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Preparation method of porous fly ash adsorbent and application of adsorbent

An adsorbent and fly ash technology, which is applied in the field of preparation of porous fly ash adsorbent for removing Hg0 from coal-fired flue gas, can solve the problems of complex process, high cost, poor cycle stability, etc., and achieve simple preparation process, Inexpensive and easy to remove

Active Publication Date: 2018-06-22
TAIYUAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The invention provides a preparation method of a porous fly ash adsorbent and the application of the adsorbent to solve the problem of removing Hg from coal-fired flue gas in the existing preparation. 0 The process of adsorbent is complicated, the cost is high, the prepared adsorbent has low removal precision, poor cycle stability and other problems

Method used

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  • Preparation method of porous fly ash adsorbent and application of adsorbent

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Experimental program
Comparison scheme
Effect test

Embodiment approach 1

[0021] Weigh 100g of sieved fly ash with a particle size of 0.1-0.15mm, mix with 40g of CaO powder, add 40ml

[0022] The deionized water is configured into a mixed solution and placed in a conical flask. After the conical flask is placed in a water bath and stirred at a constant speed for 20 min at 50 °C, the excess liquid is filtered off, and the obtained slurry sample is placed in an air drying oven. Dry at 60°C for 10 hours to obtain powdered fly ash aggregate, and then mix the fly ash aggregate powder with sodium bentonite, sodium carboxymethyl cellulose and powdered corncob in a mass ratio of 12:4:2:1, Add 30ml of deionized water and extrude into cylindrical pellets with a diameter of 2mm and a height of 3mm, and put them in an air drying oven to dry at 50 and 90°C for 5h respectively, and finally rise from room temperature to 700°C in a muffle furnace. The porous fly ash adsorbent I was prepared at constant temperature for 5h and naturally cooled to room temperature. R...

Embodiment approach 2

[0024] Weigh 80g of sieved fly ash with a particle size of 0.1-0.15mm, mix with 20g of CaO powder, add 40ml

[0025] The deionized water is configured into a mixed solution and placed in a conical flask. After the conical flask is placed in a water bath and stirred at a constant speed for 25 min at 47 °C, the excess liquid is filtered off, and the obtained slurry sample is placed in an air drying oven. Dry at 68°C for 8 hours to obtain powdered fly ash aggregate, and then mix the fly ash aggregate powder with sodium bentonite, sodium carboxymethyl cellulose and powdered corncob in a mass ratio of 12:5:1:2, Add 30ml of deionized water and extrude to make cylindrical particles with a diameter of 2mm and a height of 2mm, and put them in an air drying oven to dry at 50 and 90 °C for 5 hours, and finally in a muffle furnace from room temperature to 760 °C. The porous fly ash adsorbent II was prepared at constant temperature for 3h and naturally cooled to room temperature. The remo...

Embodiment approach 3

[0027] Weigh 80g of sieved fly ash with a particle size of 0.1-0.15mm, mix with 20g of CaO powder, add 40ml

[0028] The deionized water is configured as a mixed solution and placed in a conical flask. After the conical flask is placed in a water bath and stirred at a constant speed for 20 min at 50 °C, the excess liquid is filtered off, and the obtained slurry sample is placed in an air drying oven. Dry at 60°C for 10 hours to obtain powdered fly ash aggregate, and then mix the fly ash aggregate powder with sodium bentonite, sodium carboxymethyl cellulose and powdered corncob in a mass ratio of 12:5:1:3, Add 30ml of deionized water and extrude to make cylindrical particles with a diameter of 3mm and a height of 3mm, and put them in an air drying oven to dry at 50 and 90 °C for 5 hours respectively, and finally increase the temperature from room temperature to 730 °C in a muffle furnace. The porous fly ash adsorbent III was prepared by maintaining at constant temperature for 3...

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Abstract

The invention provides a preparation method of a porous fly ash adsorbent and application of the adsorbent. The method takes metal oxide Fe2O3 and MgO in coal combustion fly ash which is used as an adsorbent matrix and effectively components for oxidizing and adsorbing HgO; while fly ash aggregate is prepared, CaO is changed into Ca(OH)2 and the porosity of the fly ash aggregate is also increased;the application is that the adsorbent is used for removing the HgO in coal combustion flue gas in a high-precision manner in a temperature range of 80 to 300 DEG C until the content of the HgO is 4mug / m<3>. The adsorbent prepared by the method has a relatively good pore structure and the specific surface area is greater than 180m<2> / g; the fly ash, corncobs, sodium bentonite and sodium carboxymethyl cellulose are cheap and easy to obtain; a preparation technology is simple and feasible; the adsorbent has relatively good mechanical strength which is greater than 60N / mm<2>, and can be widely used for removing the HgO in various coal combustion flue gases.

Description

technical field [0001] The invention relates to a preparation method of a porous fly ash adsorbent and application of the adsorbent, in particular to a method for removing Hg from coal-fired flue gas 0 Preparation method of porous fly ash adsorbent and application of the adsorbent. Background technique [0002] Coal is an important fossil energy, and its clean transformation is important for sustainable development. Coal combustion for power generation is the main way of coal utilization at present. From January 1, 2015, the emission limit of mercury and its compounds in the flue gas of coal-fired boilers is 30 μg / m 3 On August 16, 2017, China is a signatory to the Global Mercury Pollution Control Convention, the Minamata Convention on Mercury, which came into effect, further strengthening the emphasis on mercury emissions. Therefore, the problem of mercury pollution in coal-fired flue gas is becoming more and more important. Become the focus of attention, in coal-fired fl...

Claims

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Application Information

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IPC IPC(8): B01J20/20B01D53/02B01J20/30
Inventor 樊保国郑仙荣柳成亮郝海俊耿瑞明乔晓磊
Owner TAIYUAN UNIV OF TECH