Heat conduction and storage multifunctional pouring silica gel and preparation method thereof
A multi-functional, silica gel technology, applied in chemical instruments and methods, adhesives, heat exchange materials, etc., can solve the problems of limited adsorption capacity of phase change materials, potting applications in unfavorable conductive occasions, affecting the insulation performance of potting silica gel, etc. Achieve the effect of avoiding the serious problems of melt flow and infiltration migration and graphite conduction, good heat storage and temperature control, and improved mechanical properties
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[0045]The phase-change microcapsules described in the present invention can be commercially available phase-change microcapsules, for example, paraffin alkane can be used as the core material, urea-formaldehyde resin is used as the shell, and a thermally conductive filler is also contained. The thermally conductive filler is coated with paraffin wax in the urea-formaldehyde resin. The low-temperature heat-controlled phase-change microcapsules are added in the alkane process, and the heat-conducting filler is added in an amount of 5% to 30% of the paraffin alkane mass percentage. The specific preparation method of the low-temperature thermally controlled phase change microcapsules, for example, may include: the first step, paraffin alkane preheating; the second step, urea-formaldehyde resin prepolymer synthesis; the third step, styrene maleic anhydride resin solution , water and inorganic salt polymerization; the fourth step, the materials are mixed to obtain the mixture; the fi...
Embodiment 1
[0064] ① First mix the nano-alumina powders with a particle size of 15 μm and 30 μm evenly according to the mass ratio of 1:4, then weigh 14g of uniformly mixed thermal conductive filler and 0.14g of silane coupling agent n-octyltriethoxysilane, and put N-octyltriethoxysilane and water were prepared into a solution at a molar ratio of 1:3, and an appropriate amount of ethanol was added to mix evenly, and left to stand for 20 minutes. Slowly add the hydrolyzed silane coupling agent solution into the thermally conductive filler, stir well until it is uniformly dispersed, and heat and stir the mixed solution in a water bath at 65°C, so that the hydrolyzed silane coupling agent can perform surface treatment on the thermally conductive filler , to obtain a surface-treated thermally conductive filler mixture. Centrifuge the surface-treated thermally conductive filler mixture at a centrifugal speed of 1500r / min for 6 minutes for solid-liquid separation and separate the thermally cond...
Embodiment 2
[0072] ① Mix 15μm and 30μm nano-alumina powders evenly according to the mass ratio of 1 / 4, then weigh 14g of uniformly mixed thermal conductive filler and 0.14g of silane coupling agent n-octyltriethoxysilane, and n-octyltriethoxysilane Ethoxysilane and water were formulated into a solution at a molar ratio of 1:3, and an appropriate amount of ethanol was added to mix evenly, and left to stand for 20 minutes. Slowly add the hydrolyzed silane coupling agent solution into the thermally conductive filler, stir well until it is uniformly dispersed, and heat and stir the mixed solution in a water bath at 65°C, so that the hydrolyzed silane coupling agent can perform surface treatment on the thermally conductive filler , to obtain a surface-treated thermally conductive filler mixture. Centrifuge the surface-treated thermally conductive filler mixture at a centrifugal speed of 1500r / min for 6 minutes for solid-liquid separation and separate the thermally conductive filler solid matte...
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