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Additive for lead-acid storage battery gelled electrolyte and preparation method and application thereof

A colloidal electrolyte, lead-acid battery technology, applied in lead-acid batteries, acid electrolytes, secondary batteries, etc., can solve the problems of human health and ecological environment hazards, poor stability of lead-acid batteries, and low cycle life, etc. Effects of improved chemical stability and corrosion resistance, increased actual surface area, and improved cycle life

Active Publication Date: 2018-09-18
TIANNENG GRP HENAN ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problems in the prior art that the lead-acid battery has poor stability, large resistance, low cycle life, and the additive raw materials used in the colloidal electrolyte of the lead-acid battery are extremely harmful to human health and the ecological environment. , and proposed a lead-acid battery colloidal electrolyte additive and its preparation method and application

Method used

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  • Additive for lead-acid storage battery gelled electrolyte and preparation method and application thereof
  • Additive for lead-acid storage battery gelled electrolyte and preparation method and application thereof
  • Additive for lead-acid storage battery gelled electrolyte and preparation method and application thereof

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Embodiment 1

[0017] A kind of lead-acid accumulator colloidal electrolyte additive that the present invention proposes, comprises the raw material of following weight portion: 1 part of 1-butyl-3-methylimidazolium dodecyl sulfate, 1-allyl-3-methyl 2 parts of imidazolium chloride salt, 2 parts of nano-boron oxide, 5 parts of titanium dioxide, 8 parts of nano-titanium diboride, 1 part of graphene, 8 parts of acetylene black, 4 parts of sulfate, 7 parts of grease, polyacrylamide 1 part, 2 parts of sulfuric acid, 28 parts of distilled water; the concentration of the sulfuric acid solution is 1.02g / cm 3 .

[0018] Its preparation method comprises the following steps:

[0019] S1. Add the specific gravity of 1-allyl-3-methylimidazolium chloride, nano-boron oxide, sulfate, lubricating grease and distilled water into the agitator, stir and mix evenly at a speed of 450r / min to obtain Mixture A;

[0020] S2. Add the specific gravity of titanium oxide, nano-titanium diboride, graphene and acetylen...

Embodiment 2

[0023] A kind of lead-acid accumulator colloidal electrolyte additive that the present invention proposes, comprises the raw material of following weight portion: 1-butyl-3-methylimidazolium lauryl sulfate 3 parts, 1-allyl-3-methyl 10 parts of imidazolium chloride salt, 5 parts of nano-boron oxide, 7 parts of titanium dioxide, 12 parts of nano-titanium diboride, 4 parts of graphene, 4 parts of acetylene black, 7 parts of sulfate, 10 parts of grease, polyacrylamide 2 parts, 5 parts of sulfuric acid, 32 parts of distilled water; the concentration of sulfuric acid solution is 1.10g / cm 3 .

[0024] Its preparation method comprises the following steps:

[0025] S1. Add the specific gravity of 1-allyl-3-methylimidazolium chloride, nano-boron oxide, sulfate, lubricating grease and distilled water into the agitator, stir and mix evenly at a speed of 550r / min to obtain Mixture A;

[0026] S2. Add the specific gravity of titanium oxide, nano-titanium diboride, graphene and acetylene ...

Embodiment 3

[0029] A kind of additive for colloidal electrolyte of lead-acid storage battery that the present invention proposes, comprises the raw material of following weight portion: 5 parts of 1-butyl-3-methylimidazolium lauryl sulfates, 1-allyl-3-methyl 20 parts of imidazolium chloride salt, 7 parts of nano-boron oxide, 9 parts of titanium dioxide, 15 parts of nano-titanium diboride, 8 parts of graphene, 1 part of acetylene black, 10 parts of sulfate, 13 parts of grease, polyacrylamide 3 parts, 8 parts of sulfuric acid, 35 parts of distilled water; the concentration of the sulfuric acid solution is 1.17g / cm 3 .

[0030] Its preparation method comprises the following steps:

[0031] S1. Add the specific gravity of 1-allyl-3-methylimidazolium chloride, nano boron oxide, sulfate, lubricating grease and distilled water into the agitator, stir and mix evenly at a speed of 650r / min to obtain Mixture A;

[0032]S2. Add the specific gravity of titanium oxide, nano-titanium diboride, graph...

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Abstract

The invention belongs to the technical field of storage batteries, and particularly relates to an additive for a lead-acid storage battery gelled electrolyte and a preparation method and application thereof. In the prior art, the lead-acid storage battery has low stability, high resistance and short cycle life, and the additive raw material for the lead-acid storage battery gelled electrolyte is harmful to body health and ecological environment. The additive for the lead-acid storage battery gelled electrolyte is prepared from the following raw materials: 1-butyl-3-methyl imidazole dodecyl sulfate, 1-allyl-3-methylimidazolium chloride, nano boron oxide, titanium dioxide, nano titanium diboride, graphene, acetylene black, sulfate, lubricating grease, polyacrylamide, sulfuric acid solution,and distilled water. The additive for the lead-acid storage battery can effectively lower the battery internal resistance, enables the battery to better carry high current, increases the capacity andprolongs the cycle life of the lead-acid storage battery, thereby being worth promoting.

Description

technical field [0001] The invention relates to the technical field of storage batteries, in particular to an additive for colloidal electrolyte of lead-acid storage batteries, a preparation method and application thereof. Background technique [0002] In storage batteries, lead-acid batteries have the advantages of mature technology, cheap price, good charging and discharging performance, and safe use. As the most important stable power supply and DC power supply, they are widely used in aviation, railways, automobiles, ships, communications, and finance In various industries such as military and national defense, it has become an indispensable energy product in social production and human life. Lead-acid battery refers to a battery whose electrodes are mainly made of lead and its oxides, and the electrolyte is a sulfuric acid solution. In the discharge state of the lead-acid battery, the main component of the positive electrode is lead dioxide, and the main component of t...

Claims

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Application Information

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IPC IPC(8): H01M10/10H01M10/42B82Y30/00
CPCB82Y30/00H01M10/10H01M10/4235H01M2300/0008Y02E60/10
Inventor 王强民常传杰李亚非程可红
Owner TIANNENG GRP HENAN ENERGY TECH
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