Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

High-performance functionalized alloy modified polypropylene corrugated pipe special-use material and preparation method thereof

A technology of polypropylene and chemical alloys, which is applied in the field of high-performance functional alloy modified polypropylene corrugated pipe special materials and its preparation, can solve the problems of inability to achieve flame retardancy, poor low-temperature performance, and high processing costs, and achieve surface gloss Good, good anti-crack performance, small thermal shrinkage coefficient

Active Publication Date: 2019-03-01
FUJIAN NORMAL UNIV
View PDF5 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, corrugated pipes for electric power are generally HDPE pipes and MPP single-wall corrugated pipes, which are respectively made of HDPE (high-density polyethylene) and reinforced modified polypropylene materials. These two materials can only be used for round pipes, not for square pipes. Requirements for the use of modified polypropylene pipes for electric power
HDPE pipes have the following disadvantages: 1. Low Vicat temperature, poor heat resistance, less than 80 ℃; 2. Low tensile strength, less than 18 MPa; 3. Low flexural modulus, less than 800 MPa; 4. Poor flame retardancy, easy 5. Poor processability, high viscosity of HDPE material, resulting in slow production speed and poor gloss of pipe appearance
[0003] The MPP single-wall corrugated pipe is made of reinforced modified polypropylene raw materials. The main mechanism is to increase the strength of the pipe by adding a large amount of inorganic reinforcing materials (the circular pipe is limited by the structure, and the compressive capacity in the vertical direction is higher than that of the pipe). It is much lower than the square pipe, so it is necessary to make up the structural defects through materials), but in this way, the toughness index and other indexes of the material are greatly damaged, so there are the following disadvantages: 1. The low temperature performance is poor, because it is necessary to make up for the structural defects. Defects in compressive strength, a large amount of inorganic reinforcing materials are added to the material, which seriously damages the toughness of the material, and the impact performance is greatly reduced; 2. The tensile strength is low, generally about 22 MPa; 3. The surface of the product is smooth 4. Poor flame retardancy, because in order to increase the modulus of the material, a large amount of inorganic powder material is added to the formula, and the inorganic powder material has a combustion-supporting effect on the product, so it cannot be flame-retardant; 5. The thermal conductivity is low, ranging from 0.28 to 0.32, resulting in slow cooling and forming speed, low production speed and high processing cost

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • High-performance functionalized alloy modified polypropylene corrugated pipe special-use material and preparation method thereof
  • High-performance functionalized alloy modified polypropylene corrugated pipe special-use material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A high-performance functional alloy modified polypropylene bellows special material is composed of: 65 parts of homopolypropylene powder, 15 parts of block copolymerized polypropylene powder, 10 parts of filler, 5 parts of compatibilizing and toughening agent, fluidity 2.5 parts of modifier, 2 parts of flame retardant, 0.3 part of antioxidant, 0.2 part of ultraviolet absorber.

[0034] The preparation method is carried out according to the following steps:

[0035] (1) Add 8 kg of hollow glass microspheres, 2 kg of nano-calcium carbonate and 1 wt% silane coupling agent KH560 into the high mixer, keep the speed at 2000 rpm, and stir at high speed for 20 minutes to obtain the filler described in the present invention ;

[0036](2) 5 kg polypropylene (PP), 0.5 wt% dicumyl peroxide (DCP), 3 wt% maleic anhydride (MAH), and 5 wt% siloxane KH580 were added to the internal mixer together, Banburying at 190°C for 8 min at a rotating speed of 30 rpm to obtain the compatibilizin...

Embodiment 2

[0042] A high-performance functional alloy modified polypropylene bellows special material is composed of: 70 parts of homopolypropylene powder, 10 parts of block copolymerized polypropylene powder, 8 parts of filler, 7 parts of compatibilizing and toughening agent, fluidity 2.5 parts of modifier, 2.2 parts of flame retardant, 0.2 part of antioxidant, 0.1 part of ultraviolet absorber.

[0043] The preparation method is carried out according to the following steps:

[0044] (1) Add 5 kg of hollow glass microspheres, 3 kg of nano-calcium carbonate and 1 wt% of silane coupling agent KH550 into the high mixer, keep the speed at 2000 rpm, and stir at high speed for 20 minutes to obtain the filler described in the present invention ;

[0045] (2) Add 5 kg polypropylene (PP), 0.8 wt% dicumyl peroxide (DCP), 5 wt% maleic anhydride (MAH), and 8 wt% vinyltriethoxysilane to the banburying mixer In the machine, at 190 ℃, banburying 8 min under the condition of rotating speed 30 rpm, obt...

Embodiment 3

[0050] (1) Add 5 kg polypropylene (PP), 0.8 wt% dicumyl peroxide (DCP), 5 wt% maleic anhydride (MAH), and 8 wt% vinyltriethoxysilane to the banburying mixer In the machine, at 190 ℃, banburying 8 min under the condition of rotating speed 30 rpm, obtain the compatibilizing and toughening agent of the present invention;

[0051] (2) Mix 2.0 kg of homopolypropylene and 8.0 kg of block copolymerized polypropylene with the above-mentioned compatibilizing and toughening agent. Melt granulation is carried out in the extruder, the barrel temperature is 130 °C, 145 °C, 155 °C, 170 °C, 180 °C, 185 °C, 195 °C, 205 °C, 180 °C, 170 °C, the screw speed is 160r / min, The feeding speed is 16 r / min. The masterbatch is injected, and the temperature of the injection molding machine is 200 °C, 200 °C, and 190 °C. The samples obtained by injection molding were subjected to tensile (GB / T1040.2-2006) and impact (GB / T1943-2008) performance tests, and the results are shown in figure 1 and figure 2...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
oxygen indexaaaaaaaaaa
Login to View More

Abstract

The invention discloses a high-performance functionalized alloy modified polypropylene corrugated pipe special-use material and a preparation method thereof. The special-use material includes, by weight, 40-70 parts of homo-polypropylene powder, 15-25 parts of block-copolymerized polypropylene powder, 3-15 parts of filler, 2-10 parts of a compatibilizing and toughening agent, 1-5 parts of a flowability modifier, 1-5 parts of a flame retardant, 0.1-1.2 parts of an antioxidant, and 0.05-0.5 parts of an ultraviolet absorber. The corrugated pipe manufactured from the special-use material has goodmechanical performance and low-temperature anti-impact effect, is high in thermal-deformation temperature and heat-conductivity, and has good flame retarding effect, excellent surface glossiness and production stability.

Description

technical field [0001] The invention belongs to a high-performance functional alloy modified polypropylene corrugated pipe special material and a preparation method thereof. Background technique [0002] my country is a big country in the production and consumption of plastic products, especially plastic pipes occupy an extremely important position in the development of the national economy. Plastic pipes are widely used in many industrial applications such as construction engineering, electric power engineering, municipal engineering, communication engineering and petrochemical engineering, and are closely related to people's lives. The development field of this industry is not limited to the manufacture of plastic pipes, but also derives from many related fields such as plastic material modification research, formula system design and engineering installation, forming a plastic pipe manufacturing based on new material research and material modification. The development tr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L53/00C08L51/06C08K9/06C08K7/28C08K3/26C08K5/132
CPCC08K2003/265C08K2201/011C08L23/12C08L2201/08C08L2203/18C08L53/00C08L51/06C08K9/06C08K7/28C08K3/26C08K5/132
Inventor 黄宝铨颜品萍杨裕金陈庆华成惠斌杨松伟
Owner FUJIAN NORMAL UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products