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Polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors and preparation method thereof

A technology of polybutyl methacrylate and polybutyl acrylate, which is applied in the measurement of the property and force of piezoelectric devices, electromagnetic measurement devices, and electric/magnetic solid deformation measurement, etc., which can solve the problem of lack of transparency and limited applications , lack of flexibility and other issues, to achieve the effect of good flexibility and transparency, high power, and strong ability to lose electrons

Active Publication Date: 2018-12-28
HUNAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the materials used for triboelectric nanogenerators are mostly metals or crystalline polymer materials, so they are not transparent and lack flexibility, which limits their application in some special cases.

Method used

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  • Polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors and preparation method thereof
  • Polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors and preparation method thereof
  • Polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] This embodiment provides a preparation method of polybutyl acrylate-polybutyl methacrylate copolymer for flexible nanogenerators and self-driving sensors. The specific steps are:

[0035] S1. Add 30mmol butyl acrylate, 90mmol butyl methacrylate, 0.4mmol 4-methylbenzophenone, 0.4mmol cuprous bromide and 0.4mmol pentamethyldivinyltriamine to the two-necked flask successively, The reactants in the reaction were refrigerated and vacuum deaerated and then sealed in a vacuum environment. Then react 15h in oil bath at 90 DEG C, obtain polybutyl acrylate-polybutyl methacrylate copolymer;

[0036] S2. the obtained polybutyl acrylate-polybutyl methacrylate copolymer is dissolved in chloroform, and then extracted and purified in methanol / 5% hydrochloric acid solution to obtain polybutyl acrylate-polybutyl methacrylate copolymer. The purified product is dried;

[0037] S3. The polybutyl acrylate-polybutyl methacrylate copolymer dried in step S2 is hot-pressed at 100 ° C to form a...

Embodiment 2

[0039] This embodiment provides a preparation method of polybutyl acrylate-polybutyl methacrylate copolymer for flexible nanogenerators and self-driving sensors. The specific steps are:

[0040] S1. Add 30mmol butyl acrylate, 60mmol butyl methacrylate, 0.4mmol 4-methylbenzophenone, 0.4mmol cuprous bromide and 0.8mmol 4,4'-dinonyl-2,2'- Bipyridyl was added into a two-necked flask, and the reactants in the flask were refrigerated and vacuum-deaerated and then sealed in a vacuum environment. Then at 70 DEG C of oil bath 10h, obtain polybutyl acrylate-polybutyl methacrylate copolymer;

[0041] S2. the obtained polybutyl acrylate-polybutyl methacrylate copolymer is dissolved in chloroform, and then extracted and purified in methanol / 5% hydrochloric acid solution to obtain polybutyl acrylate-polybutyl methacrylate copolymer. The purified product is dried;

[0042] S3. The polybutyl acrylate-polybutyl methacrylate copolymer dried in step S2 is hot-pressed to form a film at 80° C. t...

Embodiment 3

[0044] This embodiment provides a preparation method of polybutyl acrylate-polybutyl methacrylate copolymer for flexible nanogenerators and self-driving sensors. The specific steps are:

[0045] S1. Add 30mmol butyl acrylate, 120mmol butyl methacrylate, 0.4mmol 4-methylbenzophenone, 0.4mmol cuprous bromide and 0.8mmol 4,4'-dinonyl-2,2'- Bipyridyl was added into a two-necked flask, and the reactants in the flask were refrigerated and vacuum-deaerated and then sealed in a vacuum environment. Then at 90 DEG C of oil bath 20h, obtain polybutyl acrylate-polybutyl methacrylate copolymer;

[0046] S2. the obtained polybutyl acrylate-polybutyl methacrylate copolymer is dissolved in chloroform, and then extracted and purified in methanol / 5% hydrochloric acid solution to obtain polybutyl acrylate-polybutyl methacrylate copolymer. The purified product is dried;

[0047]S3. The polybutyl acrylate-polybutyl methacrylate copolymer dried in step S2 is hot-pressed to form a film at 120° C. ...

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Abstract

The invention relates to a preparation method of a polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors and application of the polybutyl acrylate-poly-n-butyl methacrylate copolymer to nano new energy. The preparation method of the electropositivity-including polybutyl acrylate-poly-n-butyl methacrylate copolymer for nano generators and self-driven sensors is simple; the prepared copolymer has excellent mechanical property, transparency and favorable betatopic capability. By using the polybutyl acrylate-poly-n-butyl methacrylate copolymer for flexible nano generators and self-driven sensors, prepared friction nano generators have excellent mechanical property and transparency, prepared friction nano generators are high in power and stable in output performance, and prepared self-driven sensors are excellent in mechanical property and transparency, high in sensitivity and stable in signal output.

Description

technical field [0001] The invention relates to the field of new nano-energy, more specifically, to a polybutylacrylate-polybutylmethacrylate copolymer for flexible nanometer generators and self-driven sensors and a preparation method thereof. Background technique [0002] Nanogenerator is a new type of energy harvesting device proposed in recent years to solve the problems of energy shortage and environmental pollution. It can convert mechanical energy in nature and life into electrical energy through special materials and device design. Since nanogenerators can generate electrical signals based on external stress and deformation, they can also be used as microsensors to monitor the movement or deformation of human bodies or objects, and nanogenerators with high flexibility and transparency have a huge market demand. [0003] Compared with traditional piezoelectric nanogenerators, triboelectric nanogenerators have the advantages of high energy conversion rate, output power...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08L33/10C08J5/18G01B7/16G01L1/16
CPCC08F220/18C08F220/1804C08J5/18C08J2333/10G01B7/16G01L1/16
Inventor 米皓阳经鑫刘跃军
Owner HUNAN UNIV OF TECH
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