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Environment-friendly polishing electrolyte of titanium alloy and polishing method

A technology of titanium alloy and electrolyte, applied in the field of environmentally friendly polishing electrolyte and polishing of titanium alloy, can solve the problems of polishing conditions to be optimized, human body burns, toxicity, etc., to speed up the mass transfer of reactants and products, reduce health hazards, The effect of cheap and easy-to-obtain raw materials

Inactive Publication Date: 2018-11-06
HUNAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the prior art, the electrochemical polishing of titanium alloys has the following problems: (1) The polishing electrolyte is generally a strong acid (perchloric acid, phosphoric acid, sulfuric acid, hydrofluoric acid, etc.) etc.), toxic and volatile, and easily cause serious environmental pollution; (2) Electrochemical polishing is often accompanied by pitting, bubbles, blackening, etc., and the polishing conditions need to be optimized
However, the perchloric acid used in this application is highly corrosive and irritating, and can cause burns to the human body

Method used

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  • Environment-friendly polishing electrolyte of titanium alloy and polishing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] One of the embodiments of the environment-friendly polishing electrolyte and polishing method of a titanium alloy of the present invention comprises the following steps:

[0047] (1) Pretreatment: After polishing the TC4 titanium alloy with a size of 20 mm × 10 mm × 2 mm through 320-mesh and 1000-mesh metallographic sandpaper in sequence, rinse it with deionized water and absolute ethanol in sequence, and then wash it in absolute ethanol. Ultrasonic cleaning in medium for 5 minutes, dried for later use. The treated titanium alloy surface such as figure 1 shown.

[0048] (2) Configure the electrolyte. The composition of the electrolyte is as follows:

[0049] Ethanol 16 mL

[0050] Ethylene glycol 64 mL

[0051] Sodium chloride 0.46 g

[0052] Ammonium fluoride 0.5 g

[0053] Triethanolamine 1 mL

[0054] (3) Assemble the electrolytic cell: Pour the electrolyte into the reservoir, and use an ice-water bath to control the temperature of the electrolyte in the rese...

Embodiment 2

[0058] One of the embodiment of the environment-friendly polishing electrolyte of a kind of titanium alloy of the present invention and polishing method, as figure 1 , figure 2 As shown, the main technical solution of this embodiment 2 is basically the same as that of embodiment 1, and the features not explained in this embodiment 2 are explained in embodiment 1, and will not be repeated here. The difference between this embodiment and embodiment 1 is:

[0059] (1) Pretreatment: After polishing the TC4 titanium alloy with a size of 20 mm × 10 mm × 2 mm through 20-mesh and 1000-mesh metallographic sandpaper in sequence, rinse it with deionized water and absolute ethanol in sequence, and then wash it in absolute ethanol. Ultrasonic cleaning in medium for 5 minutes, dried for later use. The treated titanium alloy surface such as figure 1 shown.

[0060] (2) Configure the electrolyte: the composition of the electrolyte is as follows:

[0061] Ethanol 16 mL

[0062] Ethylene...

Embodiment 3

[0071] One of the embodiment of the environment-friendly polishing electrolyte of a kind of titanium alloy of the present invention and polishing method, as figure 1 , image 3 As shown, the main technical solution of this embodiment 3 is basically the same as that of embodiment 2, and the features not explained in this embodiment 3 are explained in embodiment 2, and will not be repeated here. The difference between this embodiment and embodiment 2 is:

[0072] (1) Pretreatment: After polishing the TC4 titanium alloy with a size of 20 mm × 10 mm × 2 mm through 20-mesh and 1000-mesh metallographic sandpaper in sequence, rinse it with deionized water and absolute ethanol in sequence, and then wash it in absolute ethanol. Ultrasonic cleaning in medium for 5 minutes, dried for later use. The treated titanium alloy surface such as figure 1 shown.

[0073] (2) Configure the electrolyte: the composition of the electrolyte is as follows:

[0074] Ethanol 16 mL

[0075] Ethylene ...

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Abstract

The invention discloses an environment-friendly polishing electrolyte of a titanium alloy and a polishing method, The electrolyte is composed of ethyl alcohol, ethylene glycol, sodium chloride, ammonium fluoride and triethanolamine, the electrolyte comprises the following comments of, 1 to 1-20 of the ethyl alcohol and the ethylene glycol in a volume ratio, 0.01-0.1 mol / L of the sodium chloride inconcentration, 0.01-0.1 mol / L of the ammonium fluoride in concentration, and 0.01-0.05 mol / L of the triethanolamine in concentration. The environment-friendly polishing electrolyte of the titanium alloy and the polishing method provided by the invention have the following characteristics that perchloric acid, phosphoric acid, the sulfuric acid, hydrofluoric acid and other strong acids and the perchloric acid, chromic anhydride, hydrogen peroxide and other strong oxidants which are commonly used in a traditional polishing electrolyte of the titanium alloy are not contained, so that the environmental pollution and the health hazards to operators are effectively reduced; and raw materials are cheap and easy to obtain, the operation cost is low, the phenomena of pitting, bubbles, black and the like are effectively avoided.

Description

technical field [0001] The invention relates to the technical field of metal processing, in particular to an environment-friendly polishing electrolyte for titanium alloys and a polishing method. Background technique [0002] Titanium alloy has the advantages of high toughness, high strength and corrosion resistance, and is widely used in aerospace, shipbuilding, chemical industry, energy and other fields. However, the poor thermal conductivity, high hardness and low elastic modulus of titanium alloy make it difficult to be processed and surface treated. [0003] At present, the polishing methods for titanium alloys can be divided into mechanical polishing, chemical polishing and electrochemical polishing. [0004] Among them, electrochemical polishing is also called electrolytic polishing. Electrochemical polishing is to use the workpiece as an anode, and achieve the effect of surface smoothing and polishing through the selective passivation and dissolution process on the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25F3/26
CPCC25F3/26
Inventor 张杰郭佳瑶陈煅肖玉黎宇嫣袁世燚
Owner HUNAN UNIV OF SCI & TECH
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