Composition for hard mask
A technology of composition and hard mask, which is applied in the direction of photosensitive materials used in optomechanical devices, can solve the problem of photoresist layer or photoresist pattern consumption or increased etching amount, and the inability to ensure photosensitive Etching resistance of resist layer or photoresist pattern, etc., to achieve the effect of improving flatness, excellent flatness, improving heat resistance and etch resistance
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[0181] Through the evaluation methods described later, the corrosion resistance, solubility and flatness of the hard mask formed of the compositions of Table 1 were evaluated. The evaluation results are shown in Table 2 below.
[0182] (1) Evaluation of corrosion resistance
[0183] The compositions of the examples and the comparative examples were applied to the silicon wafer by a spin coating method, and 60 seconds were baked at 200 ° C to form a thickness. Membrane. ARF was applied on the respective films formed, and the exposure apparatus of the company was exposed using ASML (XT: 1450G, Na 0.93), and then TMAH (2.38 wt) was exposed using ASML (XT: 1450G, Na 0.93). % Aqueous solutions were developed, respectively, and achieved 60 nm of lines and gaps (LINE and SPACE) patterns.
[0184] The resulting patterning test piece is further solidified for 60 seconds at 110 ° C, using CHF 3 / Cf 4 The mixed gas was carried out for 20 second dry etching of the test piece, and the cross ...
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