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Water-resistant polyurethane adhesive

A polyurethane adhesive and water resistance technology, applied in the direction of polyurea/polyurethane adhesives, adhesives, adhesive additives, etc., can solve problems such as poor water resistance, improve initial and final adhesive strength, water resistance The effect of excellent performance and high bond strength

Inactive Publication Date: 2018-05-18
阜阳市龙建包装材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although a variety of polyurethane adhesives have been disclosed, the existing polyurethane adhesives have poor water resistance, which limits their use in some special environments

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A kind of water-resistant polyurethane adhesive proposed by the present invention, its raw materials include by weight: 50 parts of polyisocyanate, 5 parts of poly-1,4-butylene adipate diol, polyε-caprolactone diol 35 parts of alcohol, 3 parts of lignin, 1.5 parts of catalyst, 10 parts of polyethyleneimine, 3.2 parts of terpene resin, 1 part of nano titanium dioxide, 8 parts of nano silicon dioxide, 1 part of titanium diboride, 1.5 parts of ferrous sulfate , 8 parts of composite flame retardant, 3 parts of polystyrene, 0.8 part of glycerin, 2 parts of triethanolamine, 35 parts of solvent, and 0.01 part of coupling agent.

Embodiment 2

[0017] A water-resistant polyurethane adhesive proposed by the present invention, its raw materials include by weight: 15 parts of polyisocyanate, 20 parts of poly-1,4-butylene adipate diol, polyε-caprolactone diol 10 parts of alcohol, 25 parts of lignin, 0.3 parts of catalyst, 22 parts of polyethyleneimine, 1 part of terpene resin, 3 parts of nano titanium dioxide, 2 parts of nano silicon dioxide, 3.5 parts of titanium diboride, 0.2 parts of ferrous sulfate , 2 parts of composite flame retardant, 15 parts of polystyrene, 0.1 part of glycerin, 8 parts of triethanolamine, 15 parts of solvent, and 0.18 part of coupling agent.

Embodiment 3

[0019] A kind of water-resistant polyurethane adhesive proposed by the present invention, its raw materials include by weight: 43 parts of polyisocyanate, 9 parts of poly-1,4-butylene adipate diol, polyε-caprolactone diol 32 parts of alcohol, 9 parts of lignin, 1.3 parts of catalyst, 14 parts of polyethyleneimine, 3 parts of terpene resin, 1.5 parts of nano titanium dioxide, 7 parts of nano silicon dioxide, 1.6 parts of titanium diboride, 1.3 parts of ferrous sulfate , 3.2 parts of composite flame retardant, 13 parts of polystyrene, 0.2 parts of glycerin, 7 parts of triethanolamine, 20 parts of solvent, and 0.13 parts of coupling agent;

[0020] Wherein, the polyisocyanate is hexamethylene diisocyanate;

[0021] The catalyst is 2,2-dimorpholino diethyl ether;

[0022] The composite flame retardant is bis(4-aminophenoxy) phenyl phosphorus oxide, 2-phenoxy (3-hydroxyl)-phosphorus oxide, aziridine polyphosphazene, aluminum sulfate, zirconium phosphate by weight as a mixture of ...

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PUM

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Abstract

The invention discloses a water-resistant polyurethane adhesive. The water-resistant polyurethane adhesive comprises raw materials in parts by weight as follows: 15-50 parts of polyisocyanates, 5-20 parts of poly(1,4-butylene adipate), 10-35 parts of poly epsilon-caprolactone diol, 3-25 parts of lignin, 0.3-1.5 parts of a catalyst, 10-22 parts of polyethyleneimine, 1-3.2 parts of terpene resin, 1-3 parts of nano-titania, 2-8 parts of nano-silica, 1-3.5 parts of titanium diboride, 0.2-1.5 parts of ferrous sulfate, 2-8 parts of a composite flame retardant, 3-15 parts of polystyrene, 0.1-0.8 parts of glycerin, 2-8 parts of triethanolamine, 15-35 parts of a solvent and 0.01-0.18 parts of a coupling agent. The water-resistant polyurethane adhesive has high bonding strength, excellent water resistance and good flame retardance.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a water-resistant polyurethane adhesive. Background technique [0002] Polyurethane adhesives refer to adhesives containing carbamate groups or isocyanate groups in the molecular chain. Because of their excellent bonding performance and good flexibility, impact resistance, solvent resistance, abrasion resistance, It is widely used in civil, sports, aerospace, military and other fields due to its flexibility and low temperature resistance, and has become one of the indispensable important materials. Although a variety of polyurethane adhesives have been disclosed, the existing polyurethane adhesives have poor water resistance, which limits their use in some special environments. Contents of the invention [0003] Based on the technical problems in the background technology, the present invention proposes a water-resistant polyurethane adhesive, which has high bonding strength...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/06C09J145/00C09J125/06C09J11/04C09J11/06C09J11/08C08G18/64C08G18/42
CPCC08G18/4081C08G18/4202C08G18/4238C08G18/4277C08G18/6423C08G18/6492C08K2003/2241C08K2201/011C08L2201/02C08L2201/08C08L2205/035C09J11/04C09J11/06C09J11/08C09J175/06C08L45/00C08L25/06C08K13/02C08K3/22C08K3/36C08K3/38C08K3/30C08K5/053
Inventor 马龙建
Owner 阜阳市龙建包装材料有限公司