In-situ soil remedying composite material capable of efficiently removing heavy metals

A composite material, in-situ remediation technology, applied in the field of soil remediation, can solve problems such as long cycle and slow remediation time, and achieve the effect of reducing content, slowing nitrogen release, and avoiding ecological risks

Active Publication Date: 2018-11-06
CHONGQING VOCATIONAL INST OF ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the restoration plants described in this method are annual crops, the cycle is long, and the restoration time is relatively slow.

Method used

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  • In-situ soil remedying composite material capable of efficiently removing heavy metals
  • In-situ soil remedying composite material capable of efficiently removing heavy metals

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] In the soil in-situ remediation composite material for efficiently removing heavy metals of this embodiment, the composite material raw materials include the following components in parts by weight:

[0019] 10 parts of sodium persulfate, 5 parts of sodium polyepoxysuccinate, 1 part of polyvinylpyrrolidone, 1 part of nano carbon, 1 part of serpentine, 5 parts of lignite humic acid, 1 part of surfactant, 4 parts of calcium dioxide , 4 parts of traditional Chinese medicine residue, 1 part of potassium permanganate, 1 part of red mud particles, 1 part of dithiocarbamate chitosan, 1 part of methacryloxyethyl trimethylammonium chloride, the traditional Chinese medicine residue Prepared by:

[0020] a. Wash the medicine residues of Ophiopogon japonicus, licorice, and Radix isatidis to a particle size of 80 mesh, then add a zinc chloride solution with a concentration of 3mol / L, and stir and mix thoroughly at a solid-liquid ratio of 1:2. Evenly, let stand at room temperature for 24...

Embodiment 2

[0026] In the soil in-situ remediation composite material for efficiently removing heavy metals of this embodiment, the composite material raw materials include the following components in parts by weight:

[0027] 20 parts of sodium persulfate, 10 parts of sodium polyepoxysuccinate, 5 parts of polyvinylpyrrolidone, 3 parts of nano carbon, 5 parts of serpentine, 10 parts of lignite humic acid, 3 parts of surfactants, 8 parts of calcium dioxide , 8 parts of traditional Chinese medicine residue, 3 parts of potassium permanganate, 5 parts of red mud particles, 5 parts of dithiocarbamate chitosan, 3 parts of methacryloxyethyl trimethylammonium chloride, the traditional Chinese medicine residue Prepared by:

[0028] a. Wash the medicine residues of Ophiopogon japonicus, licorice and Radix isatidis, dry and pulverize to a particle size of 100 mesh, then add a zinc chloride solution with a concentration of 3mol / L, and mix thoroughly at a solid-liquid ratio of 1:2. Evenly, let stand at ro...

Embodiment 3

[0034] In the soil in-situ remediation composite material for efficiently removing heavy metals of this embodiment, the composite material raw materials include the following components in parts by weight:

[0035] 10 parts of sodium persulfate, 10 parts of sodium polyepoxysuccinate, 1 part of polyvinylpyrrolidone, 3 parts of nano carbon, 1 part of serpentine, 10 parts of lignite humic acid, 1 part of surfactant, 8 parts of calcium dioxide , 4 parts of traditional Chinese medicine residue, 3 parts of potassium permanganate, 1 part of red mud particles, 5 parts of dithiocarbamate chitosan, 1 part of methacryloxyethyl trimethylammonium chloride, the traditional Chinese medicine residue Prepared by:

[0036] a. Wash the medicine residues of Ophiopogon japonicus, licorice, and Radix isatidis to a particle size of 80 mesh, then add a zinc chloride solution with a concentration of 3mol / L, and stir and mix thoroughly at a solid-liquid ratio of 1:2. Evenly, let stand at room temperature f...

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Abstract

The invention discloses an in-situ soil remedying composite material capable of efficiently removing heavy metals. The in-situ soil remedying composite material comprises the following components: 10-20 parts of sodium persulfate, 5-10 parts of sodium polyepoxysuccinate, 1-5 parts of polyvinylpyrrolidone, 1-3 parts of nanocarbon, 1-5 parts of serpentine, 5-10 parts of lignite humate, 1-3 parts ofa surfactant, 4-8 parts of calcium dioxide, 4-8 parts of Chinese herbal residue, 1-3 parts of potassium permanganate, 1-5 parts of red mud particles, 1-5 parts of chitosan dithiocarbamate and 1-3 parts of methacryloyloxyethyl trimethylammonium chloride. The in-situ soil remedying composite material can remedy soil contaminated by various heavy metals (such as Pb, Cd, Cu, Zn, Cr and As) and toxic organic substances (such as chlorinated organic compounds, brominated organic compounds and antibiotics), reduces conditions of strong heavy metal activity and strong bioavailability in the soil, prevents transfer of the heavy metals from the soil to plants, prevents bioenrichment and amplification of the heavy metals, can efficiently remove the heavy metals such as chromium and mercury from the soil, and restores original functions of the soil, so that needs of agricultural development are met, and the ecological safety of crops and other plants is guaranteed, and the ecological risks of the bioamplification and the enrichment of the heavy metals to people are avoided.

Description

Technical field [0001] The invention relates to soil restoration, in particular to a soil in-situ restoration composite material for efficiently removing heavy metals. Background technique [0002] Soil is the most active layer of the earth's surface system, the cornerstone of human survival and development, and an important material basis for ensuring the safety of human food and ecological environment. With the development of industry and the modernization of agricultural production, heavy metal pollution in soil has become one of the main problems that endanger the quality of the global environment. Heavy metal elements are a kind of potential pollutants, which are difficult to be degraded by soil microorganisms. Once they enter the soil, it is very difficult to control. Soil heavy metal pollution mainly comes from industrial production, agricultural production and transportation. They not only lead to the decline of soil vitality and reduce food production, but also accumul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40
CPCC09K17/40
Inventor 王金霞黄阳全桑鹏程周皓
Owner CHONGQING VOCATIONAL INST OF ENG
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