A kind of automobile water-based interference type pearlescent glitter paint and preparation method thereof
An interference-type, flashing paint technology, applied in coatings, anti-corrosion coatings, etc., can solve problems such as insufficient corrosion resistance, paint film loss, floating color, etc., to achieve excellent water resistance and corrosion resistance, gorgeous and soft luster, and construction performance good effect
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Embodiment 1
[0038] Embodiment 1 The preparation of self-thickening acrylic acid emulsion
[0039] (1) Take 2g of sodium dodecylbenzenesulfonate, dissolve it in 20g of deionized water, and add 55g of methyl methacrylate and 23g of butyl acrylate dropwise under stirring at a speed of 1000rpm. Stir for 1 h after the addition to obtain a core layer pre-emulsion;
[0040] (2) Get 2g of sodium dodecylbenzene sulfonate, dissolve it in 20g of deionized water, and add dropwise 12g of methacrylic acid, 40g of hydroxyethyl methacrylate and 26g of butyl acrylate under stirring at a speed of 1000rpm Esters, after 0.5h dropwise, stir for 1h after the dropwise addition, to obtain the shell layer pre-emulsion;
[0041] (3) Add 40g of deionized water and 0.2g of sodium dodecylbenzenesulfonate under nitrogen protection into a four-necked flask equipped with an agitator, a condenser, and a two-port connecting pipe, stir well, and place in a constant temperature water bath Heating to 80° C., adding dropwis...
Embodiment 2
[0044] Embodiment 2 The preparation of self-thickening acrylic acid emulsion
[0045] (1) Take 3g of sodium dodecylbenzenesulfonate, dissolve it in 30g of deionized water, and add 45g of methyl methacrylate and 22g of butyl acrylate dropwise under stirring at a speed of 800rpm. Stir for 1 h after the addition to obtain a core layer pre-emulsion;
[0046] (2) Get 3g of sodium dodecylbenzenesulfonate, dissolve it in 30g of deionized water, and add dropwise 6g of methacrylic acid, 40g of hydroxyethyl methacrylate and 21g of butyl acrylate under stirring at 800rpm Esters, after 0.5h dropwise, stir for 1h after the dropwise addition, to obtain the shell layer pre-emulsion;
[0047] (3) Add 30g of deionized water and 0.3g of sodium dodecylbenzenesulfonate under nitrogen protection into a four-necked flask equipped with an agitator, condenser, and two-port connecting pipe, stir well, and place in a constant temperature water bath Heating to 85° C., adding dropwise 65 g of the core ...
Embodiment 3
[0050] Embodiment 3 Preparation of self-thickening acrylic acid emulsion
[0051] (1) Take 5g of sodium dodecylbenzene sulfonate, dissolve it in 25g of deionized water, and add 55g of methyl methacrylate and 15g of butyl acrylate dropwise under stirring at a speed of 1500rpm. Stir for 1 h after the addition to obtain a core layer pre-emulsion;
[0052] (2) Get 5g of sodium dodecylbenzene sulfonate, dissolve it in 25g of deionized water, stir with 1500rpm rotating speed, add dropwise the methacrylic acid of 8g, the hydroxyethyl methacrylate of 32g and the butyl acrylate of 30g Esters, after 0.5h dropwise, stir for 1h after the dropwise addition, to obtain the shell layer pre-emulsion;
[0053] (3) Add 55g deionized water and 0.4g sodium dodecylbenzenesulfonate under the protection of nitrogen in a four-necked flask equipped with a stirrer, a condenser tube, and a two-port connecting pipe, stir well, and place in a constant temperature water bath Heating to 80° C., dropwise ad...
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