Degradable compressive discoloring plastic color masterbatch and preparation method thereof

A pressure discoloration and color masterbatch technology, applied in the field of plastic coloring, can solve the problems of non-replanting, land pollution, increased damage rate of plastic products and use costs, etc., to protect health and environment, protect cleanliness, and maintain chemical stability sexual effect

Inactive Publication Date: 2018-12-18
DONGGUAN JINFULIANG PLASTIC & RUBBER TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention does not contain small molecular substances, increases the oil resistance and flux resistance of the color masterbatch, improves the migration resistance of the color masterbatch, and cannot cause precipitation in plastic products, but the carrier used in the preparation method is polyethylene, which is non-degradable Materials, and the pigments and additives used, there are heavy metals exceeding the standard, resulting in serious pollution of the land and cannot be planted again
[0004] In addition, at present, after most of the masterbatches are made into heavy-duty plastic products, such as water pipes, gears, casings, etc., when the load reaches or exceeds the warning weight, there is no relevant intelligent monitoring system to monitor it in real time to display its load. The degree of damage under pressure will virtually increase the damage rate and use cost of plastic products

Method used

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  • Degradable compressive discoloring plastic color masterbatch and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0027] A degradable pressure-changing plastic color masterbatch, which is composed of the following substances in mass fractions: 10% titanium dioxide, 10% starch, 0.5% titanate coupling agent, 0.5% stearic acid, 75% polylactic acid, di Vinyl anthracene PAIE compound 4%.

[0028] A method for degradable pressure-changing plastic color masterbatch, comprising the following steps:

[0029] Step A: put titanium dioxide, stearic acid and starch into a high-speed mixer, and stir at a high speed for 5 minutes at 95°C;

[0030] Step B: Add titanate coupling agent and divinyl anthracene PAIE compound into the high-speed mixer, and stir at high speed for 5 minutes;

[0031] Step C: Finally, add polylactic acid into the high-speed mixer, stir at high speed for 3 minutes, and obtain the mixture after discharging;

[0032] Step D: Melt and blend the mixture obtained in Step C through a twin-screw extruder, extrude and granulate, cool, dry, and pack in an aluminum foil bag to obtain a de...

Embodiment 2

[0034] A degradable pressure-changing plastic color masterbatch, which is composed of the following substances in mass fractions: 15% of permanent red, 20% of silica modified calcium carbonate, 0.1% of silane coupling agent, and 0.9% of ethylene bisstearamide %, butylene terephthalate 59%, tetraphenylethylene PAIE compounds 5%.

[0035] A method for preparing degradable pressure-changing plastic color masterbatch, comprising the following steps:

[0036] Step A: Put permanent red, ethylene bisstearamide and silica-modified calcium carbonate into a high-speed mixer, and stir at a high speed for 7 minutes at 100°C;

[0037] Step B: Add silane coupling agent and tetraphenylethylene PAIE compound into the high-speed mixer, and stir at high speed for 7 minutes;

[0038] Step C: Finally, add butylene terephthalate into the high-speed mixer, stir at high speed for 4 minutes, and obtain a mixture after discharging;

[0039] Step D: Melt and blend the mixture obtained in Step C throu...

Embodiment 3

[0041] A degradable pressure-changing plastic color masterbatch, which is composed of the following mass fractions: carbon black 30%, clay 14%, borate coupling agent 1%, fatty acid amide 5%, polylactic acid 40%, silole 10% of PAIE-like compounds, wherein the carrier is polylactic acid or butylene terephthalate.

[0042] A method for preparing degradable pressure-changing plastic color masterbatch, comprising the following steps:

[0043] Step A: Put carbon black, fatty acid amide and clay into a high-speed mixer, and stir at a high speed for 10 minutes at 105°C;

[0044] Step B: Add borate coupling agent and silole PAIE compound into the high-speed mixer, and stir at high speed for 10 minutes;

[0045] Step C: Finally, add polylactic acid into the high-speed mixer, stir at high speed for 5 minutes, and obtain the mixture after discharging;

[0046] Step D: Melt and blend the mixture obtained in step C through a twin-screw extruder, extrude and granulate, cool, dry, and pack ...

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Abstract

A degradable compressive discoloring plastic color masterbatch consists of the following substances by the mass fraction: 10-30% of a pigment, 10-40% of a filler, 0.1-1% of a coupling agent, 0.5-5% ofa lubricant, 40-80% of a carrier and 4-10% of a pressure sensitive discoloring material. With polylactic acid or butylene terephthalate as a carrier, the proportion of the pigment and the additive isoptimized, the degradable compressive discoloring color masterbatch is obtained, has the advantages of uniform coloring, low cost, easy control of processing technology, excellent dispersibility andthe like, and has broad industrial application prospects.

Description

technical field [0001] The invention belongs to the field of plastic coloring, and in particular relates to a degradable pressure-changing plastic color masterbatch and a preparation method thereof. Background technique [0002] Color masterbatch is a plastic coloring product developed in the 1960s. It is a polymer compound prepared by uniformly loading pigments in resin. It has the advantages of convenient use and stable color; color masterbatch Granules have entered China for more than 40 years. The variety has grown from scratch, and the output and quality have been greatly improved compared with the beginning of development. It is also widely used in the fields of plastic products such as films, plastic products, chemical fibers, cables, and building materials. Colored with masterbatch. [0003] Patent 107973957A discloses a precipitation-preventing masterbatch, which consists of the following components in parts by weight: 15-50 parts of polyethylene, 5-50 parts of pig...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L67/02C08J3/22
CPCC08J3/226C08J2367/02C08J2367/04
Inventor 黄成明陈伟聪
Owner DONGGUAN JINFULIANG PLASTIC & RUBBER TECH CO LTD
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