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Treatment method for aluminium-alloy synergistic fluoropolymer coating with high-temperature viscosity resistance

A fluoropolymer, coating treatment technology, applied in the direction of coating, surface reaction electrolytic coating, electrolytic coating, etc., can solve the problems of affecting the use of aluminum alloy, affecting the production efficiency of bag making, strong high temperature viscosity, etc., to improve production Efficiency, high hardness, good light resistance

Active Publication Date: 2019-01-18
NO 59 RES INST OF CHINA ORDNANCE IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The inventor found in the research that the aluminum alloy synergistic coating prepared by the process disclosed in CN1687488A has a certain degree of improvement in hardness, wear resistance, corrosion resistance and other properties compared with ordinary aluminum alloys, but when the aluminum alloy material is heated due to friction, After heating and other conditions cause the temperature of the aluminum alloy synergistic coating to rise, especially after the temperature rises above 160°C, the synergistic coating will show strong high-temperature viscosity (the high-temperature viscosity in the present invention refers to the coating on the metal surface. layer in a high-temperature environment), which seriously affects the use of aluminum alloys; for example, in the field of non-PVC bag-making, aluminum alloys prepared by CN1687488A process, aluminum alloy synergistic coatings and non-PVC bag-making products have adhesion phenomenon , which seriously affects the production efficiency of bag making

Method used

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  • Treatment method for aluminium-alloy synergistic fluoropolymer coating with high-temperature viscosity resistance
  • Treatment method for aluminium-alloy synergistic fluoropolymer coating with high-temperature viscosity resistance

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Take a 7075 aluminum alloy (Al-Zn-Mg-Cu super duralumin) mold sample for non-PVC bags, degrease it with an alkaline degreasing solution at 61°C for 8 minutes, wash it with water, and place it in 42g / l hydrogen peroxide Etch and wash at 62°C for 3 minutes in sodium solution to remove the oxide film on the surface of the aluminum alloy, and obtain the aluminum alloy mold sample after etching; put the above-mentioned etched aluminum alloy mold sample in 21% nitric acid solution for pickling Light treatment for 3 minutes, remove the hanging ash and residues produced by pickling, and obtain the aluminum alloy mold sample after pickling;

[0025]The aforementioned aluminum alloy mold sample after pickling was placed in a mixed acid solution for hard anodic oxidation treatment, and after washing with water, an aluminum alloy hard anodized film was obtained (the inventor observed that the aluminum alloy hard anodized film was very uniform); Among them, the content of sulfuric a...

Embodiment 2

[0030] Take 7A04T6 (Al-Zn-Mg-Cu super duralumin) aluminum alloy mold sample, degrease with alkaline degreasing solution at 74°C for 9 minutes, wash with water and place in 49g / l sodium hydroxide solution at 73°C Etching and washing for 5 minutes to remove the oxide film on the surface of the aluminum alloy to obtain an aluminum alloy mold sample after etching and washing; placing the aforementioned aluminum alloy mold sample after etching and washing in 29% nitric acid solution for pickling and light treatment for 9 minutes, Remove the hanging ash and residues produced by pickling, and obtain the aluminum alloy mold sample after pickling;

[0031] The aforementioned aluminum alloy mold sample after pickling was placed in a mixed acid solution for hard anodic oxidation treatment, and after washing with water, an aluminum alloy hard anodized film was obtained (the inventor observed that the aluminum alloy hard anodized film was very uniform); Among them, the content of sulfuric ...

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Abstract

The invention provides a treatment method for an aluminium-alloy synergistic fluoropolymer coating with high-temperature viscosity resistance. The method comprises the following steps: firstly, a mixed acid solution containing sulfonated anthracene is used for preparing an aluminium-alloy hard anodic oxide film by electrolysis; then chambering is performed on the aluminium-alloy hard anodic oxidefilm, and a fluoropolymer is introduced; the fluoropolymer and the aluminium-alloy hard anodic oxide film are fused into a whole by vacuum heat treatment, and the synergistic coating with the high-temperature viscosity resistance is prepared. The prepared aluminium-alloy synergistic fluoropolymer coating with high-temperature viscosity resistance is uniformly black, has quite good uniformity, still has high-temperature viscosity resistance in the range of 160-185 DEG C, and meets use requirements of aluminium alloy under high-temperature viscosity resistant condition; the problem of high-temperature viscosity in a non-PVC bag making process is solved effectively, and non-PVC bag making efficiency can be increased remarkably when the method is applied to a non-PVC bag making production line; besides, the method has quite important application value in solving the welding problems of three-layer films and five-layer films of the aluminium alloy and the problem of poor soldering of films.

Description

technical field [0001] The invention relates to the treatment of high-temperature anti-adhesion coating of aluminum alloy, in particular to a treatment method of high-temperature anti-adhesion fluoropolymer synergistic coating of aluminum alloy. Background technique [0002] Aluminum alloy is an important non-ferrous metal material, which is widely used in aviation, aerospace, automobile, machinery manufacturing, shipbuilding, chemical industry and other fields. In the process of manufacturing aluminum alloy parts, in order to improve the performance of aluminum alloy parts (such as electrical conductivity, thermal conductivity, wear resistance, corrosion resistance and optical properties, etc.), surface treatment is usually required. At present, the surface treatment methods of aluminum alloy materials mainly include painting treatment method, ordinary anodic oxidation dyeing and sealing treatment method, hard anodic oxidation dyeing and sealing treatment method; There are...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D11/06C25D11/18
CPCC25D11/06C25D11/18
Inventor 邹洪庆吕基成钱建才吴厚昌韩虞梅方敏
Owner NO 59 RES INST OF CHINA ORDNANCE IND
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