Phase-change material liquid and solid-phase propping agent formed by phase-change material liquid

A technology of phase change materials and solvents, which is applied in the direction of drilling composition, mining fluid, earthwork drilling, etc., can solve the problem of solid phase proppant (insufficient toughness of solid phase particles, affecting the conductivity of propped fractures, solid phase support Solve problems such as slow reaction speed of the agent, achieve the effect of shortening the reaction molding time, reducing construction risks and potential safety hazards, and good toughness

Active Publication Date: 2018-09-28
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In 2010, Schlumberger proposed that the fracture conductivity of HIWAY high-speed channel flow is not affected by the permeability of proppant. Compared with conventional fracturing technology, this technology also needs to inject solid phase proppant into the formation, and the process implementation is complicated
Although this process solves some major problems in the injection of solid phase proppant in conventional hydraulic fracturing, it also has some defects: on the one hand, the toughness of the solid phase proppant (solid phase particles) obtained by phase transformation is insufficient, and it is easy to occur Broken, blocking the gaps between solid phase particles, affecting the conductivity of propped fractures
On the other hand, the reaction speed of phase change material liquid forming into solid phase proppant is slow, which requires a long construction operation time, and during this period, once the phase change material has not phase change before the fracture is closed, it has a certain pressure. capacity of the proppant, the phase change fracturing process will fail

Method used

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  • Phase-change material liquid and solid-phase propping agent formed by phase-change material liquid
  • Phase-change material liquid and solid-phase propping agent formed by phase-change material liquid
  • Phase-change material liquid and solid-phase propping agent formed by phase-change material liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] This embodiment provides a type of phase change material liquid and solid phase proppants that use melamine substances as supramolecular building units.

[0038] Two phase change material liquid HPP 1 And HPP 2 The preparation process is as follows:

[0039] HPP 1 :First take 50g of xylene, then add 40g of melamine, 30g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium lauryl sulfate, 0.5g of phosphoric acid, 0.5g of calcium chloride, and two peroxides Benzoyl 1g. Put all in the flask and stir evenly at room temperature to complete the phase change material liquid HPP 1 Preparation.

[0040] HPP 2 :First take 50g of xylene, then add 40g of 2,4-diamino-6-diallylamino-1,3,5-triazine, 30g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, ten Sodium dialkyl sulfate 0.5g, phosphoric acid 0.5g, calcium chloride 0.5g, dibenzoyl peroxide 1g. Put all in the flask and stir evenly at room temperature to complete the phase change materia...

Embodiment 2

[0048] This embodiment provides a type of phase change material liquid and solid phase proppant containing a pore former.

[0049] Three phase change material liquid HPP 3 , HPP 4 , HPP 5 The preparation process is as follows:

[0050] HPP 3 : First take 50g of xylene, then add 40g of propenyl-substituted triazine, 30g of dicyclopentadiene resin, 0.7g of polyvinyl alcohol, 0.3g of sodium lauryl sulfonate, 0.5g of phosphoric acid, 0.5g of calcium chloride, Dibenzoyl oxide 1g, ammonium bicarbonate 5g. Put all in the flask, stir evenly at room temperature to complete the underground phase change material liquid HPP 3 Preparation.

[0051] HPP 4 :First take 50g of xylene, then add 40g of acrylic substituted melamine, 30g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium dodecyl sulfonate, 1g of sodium bicarbonate, and two peroxides. 1g tert-butyl, 5g solid paraffin. Put all in the flask, stir evenly at room temperature to complete the underground phase ...

Embodiment 3

[0066] This embodiment provides a type of phase change material liquid and solid phase proppants that use melamine substances as supramolecular building units.

[0067] Two phase change material liquid HPP 1 And HPP 2 The preparation process is as follows:

[0068] HPP 6 :First take 45g of xylene, then add 12g of melamine, 60g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium lauryl sulfate, 0.5g of phosphoric acid, 0.5g of calcium chloride, and two peroxides Benzoyl 1g. Put all in the flask and stir evenly at room temperature to complete the phase change material liquid HPP 6 Preparation.

[0069] HPP 7 :First take 20g of xylene, then add 60g of melamine, 20g of dicyclopentadiene resin, 0.5g of hydroxypropyl methylcellulose, 0.5g of sodium lauryl sulfate, 0.5g of phosphoric acid, 0.5g of calcium chloride, and two peroxides Benzoyl 1g. Put all in the flask and stir evenly at room temperature to complete the phase change material liquid HPP 7 Prepara...

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PUM

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Abstract

The invention provides a phase-change material liquid and a solid-phase propping agent formed by the phase-change material liquid. The phase change material liquid is prepared from the following components in percentage by mass: 10-60 wt% of a super-molecule construction unit, 20-50 wt% of a super-molecule functional unit, 0.1-2 wt% of a dispersing agent, 0.1-1 wt% of an inorganic construction promoting agent, 0.1-1 wt% of an initiator and the balance of a solvent; the super-molecule construction unit comprises a melamine substance and / or a triazine substance; the super-molecule functional unit comprises dicyclopentadiene resin; and the dispersing agent comprises a hydroxyl-containing polysaccharide substance and a surfactant. After entering a reservoir, the phase-change material liquid can form a solid-phase substance to prop cracks under super-molecule chemical and physical action. Due to the injection of the non-solid phase, the string friction can be effectively reduced, and the requirements on construction equipment, ground surface pipelines, wellheads and operating tool strings are reduced. Therefore, the construction cost is effectively reduced, and the construction risk andthe potential safety hazard are reduced.

Description

Technical field [0001] The invention belongs to the technical field of oil reservoir development, and specifically relates to a phase change material liquid and a solid phase proppant formed therefrom. Background technique [0002] Hydraulic fracturing technology has been widely used in the development of oil and gas fields as the main measure to increase oil and gas well production and water well injection, and has made important contributions to the stable production and injection of oil and gas fields. Hydraulic fracturing is to pump high-viscosity prefluid into the target reservoir to form fractures and extend them under high pressure, and then pump the sand-carrying liquid mixed with proppant. The sand-carrying liquid can continue to extend the fractures and carry the proppant deeply. For fractures, it’s best to break the fracturing fluid and degrade it into low-viscosity fluids flowing back to the bottom of the well, leaving a flow channel with high conductivity formed by t...

Claims

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Application Information

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IPC IPC(8): C08L45/00C08L29/04C08L1/28C08K13/02C08K5/3492C08K5/41C08K3/32C08K3/16C08J9/08C08J9/10C08J9/14C08J3/24C09K8/68C09K8/80
CPCC08J3/246C08J9/0028C08J9/0033C08J9/0061C08J9/0066C08J9/08C08J9/102C08J9/141C08J9/142C08J2201/042C08J2201/0502C08J2203/02C08J2203/04C08J2203/12C08J2203/14C08J2345/00C08J2401/28C08J2429/04C08K5/34922C08K5/41C08K13/02C08K2003/162C08K2003/329C09K8/68C09K8/80C09K8/882C08L45/00C08L29/04C09K8/604C09K8/64
Inventor 胡书宝杨勇赵立强刘国华宁萌萌徐昆杜娟李凝张丽娜贾元钊
Owner PETROCHINA CO LTD
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