Acrylate emulsion for plastic base materials and method for preparing acrylate emulsion

A technology of methyl methacrylate and acrylate, which is applied in the field of acrylate emulsion of plastic substrates and its preparation, can solve the problems of poor adhesion of plastic substrates, poor solvent resistance, and poor paint mixing stability, etc., and achieve good Tolerance of paint blending, improvement of gloss fullness, and effect of improving adhesion

Inactive Publication Date: 2018-09-25
佛山市顺德区巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing one-component acrylic resins often encounter problems such as poor water resistance, poor solvent resistance, poor chemical resistance, poor adhesion to plastic substrates, low gloss, and poor paint stability. Therefore, how to develop an excellent performance The acrylate emulsion used for plastic substrates is a major technical problem in the industrial plastic coating industry

Method used

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Examples

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Effect test

preparation example Construction

[0041] In addition, the present invention also provides a method for preparing the acrylate emulsion for plastic substrates, specifically comprising the following steps:

[0042] a) Preparation of bottom material liquid A: In the reaction kettle equipped with agitator, condenser and constant flow pump feeding device, add 10-30 parts of deionized water and 0.5-1 part of surfactant, and raise the temperature in the kettle to to 80-85°C;

[0043] b) Preparation of monomer solution B: butyl acrylate, methyl methacrylate, styrene, functional monomer, remaining surfactant, hydrophilic unsaturated organic acid 0.5- 2 parts, 5-10 parts of deionized water, mixed into a uniform solution, and stirred for 20-30 minutes for later use;

[0044] c) Preparation of initiator solution C: add the initiator of the formula amount into the remaining deionized water, stir and dissolve for subsequent use;

[0045] d) When the temperature in the kettle reaches 80-85°C, add 1-5 parts of the monomer s...

Embodiment 1

[0050] A kind of acrylate emulsion for plastic substrate, by weight, the acrylate emulsion comprises the following raw materials: 40 parts of deionized water, 10 parts of butyl acrylate, 25 parts of methyl methacrylate, 5 parts of styrene, 2 parts of hydrophilic unsaturated organic acid, 1 part of functional monomer, 1 part of surfactant, 0.1 part of initiator, and 1.5 parts of pH regulator.

[0051] The hydrophilic unsaturated organic acid is a mixed solution of 1 part of acrylic acid and 1 part of methacrylic acid.

[0052] The functional monomer is vinyltrimethoxysilane.

[0053] The surfactant is a combined emulsifier formed by mixing an anionic emulsifier and a nonionic emulsifier at a mass ratio of 1:1. The anionic emulsifier uses sodium dodecylsulfonate; the nonionic emulsifier uses alkylphenol polyoxyethylene ether.

[0054] The initiator is ammonium persulfate.

[0055] The pH regulator is ammonia water.

[0056] In addition, the present invention also provides a ...

Embodiment 2

[0065] A kind of acrylate emulsion for plastic substrate, by weight, the acrylate emulsion comprises the following raw materials: 45 parts of deionized water, 12 parts of butyl acrylate, 28 parts of methyl methacrylate, 7 parts of styrene, 2.5 parts of hydrophilic unsaturated organic acid, 1.5 parts of functional monomer, 1.5 parts of surfactant, 0.3 part of initiator, and 3 parts of pH regulator.

[0066] The hydrophilic unsaturated organic acid is mixed with acrylic acid and methacrylic acid at a ratio of 4:1.

[0067] The functional monomer is mixed with vinyltrimethoxysilane and methacryloxypropyltrimethoxysilane in a ratio of 2:1.

[0068] The surfactant is a combined emulsifier formed by mixing an anionic emulsifier and a nonionic emulsifier at a mass ratio of 2:1. The anionic emulsifier adopts sodium dialkyl-2-sulfosuccinate; the nonionic emulsifier adopts polyoxyethylene sorbitan monooleate.

[0069] The initiator is potassium persulfate.

[0070] The pH regulator i...

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PUM

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Abstract

The invention discloses acrylate emulsion for plastic base materials. The acrylate emulsion comprises, by weight, 40-60 parts of deionized water, 10-20 parts of butyl acrylate, 25-35 parts of methyl methacrylate, 5-10 parts of styrene, 2-5 parts of hydrophilic unsaturated organic acid, 1-3 parts of functional monomers, 1-3 parts of surfactants, 0.1-1 part of initiators and 1-3 parts of pH (potential of hydrogen) regulators. The invention further provides a method for preparing the acrylate emulsion. The acrylate emulsion and the method have the advantage that the acrylate emulsion prepared bythe aid of the method is excellent in adhesion, solvent resistance, chemical resistance, water resistance, gloss fullness and paint preparation tolerance.

Description

technical field [0001] The invention relates to an acrylate emulsion, in particular to an acrylate emulsion used for plastic substrates with excellent performance and a preparation method thereof. Background technique [0002] With the continuous improvement of people's living standards, the types of coatings used for industrial plastics are also increasing. Coating on plastics can protect and decorate plastic products, improve product performance, and prolong their service life. At present, the plastic coatings widely used in the market are solvent-based. In solvent-based coatings, solvent-based resins play a key and decisive role. In these solvent-based resin systems, the oily system has serious environmental pollution and irritation during the film-forming process. Strong smell, high VOC content, etc., but the two-component system is not conducive to storage stability, and needs to be prepared and used immediately, and has a strong pungent smell, high VOC content. [000...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F220/18C08F212/08C08F230/08C08F220/06C08F222/02C08F220/40C08F2/26C08F2/30C09D133/12
CPCC08F2/26C08F2/30C08F220/14C09D143/04C08F220/1804C08F212/08C08F230/08C08F220/06C08F222/02C08F220/40
Inventor 严东源黄天愿杨小书富岛和宪
Owner 佛山市顺德区巴德富实业有限公司
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