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Composite transparent conductive film and preparation method thereof

A transparent conductive film and thin film technology, applied in the direction of ion implantation plating, coating, metal material coating process, etc., can solve the problem of poor stability of antistatic fillers, easy failure of antistatic components, and few products of transparent antistatic coatings, etc. problem, to achieve the effect of high surface resistance accuracy, meeting the process window, and convenient process adjustment

Active Publication Date: 2018-12-14
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For transparent plastic surfaces, light transmittance is one of the most important properties of the product, and the addition of conductive fillers or conductive polymers in antistatic coatings greatly reduces the light transmittance of the product
Moreover, the stability of antistatic fillers is poor. In special environments, such as high humidity, high heat or salt spray, antistatic components are prone to failure.
[0003] At present, there are few transparent antistatic coating products on the market, and the performance of many products cannot meet the requirements for use

Method used

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  • Composite transparent conductive film and preparation method thereof
  • Composite transparent conductive film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Prepare a composite conductive film based on the surface of a plexiglass sample, the steps of the preparation method are as follows:

[0029] (1) Raw materials for preparing transition layer:

[0030] Adopt acrylic polyurethane transparent coating and adopt solution polymerization process, the names and mass percentages of each component are: methyl methacrylate: 20.0% by weight; styrene: 10% by weight; butyl acrylate: 5.0% by weight; trimethylolpropane Triacrylate: 2.0% by weight; initiator (dibenzoyl peroxide): 0.5% by weight and solvent (equal mass mixture of butyl acetate and PMP): 62.5% by weight. During synthesis, first put 15% by weight of monomer (a mixture of methyl methacrylate, styrene, butyl acrylate and trimethylolpropane triacrylate) and 20% by weight of solvent into the kettle, and reflux at 100 ° C Add the mixed solution of the remaining monomer, solvent and 25% by weight of the initiator dropwise at high temperature, drop it for 3 hours, then add the r...

Embodiment 2

[0038] A preparation method based on polycarbonate sample surface composite conductive film, the steps are as follows:

[0039] (1) Raw materials for preparing transition layer

[0040] Polysiloxane coating is used, and the name and mass percentage of each component are: ethyl orthosilicate: 4.7% by weight; methyltriethoxysilane: 50.0% by weight; KH550: 4.7% by weight; hydroxyl silicone oil: 0.2% by weight ; Tetrabutylammonium hydroxide: 0.2% by weight; Isopropanol: 40.2% by weight. When synthesizing, first put the mixture of ethyl orthosilicate and methyltriethoxysilane into the kettle, add a small amount of acetic acid until the pH is 3, raise the temperature to 80°C for reflux reaction for 2 hours, and reflux for cooling. Then add KH550 at 55°C, stir for 2h and cool to room temperature. Finally, isopropanol, hydroxy silicone oil and tetrabutylammonium hydroxide were added exceptionally to obtain polysiloxane clear coatings.

[0041] (2) Preparation of transition layer

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Abstract

The invention discloses a preparation method of a composite transparent conductive film and application thereof in antistatic electricity. The composite transparent conductive film comprises a transition layer, a conductive layer and a protective layer, wherein the transition layer is formed on a glass or plastic surface substrate and is a polyurethane acrylate or polysiloxane coating; the conductive layer is one of an ITO film, an AZO film, an IZO film, a TiO2 film, a GAO film and a ZAO film, and is deposited on the transition layer; the protective layer is deposited on the conductive layer,and is one of silicon oxide, titanium nitride and silicon nitride. According to the invention, a problem that electrostatic charges are accumulated on a surface of a transparent piece is solved whilesalt spray and moist heat resistances and other environmental properties of the conductive layer are improved by controlling the thickness and density of the protective layer.

Description

technical field [0001] The invention relates to a composite transparent conductive film and a preparation method thereof, belonging to the field of antistatic technology. Background technique [0002] Transparent plastic surfaces, such as the electronic industry and aircraft transparent parts, are prone to charge accumulation, resulting in product failure. The traditional method is to wet-coat antistatic paint on the surface of the product to avoid the accumulation of static electricity. Antistatic coating itself is a relatively mature product, and there are many related researches. These coatings often achieve antistatic effect by adding conductive fillers or conductive polymers. For transparent plastic surfaces, light transmittance is one of the most important properties of the product, and the addition of conductive fillers or conductive polymers in antistatic coatings greatly reduces the light transmittance of the product. Moreover, antistatic fillers are less stable, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/35C23C14/08C23C14/10C23C14/06B05D1/02B05D1/30
CPCB05D1/02B05D1/30C23C14/0641C23C14/0652C23C14/08C23C14/083C23C14/086C23C14/10C23C14/35
Inventor 张旋钟艳莉颜悦郝常山彭晶晶
Owner AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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