Organosilicone pressure sensitive adhesive and preparation method thereof, composite film structure, vibrating diaphragm and sound generating device
A silicone-based, silicone-rubber technology, applied in the direction of films/sheets without carriers, adhesives, film/sheet-like adhesives, etc. Problems such as poor sound quality and listening stability of the device
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[0085] The present invention also provides a preparation method of silicone pressure-sensitive adhesive, comprising the following steps:
[0086] Mixing 20-80 parts of silicone resin, 5-55 parts of silicone rubber, and 30-90 parts of organic solvent in parts by weight to obtain a mixture;
[0087] providing 0.1 to 5 parts of the catalyst, adding the catalyst to the mixture, and heat-treating the mixture added with the catalyst to obtain a colloid; and
[0088] Dry the colloid to obtain a silicone pressure-sensitive adhesive.
[0089] In an embodiment of the present invention, the silicone rubber is methylhydroxy silicone rubber, vinyl silicone rubber, or phenyl silicone rubber.
[0090] The organic solvent is at least one of benzene, toluene, ethyl acetate, xylene, N-methylpyrrolidone and butanone. Silicone resin and silicone rubber can be dissolved in this organic solvent for uniform mixing.
[0091] The catalyst is an organic complex of platinum or an organic tin compound...
Embodiment 1
[0150] In parts by weight, 5 parts of methylhydroxy silicone rubber, 20 parts of silicone resin, and 30 parts of benzene are provided, and the methylhydroxy silicone rubber and the silicone resin are dissolved in benzene to obtain a mixture. Among them, the mass ratio of methyl hydroxy silicone rubber to silicone resin is 1:4, the quantity ratio of M chain link and Q chain link in silicone resin is 1:0.7, R 1 is a methyl group, and the range of m is 15.
[0151] Provide 0.1 part of isopropanol complex of chloroplatinic acid, add the isopropanol complex of chloroplatinic acid into the mixture, and heat-treat the mixture added with the isopropanol complex of chloroplatinic acid to obtain a colloid. The temperature of the heat treatment is 80° C., and the time is 70 minutes. The isopropanol complex of chloroplatinic acid is used as a catalyst to promote the condensation reaction between the methylhydroxy silicone rubber and the silicone resin.
[0152] After the colloid is coole...
Embodiment 2
[0156] In parts by weight, 15 parts of methylhydroxy silicone rubber, 30 parts of silicone resin, and 54 parts of toluene were provided, and the methylhydroxy silicone rubber and the silicone resin were dissolved in toluene to obtain a mixture. Among them, the mass ratio of methyl hydroxy silicone rubber to silicone resin is 1:2, the quantity ratio of M chain link and Q chain link in silicone resin is 1:0.75, R 1 is a hydrogen group, and the range of m is 17.
[0157] Provide 0.5 parts of dibutyltin dilaurate, add dibutyltin dilaurate to the mixture, and heat-treat the mixture with dibutyltin dilaurate to obtain a colloid. Wherein, the temperature of the heat treatment is 90° C., and the time is 50 minutes. Dibutyltin dilaurate is used as a catalyst to promote the condensation reaction between the methylhydroxy silicone rubber and the silicone resin.
[0158] After the colloid is cooled, provide 0.5 parts of benzoyl peroxide, add benzoyl peroxide to the colloid, and stir even...
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