polyvinylidene fluoride solution, and stir evenly at a speed of 500 r / min to obtain a viscous slurry with a mass fraction of 15%, and the weight of the viscous slurry and wetting agent The ratio is 100:0.4;
[0054] S4. Apply the viscous slurry on both sides of the first separator by spraying, and dry to obtain a viscou...
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