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Heat conduction and storage multifunctional pouring silica gel and preparation method thereof

A multi-functional, silica gel technology, applied in chemical instruments and methods, adhesives, heat exchange materials, etc., can solve the problems of limited adsorption capacity of phase change materials, potting applications in unfavorable conductive occasions, affecting the insulation performance of potting silica gel, etc. Achieve the effect of avoiding the serious problems of melt flow and infiltration migration and graphite conduction, good heat storage and temperature control, and improved mechanical properties

Active Publication Date: 2018-05-29
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the heat conduction agent in the phase change composite material in this patent application is expanded graphite, which has limited adsorption capacity for phase change materials, and repeated use will cause serious problems of melt flow and permeation migration of phase change materials; in addition, expanded graphite heat conduction fillers It will seriously affect the insulation performance of potting silica gel, which is not conducive to the potting application in conductive occasions. As a thermal management system for power batteries, it has a great impact on the overall safety and reliability of power batteries, so it is not suitable for popularization and application; secondly, the The heat-conducting agent used in the heat-conducting silica gel in the patent application is alumina and magnesia, which have not undergone surface treatment, and the compatibility between the directly added filler and the silica gel matrix is ​​poor, resulting in the uniform dispersion of the heat-conducting filler in the silica gel matrix Poor performance, increased thermal resistance at the phase interface between filler / matrix, and poor thermal conductivity

Method used

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  • Heat conduction and storage multifunctional pouring silica gel and preparation method thereof
  • Heat conduction and storage multifunctional pouring silica gel and preparation method thereof
  • Heat conduction and storage multifunctional pouring silica gel and preparation method thereof

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preparation example Construction

[0045]The phase-change microcapsules described in the present invention can be commercially available phase-change microcapsules, for example, paraffin alkane can be used as the core material, urea-formaldehyde resin is used as the shell, and a thermally conductive filler is also contained. The thermally conductive filler is coated with paraffin wax in the urea-formaldehyde resin. The low-temperature heat-controlled phase-change microcapsules are added in the alkane process, and the heat-conducting filler is added in an amount of 5% to 30% of the paraffin alkane mass percentage. The specific preparation method of the low-temperature thermally controlled phase change microcapsules, for example, may include: the first step, paraffin alkane preheating; the second step, urea-formaldehyde resin prepolymer synthesis; the third step, styrene maleic anhydride resin solution , water and inorganic salt polymerization; the fourth step, the materials are mixed to obtain the mixture; the fi...

Embodiment 1

[0064] ① First mix the nano-alumina powders with a particle size of 15 μm and 30 μm evenly according to the mass ratio of 1:4, then weigh 14g of uniformly mixed thermal conductive filler and 0.14g of silane coupling agent n-octyltriethoxysilane, and put N-octyltriethoxysilane and water were prepared into a solution at a molar ratio of 1:3, and an appropriate amount of ethanol was added to mix evenly, and left to stand for 20 minutes. Slowly add the hydrolyzed silane coupling agent solution into the thermally conductive filler, stir well until it is uniformly dispersed, and heat and stir the mixed solution in a water bath at 65°C, so that the hydrolyzed silane coupling agent can perform surface treatment on the thermally conductive filler , to obtain a surface-treated thermally conductive filler mixture. Centrifuge the surface-treated thermally conductive filler mixture at a centrifugal speed of 1500r / min for 6 minutes for solid-liquid separation and separate the thermally cond...

Embodiment 2

[0072] ① Mix 15μm and 30μm nano-alumina powders evenly according to the mass ratio of 1 / 4, then weigh 14g of uniformly mixed thermal conductive filler and 0.14g of silane coupling agent n-octyltriethoxysilane, and n-octyltriethoxysilane Ethoxysilane and water were formulated into a solution at a molar ratio of 1:3, and an appropriate amount of ethanol was added to mix evenly, and left to stand for 20 minutes. Slowly add the hydrolyzed silane coupling agent solution into the thermally conductive filler, stir well until it is uniformly dispersed, and heat and stir the mixed solution in a water bath at 65°C, so that the hydrolyzed silane coupling agent can perform surface treatment on the thermally conductive filler , to obtain a surface-treated thermally conductive filler mixture. Centrifuge the surface-treated thermally conductive filler mixture at a centrifugal speed of 1500r / min for 6 minutes for solid-liquid separation and separate the thermally conductive filler solid matte...

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Abstract

The invention relates to heat conduction and storage multifunctional pouring silica gel and a preparation method thereof. The heat conduction and storage multifunctional pouring silica gel consists ofthe following components in percentage by mass: 40-89% of double-component pouring silica gel, 5-20% of phase-change microcapsules, 5-20% of heat conduction packing after surface treatment, and 1-20%of a flame retardant, wherein the heat conduction packing consists of small particle size heat conduction packing and large particle size heat conduction packing through mixing. The preparation method comprises the following steps: performing surface treatment on the heat conduction packing; preparing the heat conduction and storage composite packing; preparing the double-component pouring silicagel; preparing components A1 and B1 of the heat conduction and storage multifunctional pouring silica gel; preparing the heat conduction and storage multifunctional pouring silica gel. Due to surfacetreatment on heat conduction packing of different particle sizes, the dispersibility of the packing in a silica gel substrate is improved, the heat conduction properties of the heat conduction and storage multifunctional pouring silica gel are improved, and due to addition of the phase-change microcapsules, the heat conduction and storage multifunctional pouring silica gel has heat storage temperature control properties.

Description

technical field [0001] The invention relates to the technical field of battery heat management, in particular to a heat conduction heat storage multifunctional potting silica gel and a preparation method thereof. Background technique [0002] Batteries such as secondary batteries have been widely used as energy sources for wireless mobile devices, such as power sources for electric vehicles, hybrid electric vehicles, and plug-in hybrid electric vehicles, etc., thereby solving problems caused by vehicles using petroleum fuels. For issues such as air pollution, small wireless mobile devices may use one or more battery cells, while medium or large wireless devices such as vehicles may use medium or large battery modules that include multiple battery cells connected to each other. Or large battery modules are usually manufactured to have the smallest possible size and weight, so the battery cells stacked in these battery modules are highly integrated. [0003] During charging a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J183/07C09J11/08C09J11/04C09J11/06C09K5/14H01M10/613H01M10/653H01M10/659
CPCH01M10/613H01M10/653H01M10/659C09J11/04C09J11/06C09J11/08C09J183/04C09K5/14C08K2003/2227C08K2201/014C08K2201/003C08L2205/035C08L2205/025C08L83/04C08L45/00C08K13/06C08K9/06C08K3/22C08K5/06C08K3/2279Y02E60/10
Inventor 张雅倩金兆国陈建党广洲张靖驰纪旭阳刘斌张天翔
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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