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Absorbent for heavy metal elements in sewage and preparation method thereof

A heavy metal and absorbent technology, applied in water/sewage treatment, chemical instruments and methods, adsorbed water/sewage treatment, etc., can solve the problem of poor removal of heavy metals, and achieve good removal effect, large adsorption capacity, and efficient removal. Effect

Active Publication Date: 2020-08-28
安徽宏远职业卫生技术服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are many reports on modified starch, but there are great limitations due to the poor removal effect on heavy metals.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] An absorbent for heavy metal elements in sewage proposed by the present invention is made of the following raw materials in parts by weight: 20 parts of modified starch, 20 parts of pomegranate peel extract, 10 parts of chelated fiber, 8 parts of polyepoxysuccinic acid, carboxylic acid 5 parts of methyl chitosan, 5 parts of citric acid, 2 parts of disinfectant.

[0021] The present invention also proposes a preparation method for the heavy metal element absorbent in the above-mentioned sewage, comprising the following steps:

[0022] S1. Grinding and pulverizing the pomegranate peel extract to obtain pomegranate peel extract powder;

[0023] S2. Mix the pomegranate peel extract powder, modified starch, chelating fiber, polyepoxysuccinic acid, carboxymethyl chitosan, and citric acid, stir evenly, microwave heating, heat preservation, and cooling to obtain the mixture;

[0024] S3. Add disinfectant to the mixture and mix evenly, vacuum dry, cool, grind and pulverize.

Embodiment 2

[0026] An absorbent for heavy metal elements in sewage proposed by the present invention is made of the following raw materials in parts by weight: 50 parts of modified starch, 35 parts of pomegranate peel extract, 15 parts of chelating fiber, 17 parts of polyepoxysuccinic acid, carboxylic acid 15 parts of methyl chitosan, 10 parts of citric acid, 7 parts of disinfectant.

[0027] Wherein, the modification method of modified starch is as follows: dissolving sodium tripolyphosphate with distilled water to obtain sodium tripolyphosphate solution; 6-7. Precipitate after standing, wash with water, filter with suction, dry, and grind to obtain cross-linked starch; add water to the cross-linked starch and stir evenly, heat and gelatinize, cool down, feed nitrogen, add cerium ammonium nitrate and N , N-dimethylacetamide, stirring and reacting, then adding methyl acrylate, sealing the reaction, cooling to room temperature, adjusting the pH to 6-7, adding ethylenediamine, stirring and ...

Embodiment 3

[0033] An absorbent for heavy metal elements in sewage proposed by the present invention is made of the following raw materials in parts by weight: 35 parts of modified starch, 28 parts of pomegranate peel extract, 12 parts of chelated fiber, 13 parts of polyepoxysuccinic acid, carboxylic acid 10 parts of methyl chitosan, 8 parts of citric acid, 4 parts of disinfectant.

[0034] Among them, the modification method of modified starch is as follows: 0.6 parts of sodium tripolyphosphate are dissolved with distilled water to obtain sodium tripolyphosphate solution; 55 parts of 3% sodium carbonate solution are added to 26 parts of sweet potato starch and stirred evenly, and placed in ℃ in a constant temperature water bath, slowly add ammonium tripolyphosphate solution dropwise within 5 minutes, react for 3.5 hours, adjust the pH to 6-7, settle after standing, wash with water, filter with suction, dry and grind to obtain cross-linked starch; take 12 65 parts of cross-linked starch, ...

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Abstract

The invention discloses an absorbent for heavy metal elements in sewage and a preparation method thereof, and relates to the technical field of sewage treatment. The absorbent is made of the following raw materials in parts by weight: 20-50 parts of modified starch, 20-50 parts of pomegranate peel extract 35 parts, 10-15 parts of chelating fiber, 8-17 parts of polyepoxysuccinic acid, 5-15 parts of carboxymethyl chitosan, 5-10 parts of citric acid, 2-7 parts of disinfectant. Among the present invention, take modified starch, pomegranate peel extract as main raw material, take chelating fiber, polyepoxysuccinic acid, carboxymethyl chitosan, citric acid, disinfectant as auxiliary material, the absorbent prepared has a good effect on sewage The adsorption capacity of heavy metal elements is large, the removal rate is high, the removal effect is good, and it will not cause secondary pollution.

Description

technical field [0001] The invention relates to the technical field of sewage treatment, in particular to an absorbent for heavy metal elements in sewage and a preparation method thereof. Background technique [0002] In recent years, with the rapid development of economy and the rapid improvement of industry, society has made great progress, but at the same time, human beings are also facing more and more serious environmental problems. The main environmental problem at present is the pollution of heavy metals. The sources and quantities of heavy metals are increasing and the water quality is becoming more and more complex, which poses more and more serious threats to the natural environment and human health. Therefore, the treatment of heavy metals has become an issue of great concern. The so-called heavy metals refer to metals with high specific gravity, that is, the density exceeds 4.5g / cm3, but only 10 heavy metal elements are really classified as heavy metals in the i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/00C02F1/50C02F1/28C08F251/00C08F220/14C02F101/20
CPCC02F1/00C02F1/28C02F1/285C02F1/286C02F1/50C02F2101/20C02F2303/04C08F251/00C08F220/14
Inventor 夏怀翔赵华芝孔玉萍严章飞方栋张强段志祥
Owner 安徽宏远职业卫生技术服务有限公司