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A method for in situ formation of graphene and onion at friction interface to achieve super-slip

A technology of friction interface and graphene, which is applied in the direction of metal material coating process, coating, gaseous chemical plating, etc., can solve the problem of weak, high external dependence, lack of stability of key components and core technologies and high-end equipment and reliability issues to achieve the effect of reducing friction coefficient and wear rate and improving service life

Active Publication Date: 2019-11-05
LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] The scale of my country's manufacturing industry has jumped to the first place in the world, but it is large but not strong and not refined. Key components, core technologies and high-end equipment lack stability and reliability, resulting in a high degree of external dependence. These have become bottlenecks restricting the development of high-tech industries.

Method used

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  • A method for in situ formation of graphene and onion at friction interface to achieve super-slip
  • A method for in situ formation of graphene and onion at friction interface to achieve super-slip
  • A method for in situ formation of graphene and onion at friction interface to achieve super-slip

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Example 1 Preparation and deposition of fullerene-like carbon films on silicon wafers

[0020] (1) Routine cleaning;

[0021] (2) When the vacuum in the chamber reaches 1×10 -4 Start coating at 5 Pa, argon gas is controlled at 5 Pa, bias voltage is 800 V, conduction ratio is 0.8, frequency is 50 KHz, and cleaning is 30 minutes;

[0022] (3) The pulse bias voltage is set to -1000V, the conduction ratio is 0.4, the frequency is 70 Hz; the methane is 17Pa; the film is deposited for 120 minutes and then shut down to cool down;

[0023] (4) Take out the test after the sample is cooled to room temperature. The test result shows that the film has a hardness of 30GPa, a thickness of 1.5 microns, a surface finish of 0.1 nm, and the color of the film is black.

[0024] (5) as figure 1 As shown, the typical Raman spectrum of fullerene-like carbon films includes a steamed bread peak (peak at 1527 cm -1 ) and an acromion (about 1200cm -1 ).

Embodiment 2

[0025] Example 2 Preparation of in-situ nitriding and deposition of graphitic carbon films on GCr15 spheres

[0026] The specific implementation is as follows:

[0027] (1) Conventional cleaning: degreasing, rust removal, drying and placing in a vacuum chamber;

[0028] (2) When the vacuum in the chamber reaches 1×10 -4 Start coating at 5 Pa, argon gas is controlled at 5 Pa, bias voltage is 900 V, conduction ratio is 0.8, frequency is 50 KHz, and cleaning is 30 minutes;

[0029] (3) The pulse bias is set to -800V, the conduction ratio is 0.6, the frequency is 80 Hz; nitrogen is 8Pa; nitriding is 30 minutes;

[0030] (4) The pulse bias is set to -850V, the conduction ratio is 0.5, the frequency is 50Hz; the methane is 15Pa; and it is heated to 230°C, and the film is deposited for 120 minutes and then shut down to cool down;

[0031] (5) Take out the test after the sample is cooled to room temperature. The test result shows that the hardness of the film is 27GPa, the thicknes...

Embodiment 3

[0034] The two thin films form a friction pair, forming an onion at the friction interface ( figure 2 ) and graphene ( image 3 ). The friction coefficient is adjustable at 0.005±0.002 under different load conditions ( Figure 4 ). The friction reduction mechanism can be understood as the graphene and onion formed on the friction interface can effectively reduce the contact area of ​​the friction pair or reduce the friction interface force through spherical contact or non-commensurate surface contact, such as Figure 5 shown.

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Abstract

The invention relates to a method for realizing super-lubricity of graphene and onions formed on a friction interface in site. According to the method, fullerene-like carbon and a graphite-like carbonnanostructure film are deposited on the surfaces of metal, ceramics, polymer and the like, a friction pair is formed, and the graphene and the onions are formed on the friction interface. The reasonlies in that the graphene and the onions formed on the friction interface can effectively lower the contact area of the friction pair or reduce the action force of the friction interface through spherical contact or incommensurate face-to-face contact, and therefore the friction coefficient and the abrasion rate are obviously reduced, and the purposes of prolonging the service life and improving sensitivity and reliability are realized. The aim is to solve the problem that the service life, sensitivity and reliability of existing high-end equipment, aerospace components and the like cannot meet the requirement for 10-15 years.

Description

technical field [0001] The invention belongs to the fields of vacuum coating, surface treatment, life extension of moving parts and the like, and relates to a method for in-situ formation of graphene and onions on a friction interface to realize super-slippage. Background technique [0002] The scale of my country's manufacturing industry has jumped to the first place in the world, but it is large but not strong or refined. The lack of stability and reliability of key components, core technologies and high-end equipment has resulted in a high degree of external dependence, which has become a bottleneck restricting the development of high-tech industries. . Reducing the friction and wear of mechanical moving parts has been regarded as one of the ways to effectively prolong its working life and improve the reliability and stability of its operation. For the contact interface with relative motion under actual working conditions, super-slip will fundamentally solve the problems ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C16/26C23C16/513
CPCC23C16/26C23C16/513
Inventor 张俊彦王永富高凯雄张斌
Owner LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI