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Geo-polymer based marine concrete protective coating material and preparation method thereof

A protective coating and geopolymer technology, which is applied in the field of geopolymer-based marine concrete protective coating materials and its preparation, can solve the problems of residual stress cracking and long curing time of the coating, and achieve improved performance and constructability , short curing time and cost reduction effect

Active Publication Date: 2018-12-18
湖北恒畅路桥有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the coating also has problems such as residual stress cracking of the coating caused by large cement shrinkage, and long curing time.

Method used

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  • Geo-polymer based marine concrete protective coating material and preparation method thereof
  • Geo-polymer based marine concrete protective coating material and preparation method thereof

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preparation example Construction

[0028] Another aspect of the present invention provides a method for preparing the above-mentioned geopolymer-based marine concrete protective coating material, the preparation method comprising:

[0029] NaOH and Na with a solid content of 30-40% 2 SiO 3 Mix the aqueous solution evenly and control the Na 2 SiO 3 The modulus of the aqueous solution is 1.2-1.5M, and the A component is obtained;

[0030] Grinding and mixing calcined metakaolin, silica fume, ordinary Portland cement, nano-magnesia and rice husk ash to obtain a premix; mixing the premix, sisal fiber and modified waste natural rubber evenly, and then Mix well with silane coupling agent, silicone acrylic emulsion, water reducer and water to get component B.

[0031] As a preferred version, the grinding time is 10-20min; the time for mixing the premix, sisal fiber and modified waste natural rubber is 1-2min; The time is 1-2min.

[0032] As a preferred solution, during construction of the polymer-based marine co...

Embodiment 1

[0037] This embodiment provides a geopolymer-based marine concrete protective coating material, the specific preparation method is as follows:

[0038] NaOH and Na with a solid content of 35% 2 SiO 3 Mix the aqueous solution evenly and control the Na 2 SiO 3 The modulus of the aqueous solution is 1.2M to obtain a compound base activator; take 15 parts of the compound base activator as component A;

[0039] 45 parts of calcined metakaolin calcined at 650°C for 4 hours, 0.1 part of silica fume, 1 part of No. 32.5 ordinary Portland cement, 0.1 part of nano-magnesium oxide and 1 part of rice husk ash were ground in a planetary ball mill for 15 minutes to obtain a premixed material, spare; add premix, 0.1 part of sisal fiber and 0.3 part of modified waste natural rubber into the concrete mixer and stir for 60 seconds, then add 0.5 part of silane coupling agent KH550, 5 parts of silicone acrylic emulsion, 0.1 part of Aqua and 2 parts of water, continue to stir for 120s to obtain...

Embodiment 2

[0042] This embodiment provides a geopolymer-based marine concrete protective coating material, the specific preparation method is as follows:

[0043] NaOH and Na with a solid content of 35% 2 SiO 3 Mix the aqueous solution evenly and control the Na 2 SiO 3 The modulus of the aqueous solution is 1.5M to obtain a compound base activator; take 20 parts of the compound base activator as component A;

[0044] 45 parts of calcined metakaolin calcined at 650°C for 4 hours, 0.1 part of silica fume, 1 part of No. 32.5 ordinary Portland cement, 0.3 part of nano-magnesium oxide and 1 part of rice husk ash were ground in a planetary ball mill for 15 minutes to obtain a premixed material, spare; add premix, 0.1 part of sisal fiber and 0.3 part of modified waste natural rubber into the concrete mixer and stir for 60 seconds, then add 0.5 part of silane coupling agent KH550, 8 parts of silicone acrylic emulsion, 0.1 part of Aqua and 2 parts of water, continue to stir for 120s to obtain...

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Abstract

The invention discloses a geo-polymer based marine concrete protective coating material and a preparation method thereof. The protective coating material includes a component A and a component B, wherein the component A includes, by mass, 10-25 parts of a compound alkaline activator; and the component B includes: 45-65 parts of calcined metakaolin, 1-5 parts of ordinary Portland cement, 0.1-0.5 parts of silica fume, 2-5 parts of water, 0.1-0.5 parts of a water reducing agent, 0.1-0.5 parts of nano MgO, 5-10 parts of a silicone acrylic emulsion, 1-2 parts of rice husk ash, 0.1-0.5 parts of modified waste natural rubber, 0.1-0.5 parts of sisal fibers, and 0.5-1 part of a silane coupling agent. The unit mass parts of the component A and the component B are same. The protective coating material has high strength, short curing time, good durability, strong interfacial effect between new / old concrete, and is low in cost.

Description

technical field [0001] The invention belongs to the technical field of marine concrete protective materials, and more specifically relates to a geopolymer-based marine concrete protective coating material and a preparation method thereof. Background technique [0002] The harsh marine environment will cause the internal reinforcement of reinforced concrete to rust, resulting in cracking and damage to the reinforced concrete structure, which greatly reduces the service life and quality of the concrete structure. In order to improve the corrosion resistance of marine concrete, many studies have been carried out at home and abroad. Brushing organic anti-corrosion coatings on the concrete surface to prevent the infiltration of various corrosive media is one of the most widely used methods. However, due to the impact of harsh marine environments such as light, heat, oxygen, chemical erosion, and freeze-thaw damage, organic protective coatings are prone to aging and degradation du...

Claims

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Application Information

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IPC IPC(8): C04B28/04C04B111/24
CPCC04B28/04C04B2111/00508C04B2111/24C04B14/106C04B18/146C04B24/42C04B22/066C04B18/101C04B18/22C04B18/248C04B12/04C04B22/062C04B2103/302
Inventor 刘杰胜张同同谭晓明张荣堂董莪何翔伦云霞魏娜涂妮张浩
Owner 湖北恒畅路桥有限公司