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Environment-friendly degradable textile size mixture and preparation method thereof

A kind of textile sizing, environmental protection technology, applied in the field of textile sizing, to achieve the effect of enhancing cohesion, not easy to crust, and strong cohesion

Active Publication Date: 2019-02-12
JIANGXI HONGDA CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to disclose an environmentally friendly and degradable textile size and its preparation method in view of the problems existing in the existing modified starch size, especially the sizing effect on synthetic fibers.

Method used

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  • Environment-friendly degradable textile size mixture and preparation method thereof
  • Environment-friendly degradable textile size mixture and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Slurry formula: 80% modified starch, 15% hydroxyethyl cellulose, 5% chitosan.

[0021] The preparation method of modified starch: first put 100 kg corn starch and 200 kg water into the reaction kettle, heat and stir to dissolve, when the temperature reaches the gelatinization temperature, then add 0.25 kg orthosilicic acid and 0.25 kg amber in three batches Anhydride, stir for 1 hour after adding orthosilicic acid and succinic anhydride each time, when the orthosilicic acid and succinic anhydride are added, add 0.1 kg of silica sol with a silica content of 31%, keep warm for a period of time, cool, and use a small amount of The sodium hydroxide solution was used to adjust the pH value to 7, and finally the modified starch was obtained by spray drying.

[0022] Textile size compounding: Fully mix in a vacuum kneader according to the weight ratio of 80% of modified starch, 15% of hydroxyethyl cellulose, and 5% of chitosan to obtain textile size, and package the finished p...

Embodiment 2

[0024] Modified starch 95%, sodium carboxymethyl cellulose 1%, gelatin 4%.

[0025] The preparation method of modified starch: first put 100 kg of wheat starch and 200 kg of water into the reaction kettle, heat and stir to dissolve, when the temperature reaches the gelatinization temperature, then add 1 kg of metasilicate and 4 kg of horse starch in four batches For maleic anhydride, stir for 1 hour after adding metasilicic acid and maleic anhydride each time. After adding metasilicic acid and maleic anhydride, add 0.5 kg of silica sol with a silica content of 15%, keep warm for a period of time, and then cool , adjust the pH value to 7 with a small amount of potassium hydroxide solution, and finally obtain the modified starch through spray drying.

[0026] Textile pulp compounding: Fully mix in a vacuum kneader according to the weight ratio of 95% modified starch, 1% sodium carboxymethyl cellulose, and 4% gelatin to obtain textile pulp, and package the finished product.

Embodiment 3

[0028] Modified starch 85%, hydroxyethyl cellulose 10%, gum arabic 5%.

[0029] The preparation method of modified starch: first put 100 kg tapioca starch and 200 kg water into the reaction kettle, heat and stir to dissolve, when the temperature reaches the gelatinization temperature, then add 1 kg disilicate and 2 kg grass anhydride, add disilicate and oxalic anhydride each time and stir for 1 hour, when disilicate and oxalic anhydride are added, then add 0.3 kg of silica sol with a silica content of 20%, keep warm for a period of time, cool, and use a small amount of The potassium hydroxide solution was used to adjust the pH to 7, and finally the modified starch was obtained by spray drying.

[0030] Textile size compounding: Fully mix in a vacuum kneader according to the weight ratio of 85% of modified starch, 10% of hydroxyethyl cellulose, and 5% of gum arabic, to obtain textile size, and package the finished product.

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Abstract

The invention relates to environment-friendly degradable textile size mixture and a preparation method thereof. According to the method, modified starch, cellulose and sizing additives are compounded;the textile size mixture is prepared from the following components (by weight percent): 80-95% of the modified starch, 1-15% of the cellulose and 1-5% of the additives. The textile size mixture product prepared by the method can be used for replacing polyvinyl alcohol (PVA), is applied to warp sizing of cotton, synthetic fibers and blended yarns, has excellent sizing performance, does not cause environmental pollution, and is environmental protection size mixture.

Description

technical field [0001] The invention relates to an environment-friendly and degradable textile slurry and a preparation method, belonging to the technical field of textile slurry. Background technique [0002] Sizing is an important component of sizing yarn, which directly affects the quality and efficiency of sizing. At present, PVA is one of the commonly used sizing materials for warp yarn sizing, and has always been the first choice for sizing polyester and polyester-cotton blended yarns. However, the degradability of PVA slurry wastewater in the sewage tank is very poor, and it is easy to cause environmental pollution. In order to improve the environmental pollution caused by refractory PVA, various types of modified starch and acrylic slurry have been developed in large quantities. However, the sizing effect of modified starch sizing is not as good as that of PVA, especially for synthetic fibers, and the price of grafted starch is expensive, which increases the cost of...

Claims

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Application Information

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IPC IPC(8): D06M15/11D06M15/09D06M15/03D06M11/79D06M101/06
CPCD06M11/79D06M15/03D06M15/09D06M15/11D06M2101/06D06M2200/40
Inventor 游胜勇乐晋峰熊国辉李玲董晓娜张月凤赵朝委张鹏邹吉勇
Owner JIANGXI HONGDA CHEM IND